Hygroscopic Nature of Lithium Ions: A Simple Key to Super Tough Atmosphere-Stable Hydrogel Electrolytes

Gel electrolytes have emerged as a versatile solution to address numerous limitations associated with liquid electrolytes in electrical energy storage (EES) devices, in terms of safety, flexibility, and affordability. Aqueous gel electrolytes, in particular, exhibit exceptional features by offering one of the highest ion solvation capacities and ionic conductivities. The two main challenges with hydrogel electrolytes are their easy freezing at subzero temperatures and rapid dehydration under open conditions, leading to the failure of the EES device. In response, we present an uncomplicated and quick-to-make hydrogel electrolyte system offering impressive mechanical properties (205.5 kPa tensile strength, 2880 kJ/m 3 toughness, and 3030% strain at the break), along with antifreezing and antiflammability attributes. Notably, the hydrogel electrolyte demonstrates high ionic conductivity and superior performance in supercapacitor cells over a wide range of temperatures (−40 to 80 °C) and under various deformations. The hydrogel electrolyte maintains its capabilities under open conditions over an extended period of time, even at 50 °C, showcased by powering a wristwatch. The atmospheric stability of the hydrogel electrolyte demonstrated in this study introduces promising prospects for the future of EES devices spanning from production to end-user consumption.