journal article·2019-12

Flame-retardant composite coatings for cotton fabrics fabricated by using oxygen plasma-induced polymerization of vinyl phosphonic acid/cyclotetrasiloxane

Jiawei Li, Wei Tong, Lingmin Yi

Textile Research Journal· Volume 89· Issue 23-24
Publisher page

Abstract

Environment-friendly flame-retardant cotton textiles have been receiving considerable interest both in academic and industrial circles for years. Herein, a novel flame-retardant coating for cotton fabrics was reported based on vinyl phosphonic acid and 1,3,5,7-tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane through an O 2 plasma-induced polymerization process. The coating on cotton fabrics was confirmed by Fourier transform infrared spectrophotometry, scanning electron microscopy and energy dispersive X-ray spectrometry. Excellent flame retardancy and thermal stability properties were found from thermogravimetric analysis, the limiting oxygen index, modified vertical burning tests and pyrolysis combustion flow calorimetry. The results revealed that there was a good synergistic effect between poly(vinyl phosphonic acid) and polysiloxane segments in flame-retardant cotton fibers. The new flame-retardant coating induced an earlier decomposition of cellulose, and enhanced the formation of stable char under thermal oxygen and significantly reduced the heat release capacity.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Flame retardant materials and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Advanced Functional Coatings, College of Materials and Textiles, Zhejiang Sci-Tech University, P. R. China

Engineering Research Center for Eco-Dyeing & Finishing of Textiles, Ministry of Education, Zhejiang Sci-Tech University, P. R. China

National Demonstration Center for Experimental Textile Engineering Education (Zhejiang Sci-Tech University), P. R. China

Funding

the Zhejiang Provincial Top Key Academic Discipline of Chemical Engineering and Technology

References (44)

Show source-provided references
1. 10.1016/j.polymdegradstab.2013.07.01210.1016/j.polymdegradstab.2013.07.012 ↗
2. 10.1039/C5RA01176K10.1039/C5RA01176K ↗
3. Barker RH and Drews MJ. Flame retardants for cellulose materials. In: Nevell TP and Haig Zeronian S (eds) Cellose chemistry and its applications . New York: Ellis Horwood Lim., 1985, pp. 423–454.
4. 10.1016/j.progpolymsci.2015.04.01010.1016/j.progpolymsci.2015.04.010 ↗
5. 10.1016/j.polymdegradstab.2010.03.03610.1016/j.polymdegradstab.2010.03.036 ↗
6. 10.1016/S0141-3910(96)00038-910.1016/S0141-3910(96)00038-9 ↗
7. 10.1007/s10853-017-1390-110.1007/s10853-017-1390-1 ↗
8. 10.3390/coatings603003310.3390/coatings6030033 ↗
9. 10.1016/j.compositesb.2015.03.06110.1016/j.compositesb.2015.03.061 ↗
10. 10.1021/bm300873b10.1021/bm300873b ↗
11. 10.1016/j.surfcoat.2006.05.00210.1016/j.surfcoat.2006.05.002 ↗
12. 10.1016/j.surfcoat.2006.10.02710.1016/j.surfcoat.2006.10.027 ↗
13. 10.1016/j.compositesb.2012.07.05210.1016/j.compositesb.2012.07.052 ↗
14. 10.1039/C6RA26075F10.1039/C6RA26075F ↗
15. 10.1016/j.carbpol.2017.05.05410.1016/j.carbpol.2017.05.054 ↗
16. 10.1016/j.eurpolymj.2015.05.00510.1016/j.eurpolymj.2015.05.005 ↗
17. 10.1016/j.radphyschem.2017.10.01310.1016/j.radphyschem.2017.10.013 ↗
18. 10.1016/j.polymdegradstab.2016.04.01210.1016/j.polymdegradstab.2016.04.012 ↗
19. 10.1016/j.porgcoat.2016.10.03510.1016/j.porgcoat.2016.10.035 ↗
20. 10.1007/s10570-015-0599-x10.1007/s10570-015-0599-x ↗
21. 10.1016/j.cej.2016.02.08010.1016/j.cej.2016.02.080 ↗
22. 10.1016/j.polymdegradstab.2016.02.00910.1016/j.polymdegradstab.2016.02.009 ↗
23. 10.1016/j.polymdegradstab.2017.11.00610.1016/j.polymdegradstab.2017.11.006 ↗
24. 10.1021/acsami.7b0986310.1021/acsami.7b09863 ↗
25. 10.1007/s10570-017-1294-x10.1007/s10570-017-1294-x ↗
26. 10.1016/j.jaap.2017.04.01110.1016/j.jaap.2017.04.011 ↗
27. 10.1016/j.polymdegradstab.2010.02.02210.1016/j.polymdegradstab.2010.02.022 ↗
28. 10.1039/c3ta00107e10.1039/c3ta00107e ↗
29. 10.1016/j.carbpol.2013.03.06610.1016/j.carbpol.2013.03.066 ↗
30. 10.1016/j.jaap.2014.04.01410.1016/j.jaap.2014.04.014 ↗
31. 10.1016/j.surfcoat.2015.06.05010.1016/j.surfcoat.2015.06.050 ↗
32. 10.1016/j.matlet.2017.05.02910.1016/j.matlet.2017.05.029 ↗
33. 10.1177/004051751774849210.1177/0040517517748492 ↗
34. 10.1016/j.polymdegradstab.2008.11.01910.1016/j.polymdegradstab.2008.11.019 ↗
35. Li Y · J Appl Polym Sci · 2014 · 131 · 4001110.1002/app.40011 ↗
36. 10.1002/pi.546610.1002/pi.5466 ↗
37. 10.1016/j.polymdegradstab.2014.08.02710.1016/j.polymdegradstab.2014.08.027 ↗
38. Shafizadeh F. Thermal degradation of cellulose. In: Nevell TP and Haig Zeronian S (eds) Cellose chemistry and its applications . New York: Ellis Horwood Lim., 1985, pp. 264–289.
39. 10.1016/j.jaap.2003.09.00510.1016/j.jaap.2003.09.005 ↗
40. 10.1016/j.polymdegradstab.2013.10.00410.1016/j.polymdegradstab.2013.10.004 ↗
41. 10.1016/j.polymdegradstab.2009.11.04710.1016/j.polymdegradstab.2009.11.047 ↗
42. 10.1016/j.jaap.2012.11.00910.1016/j.jaap.2012.11.009 ↗
43. 10.1016/j.jaap.2009.10.01110.1016/j.jaap.2009.10.011 ↗
44. 10.1080/1532179960801485910.1080/15321799608014859 ↗