journal article·2012-06-26Open access

Nanocomposites Containing Neutral Blue Emitting Cyclometalated Iridium(III) Emitters for Oxygen Sensing

Marta Marín-Suárez, Basile F. E. Curchod, Ivano Tavernelli, Ursula Rothlisberger, Rosario Scopelliti, Il Jung, Davide Di Censo, Michael Grätzel, Jorge Fernando Fernández-Sánchez, Alberto Fernández-Gutiérrez, Md. Khaja Nazeeruddin, Etienne Baranoff

Chemistry of Materials· Volume 24· Issue 12

Abstract

The behavior toward oxygen sensing of nanocomposites made of the aluminum oxide-hydroxide nanostructured solid support (AP200/19) and neutral blue emitting cyclometalated iridium(III) complexes was studied. The results are compared with the same dyes immobilized in polystyrene films. Since the photoluminescence of the complexes is totally quenched for oxygen concentrations just over 10%, these systems using the blue region of the visible spectrum are promising for oxygen detection at low concentration. In particular, dyes supported into the AP200/19 provide the best sensitivity to oxygen concentration, with the possibility to detect oxygen below 1% O 2 in gas (0.01 bar).
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Research context

OpenAlex topics: Analytical Chemistry and Sensors · Organic Light-Emitting Diodes Research · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Analytical Chemistry, Faculty of Sciences, University of Granada, E-18071 Granada, Spain

Laboratory of Computational Chemistry and Biochemistry, École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland

Laboratory of Photonics and Interfaces, École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland

School of Chemistry, University of Birmingham, Edgbaston B15 2TT, England

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