Anti-microbial and methylene blue dye adsorption properties of cotton fabrics modified with TiO 2 , Fe, Ag-doped TiO 2 , and graphene oxide nanomaterials
Source abstract
Abstract
Nanoparticle materials have received increasing attention in the functional modification of textiles. In this work, pure TiO 2 , Ag-doped TiO 2 , Fe-doped TiO 2 , and graphene oxide nanoparticles were used to impart the anti-bacterial and adsorptive properties of nanoparticles to cotton fabric. The treated fabric materials were investigated by X-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy. The obtained treated fabrics were used as adsorbents for the removal of methylene blue from aqueous solution. The functionalized cotton fabrics were tested for their anti-microbial capability against Escherichia coli, Bacillus cereus, and Candida albicans. All the functionalized fabrics have higher anti-microbial activity compared to untreated cotton, especially the fabrics containing silver and Fe-doped TiO 2 . The optimum conditions of the adsorption process are determined via the study of the effect of the initial concentration of dye, pH, and contact time on the removal efficiency. Langmuir, Freundlich, and Temkin isotherms are applied for the equilibrium adsorption data. GO-Cot and Ag-Ti@GO-Cot samples showed the highest adsorption removal activity. The linear correlation coefficient ( R 2 ) showed that the Temkin model well fitted the data of adsorption in the GO-Cot sample. The analysis of experimental data with different kinetic models showed that the pseudo-second-order kinetic model well fitted the adsorption data better than the other kinetic models of the pseudo-first-order, Elovich, and intra-particle diffusion.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Graphene and Nanomaterials Applications · Nanoparticles: synthesis and applications · Nanomaterials for catalytic reactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Chemistry Department, Faculty of Science, Benha University, Egypt
Chemistry Department, Faculty of Science, Imam Mohammad Ibn Saud Islamic University, Kingdom of Saudi Arabia
Ministry of Trade and Industry (Industrial Control Authority), Egypt
References (100+)
Show source-provided references
1. Ibrahim NA, Eid BM, Sharaf SM. Functional finishes for cotton-based textiles: current situation and future trends. Textiles and clothing . Hoboken: John Wiley & Sons, Inc.; Beverly: Scrivener Publishing LLC, 2019, pp.131–190.10.1002/9781119526599.ch7 ↗
2. 10.1016/j.colsurfb.2010.03.02910.1016/j.colsurfb.2010.03.029 ↗
3. 10.3390/ma906049810.3390/ma9060498 ↗
4. 10.3390/coatings910060610.3390/coatings9100606 ↗
5. 10.1007/s10570-019-02497-810.1007/s10570-019-02497-8 ↗
6. 10.1016/j.ijbiomac.2017.02.05810.1016/j.ijbiomac.2017.02.058 ↗
7. 10.1016/j.carbpol.2018.06.01010.1016/j.carbpol.2018.06.010 ↗
8. 10.1021/am200447p10.1021/am200447p ↗
9. 10.1063/1.274232410.1063/1.2742324 ↗
10. Khan I · Arab J Chem
11. 10.1007/s13204-011-0045-910.1007/s13204-011-0045-9 ↗
12. Chattopadhyay DP · Ind J Fibre Textile Res · 2009 · 34 · 368
13. Chaudhari SB · Melliand Int · 2009 · 15 · 214
14. 10.1080/15440478.2010.55076910.1080/15440478.2010.550769 ↗
15. 10.1021/acs.langmuir.5b0234110.1021/acs.langmuir.5b02341 ↗
16. 10.1007/s10570-016-1012-010.1007/s10570-016-1012-0 ↗
17. 10.1016/j.ecoenv.2021.11197810.1016/j.ecoenv.2021.111978 ↗
18. 10.1016/j.colsurfb.2007.12.01810.1016/j.colsurfb.2007.12.018 ↗
19. 10.1007/s12034-020-02322-010.1007/s12034-020-02322-0 ↗
20. 10.3390/catal1007075910.3390/catal10070759 ↗
21. Haghi M. · Intern J Adv Biotechnol Res · 2012 · 3 · 621
22. 10.3390/catal910085510.3390/catal9100855 ↗
23. Le TS · Adv Nat Sci Nanosci Nanotechnol · 2015 · 6
24. 10.1016/S1001-0742(12)60318-010.1016/S1001-0742(12)60318-0 ↗
25. 10.3390/nano802012810.3390/nano8020128 ↗
26. 10.1021/acsami.7b0092010.1021/acsami.7b00920 ↗
27. 10.1021/acs.est.5b0573410.1021/acs.est.5b05734 ↗
28. 10.1016/j.jece.2021.10548010.1016/j.jece.2021.105480 ↗
29. Nguyen TMP · Mater Sci Appl · 2021 · 12 · 89
30. 10.3390/nano1011231810.3390/nano10112318 ↗
