Preparation and characterization of reactive chitosan quaternary ammonium salt and its application in antibacterial finishing of cotton fabric
Source abstract
Abstract
The water soluble and reactive O-methyl acrylamide quaternary ammonium salt of chitosan (NMA-HTCC) was prepared with a view to develop an antibacterial finishing on cotton fabric. 2-hydroxypropyltrimethyl ammonium chloride chitosan (HTCC) was synthesized by the chemical reaction of chitosan and 2,3-epoxypropyltrimethyl ammonium chloride. Then, NMA-HTCC with reactive groups was synthesized by the chemical reaction of HTCC and N-(hydroxymethyl) –acrylamide, and its chemical structure was characterized by the Fourier transform infrared spectroscopy and nuclear magnetic resonance (NMR). The antibacterial activities of chitosan and NMA-HTCC were tested and compared by the minimal inhibitory method. Cotton fabrics were finished by NMA-HTCC under the alkalinity condition using sodium bicarbonate as the catalyst. The antibacterial activity of cotton fabric before and after finishing was measured by the oscillation flask method. The results showed that both chitosan and NMA-HTCC had a significant antibacterial effect on staphylococcus and coli, and the antibacterial activity of NMA-HTCC was better than that of chitosan. The antibacterial activity of cotton fabric to staphylococcus and coli were significantly improved after finishing by chitosan and NMA-HTCC, and the antibacterial activity of the cotton fabric finished by NMA-HTCC was better than that finished by chitosan.
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Research context
OpenAlex topics: Dyeing and Modifying Textile Fibers
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Textiles and Clothes, Yancheng Institute of Technology, P. R. China
Jiangsu Entry-Exit Inspection and Quarantine Bureau Textile Laboratory, P. R. China
References (20)
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1. Spinelli VA, Laranjeira MCM and Fávere VT. Preparation and characterization of quaternary chitosan salt: Adsorption equilibrium of chromium(VI) ion. Reactive Funct Polym 2004; 61: 347.10.1016/j.reactfunctpolym.2004.06.010 ↗
2. Zhang W, Cheng YG and Chen YY. Salt-free reactive dyeing of Bombyx Mori silk fabric treated by chitosan quaternary ammonium salt (HTCC). Text Aux 2012; 29: 39.
3. Mohamed NA, Mohamed RR and Seoudi RS. Synthesis and characterization of some novel antimicrobial thiosemicarbazone O-carboxymethyl chitosan derivatives. Int J Biol Macromol 2014; 63: 163.10.1016/j.ijbiomac.2013.10.044 ↗
4. Li PW, Wang G, Yang ZM, et al. Development of drug-loaded chitosan-vanillin nanoparticles and its cytotoxicity against HT-29 cells. Drug Deliv 2014; 21: 548.10.3109/10717544.2014.900590 ↗
5. Alonso D, Gimeno M, Olayo R, et al. Cross-linking chitosan into UV-irradiated cellulose fibers for the preparation of antimicrobial-finished textiles. Carbohydr Polym 2009; 77: 536.10.1016/j.carbpol.2009.01.027 ↗
6. Lu YH, Lin H, Chen YY, et al. Structure and performance of Bombyx mori silk modified with nano-TiO2 and chitosan. Fibers Polym 2007; 18: 1.10.1007/BF02908152 ↗
7. Lu YH, Cheng DH, Lu S, et al. Preparation of quaternary ammonium salt of chitosan nanoparticles and their textile properties on Antheraea pernyi silk modification. Text Res J 2014; 84: 2115.10.1177/0040517514538691 ↗
8. Lim SH and Hudson SM. Synthesis and antimicrobial activity of a water-soluble chitosan derivative with a fiber-reactive group. Carbohydr Res 2004; 6: 313.10.1016/j.carres.2003.10.024 ↗
9. Zhang W, Zhu B and Chen YY. Application of chitosan quaternary ammonium salt to antibacterial finishing of Bombyx mori silk fabrics. J Text Res 2010; 31: 76.
10. Fu X, Shen Y, Jiang X, et al. Chitosan derivatives with dual-antibacterial functional groups for antimicrobial finishing of cotton fabrics. Carbohydr Polym 2011; 85: 221.10.1016/j.carbpol.2011.02.019 ↗
11. Tayel AA, Moussa SH, El-Tras WF, et al. Anticandidal action of fungal chitosan against Candida albicans. Int J Biol Macromol 2011; 49: 241.10.1016/j.ijbiomac.2011.04.023 ↗
12. Akhtar M, Hai A, Awais MM, et al. Immuno stimulatory and protective effects of Aloe vera against coccidiosis in industrial broiler chickens. Vet Parasitol 2012; 186: 170.10.1016/j.vetpar.2011.11.059 ↗
13. Fan L, Wu P, Zhang J, et al. Synthesis and anticoagulant activity of the quaternary ammonium chitosan sulfates. Int J Biol Macromol 2012; 50: 31.10.1016/j.ijbiomac.2011.09.024 ↗
14. Xu YH, Du ZF and Liu X. Structure and properties of chitosan imine modified cotton fibers. J Text Res 2012; 33: 35.
15. Silva SS, Caridade SG, Mano JF, et al. Effect of crosslinking in chitosan/aloe vera-based membranes for biomedical applications. Carbohydr Polym 2013; 98: 581.10.1016/j.carbpol.2013.06.022 ↗
16. Zhang W and Zhou JJ. Salt-free dyeing properties of cotton fabric modified with reactive quaternary ammonium salt of chitosan (NMA-HTCC). Text Aux 2014; 31: 41.
17. Silva SS, Popa EG, Gomes ME, et al. Acta Biomater 2013; 9: 6790.10.1016/j.actbio.2013.02.027 ↗
18. Topalovic T, Nierstrasz VA, Bautista L, et al. XPS and contact angle study of cotton surface oxidation by catalytic bleaching. Colloid Surf A 2007; 296: 76.10.1016/j.colsurfa.2006.09.026 ↗
19. Lu YH, Liu ZM and Lin J. Synthesis of reactive quaternary ammonium salt of chitosan and its application on antibacterial finishing of tussah silk. J Text Res 2010; 4: 88.
20. Wang JG, Wang YL, Ge MQ, et al. Research on antimicrobial finishing of cotton fabrics with a citric acid and chitosan. J Text Res 2006; 27: 89.