31. Hontañon E · Int J Theor Appl Nanotechnol · 2016 · 4 · 17
32. 10.1080/15440478.2018.155814610.1080/15440478.2018.1558146 ↗
33. 10.1021/nn101097v10.1021/nn101097v ↗
34. 10.1021/nn101390x10.1021/nn101390x ↗
35. 10.1021/nn101081t10.1021/nn101081t ↗
36. 10.1063/1.355543810.1063/1.3555438 ↗
37. 10.1063/1.348495610.1063/1.3484956 ↗
38. Karthikeyan K · Appl Phys Lett · 2011 · 98
39. Qi K · Text Res J · 2011 · 8 · 101
40. 10.1007/s10971-005-1321-510.1007/s10971-005-1321-5 ↗
41. 10.1016/j.porgcoat.2006.08.02710.1016/j.porgcoat.2006.08.027 ↗
42. 10.1016/j.memsci.2017.03.01410.1016/j.memsci.2017.03.014 ↗
43. 10.1016/j.cej.2014.12.09010.1016/j.cej.2014.12.090 ↗
44. 10.4491/eer.2015.01810.4491/eer.2015.018 ↗
45. Ebrahim SE · Assoc Arab Univ J Eng Sci · 2018 · 25 · 29
46. 10.1007/s11356-016-7750-610.1007/s11356-016-7750-6 ↗
47. 10.1016/j.jhazmat.2018.09.07010.1016/j.jhazmat.2018.09.070 ↗
48. 10.1016/j.jclepro.2018.03.20910.1016/j.jclepro.2018.03.209 ↗
49. Ali I · Int J Electrochem Sci · 2012 · 7 · 189810.1016/S1452-3981(23)13848-X ↗
50. 10.1016/j.jenvman.2008.11.01710.1016/j.jenvman.2008.11.017 ↗
51. 10.1007/s11356-019-05706-w10.1007/s11356-019-05706-w ↗
52. 10.1016/j.elecom.2016.12.00810.1016/j.elecom.2016.12.008 ↗
53. 10.1016/j.msec.2011.03.00610.1016/j.msec.2011.03.006 ↗
54. 10.1016/j.molliq.2016.06.07410.1016/j.molliq.2016.06.074 ↗
55. 10.1016/j.jcis.2015.04.03510.1016/j.jcis.2015.04.035 ↗
56. 10.1039/C5RA02557E10.1039/C5RA02557E ↗
57. 10.1016/j.molliq.2014.07.03010.1016/j.molliq.2014.07.030 ↗
58. 10.1016/j.jtice.2013.12.02110.1016/j.jtice.2013.12.021 ↗
59. 10.1038/srep3164110.1038/srep31641 ↗
60. 10.1016/j.molliq.2015.09.00610.1016/j.molliq.2015.09.006 ↗
61. 10.1021/acs.jced.8b0065610.1021/acs.jced.8b00656 ↗
62. 10.1016/j.envpol.2020.11423110.1016/j.envpol.2020.114231 ↗
63. 10.1080/0149639970800222710.1080/01496399708002227 ↗
64. 10.1016/j.jcis.2011.06.06710.1016/j.jcis.2011.06.067 ↗
65. 10.1038/s41598-017-18108-010.1038/s41598-017-18108-0 ↗
66. Crini G · Environ Chem Sustain World · 2018 · 18 · 23
67. 10.1016/j.chemosphere.2018.04.05310.1016/j.chemosphere.2018.04.053 ↗
68. 10.1016/j.ccr.2017.11.00310.1016/j.ccr.2017.11.003 ↗
69. 10.1038/s41598-018-19978-810.1038/s41598-018-19978-8 ↗
70. 10.1038/s41565-018-0234-810.1038/s41565-018-0234-8 ↗
71. Ali I, Jain CK. In: Lehr J (ed.), Waste water treatment. Water encyclopedia: domestic, municipal, and industrial water supply and waste disposal . New York: John Wiley & Sons, 2005.
72. 10.1007/s11356-012-0950-910.1007/s11356-012-0950-9 ↗
73. 10.1021/acsami.0c0284810.1021/acsami.0c02848 ↗
74. 10.1039/C7TA10428F10.1039/C7TA10428F ↗
75. 10.1016/j.jhazmat.2019.12179210.1016/j.jhazmat.2019.121792 ↗
76. 10.3923/jas.2006.692.69510.3923/jas.2006.692.695 ↗
77. 10.1016/j.wri.2014.06.00210.1016/j.wri.2014.06.002 ↗
78. 10.1016/j.jhazmat.2008.07.15510.1016/j.jhazmat.2008.07.155 ↗
79. 10.1016/j.jwpe.2014.03.00210.1016/j.jwpe.2014.03.002 ↗
80. 10.1016/j.desal.2008.01.01510.1016/j.desal.2008.01.015 ↗
81. 10.1016/j.jwpe.2014.02.00110.1016/j.jwpe.2014.02.001 ↗
82. 10.1016/j.wri.2014.04.00210.1016/j.wri.2014.04.002 ↗
83. 10.1016/j.jhazmat.2008.10.10110.1016/j.jhazmat.2008.10.101 ↗
84. 10.1016/j.jscs.2010.10.00210.1016/j.jscs.2010.10.002 ↗
85. 10.1016/S0045-6535(02)00629-X10.1016/S0045-6535(02)00629-X ↗
86. 10.1021/ie010667+10.1021/ie010667+ ↗
87. 10.1006/jcis.2001.798910.1006/jcis.2001.7989 ↗
88. 10.1016/j.jtice.2012.09.00710.1016/j.jtice.2012.09.007 ↗
89. 10.1021/ja806262m10.1021/ja806262m ↗
90. 10.1016/j.synthmet.2015.01.01710.1016/j.synthmet.2015.01.017 ↗
91. 10.3390/ma811543710.3390/ma8115437 ↗
92. 10.1021/ja02242a00410.1021/ja02242a004 ↗
93. Freundlich HMF. · J Phys Chem · 1906 · 57 · 385
94. 10.1039/f1977730045610.1039/f19777300456 ↗
95. 10.1016/j.ultsonch.2016.06.02210.1016/j.ultsonch.2016.06.022 ↗
96. Oboh IO · Int J Phys Sci · 2013 · 8 · 1722
97. 10.1016/j.still.2015.07.01310.1016/j.still.2015.07.013 ↗
98. 10.1016/j.apsusc.2014.11.09710.1016/j.apsusc.2014.11.097 ↗
99. 10.1016/j.colsurfa.2020.12462310.1016/j.colsurfa.2020.124623 ↗
100. 10.1016/j.carbpol.2018.08.06810.1016/j.carbpol.2018.08.068 ↗