journal article·2026-01-26

Effects of variability of wood chip composition on recovery cycle operation

Tortsen Meyer

TAPPI Journal· Volume 25· Issue 1
Publisher page

Abstract

Fluctuations in wood chip properties in kraft pulp mills, which often follow seasonal patterns, can lead to changes or disruptions in the operation of the recovery cycle whereby the root causes are not immediately obvious. In some cases, these changes are attributed to operational adjustments in the digester or brownstock washing areas resulting from the variability in wood characteristics. Varying wood chip characteristics that have the most significant impact on the recovery cycle operation include the content of non-process elements (NPEs), extractives, and properties influenced by chip storage conditions. Elevated levels of NPEs, often associated with a higher influx of wood bark into the digester, can negatively affect the entire recovery cycle. Increased levels of chlorine and potassium can lead to severe fouling and corrosion in the recovery boiler. Higher concentrations of silicon, aluminum, phosphorus, magnesium and calcium in the chips may accelerate scaling in the evaporation plant, impair dregs and lime mud settling and filtering, reduce lime mud solids content and lime availability, and increase the amounts of dregs, grits, and purged lime mud. This technical review provides an overview of the most significant effects that changes in wood chip quality can potentially exert on various processes within the kraft recovery cycle.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Lignin and Wood Chemistry · Materials Engineering and Processing · Advanced Cellulose Research Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

University of Toronto

References (63)

Show source-provided references
1. 1. Hart, P., TAPPI J. 8(3): 4(2009). https://doi.org/10.32964/TJ8.3.4.10.32964/TJ8.3.4 ↗
2. 2. Laganière, B. and Hernández, R.E., For. Prod. J. 55(3): 44(2005).
3. 3. Meyer, T., Munn, H., Tran, H., TAPPI J. 21(8): 435(2022). https://doi.org/10.32964/TJ21.8.435.10.32964/TJ21.8.435 ↗
4. 4. Doldán, J., Poukka, O., Salmenoja, K., et al., O Papel 72(7): 47(2011).
5. 5. Richardson, B., Uloth, V., Lownertz, P., et al., “Behaviour of non-process elements in the kraft recovery system,” Int. Chem. Recovery Conf., TAPPI Press, Atlanta,1998.
6. 6. Werkelin, J., Skrifvars, B.-J., and Hupa, M., Biomass Bioenergy 29: 451(2005). https://doi.org/10.1016/j.biombioe.2005.06.005.10.1016/j.biombioe.2005.06.005 ↗
7. 7. Frandsen, F.J., van Lith, S.C., Korbee, R., et al., Fuel Process. Technol. 88: 1118(2007). https://doi.org/10.1016/j.fuproc.2007.06.012.10.1016/j.fuproc.2007.06.012 ↗
8. 8. Rajesh, K.S., Tamilarasy, R.S., Vijayakumar, T., et al., IPPTA J. 21(3): 129(2009).
9. 9. “The modern white liquor plant,” Valmet – Technical Paper Series, Valmet, Espoo, Finland, 1 July 2017.
10. 10. Hogan, B., McDermott, F., and Schmidt, O., J. Plant Nutr. Soil Sci. 181: 231(2018). https://doi.org/10.1002/jpln.201700515.10.1002/jpln.201700515 ↗
11. 11. Rothpfeffer, C. and Karltun, E., Biomass Bioenergy 31: 717(2007). https://doi.org/10.1016/j.biombioe.2007.06.017.10.1016/j.biombioe.2007.06.017 ↗
12. 12. Krutul, D., Zielenkiewicz, T., Radomski, A., et al., Wood Res. 62(3): 353(2017).
13. 13. Salmenoja, K., Poukka, O., and Battegazzore, M., “Management of non-process elements in eucalyptus kraft pulp mills,” 42nd Pulp Pap. Int. Congr. Exhib., ABTCP-PI 2009, ABTCP, São Paulo, 2009.
14. 14. Tran, H., “Recovery boiler fireside deposits and plugging preven-tion,” TAPPI Kraft Recovery Operations Course, Vol. 2, 2007, p. 537.
15. 15. Tran, H., Gonsko, M., and Mao, X., TAPPI J. 82(9): 93(1999).
16. 16. Jordan, J.M. and Bryant, P.S. “Cluster rule impact on recovery boiler operations: chloride and potassium concentrations in the kraft liquor cycle,” Int. Environ. Conf., TAPPI Press, Atlanta, 1995.
17. 17. Saarela, K.-E., Harju, L., Lill, J.-O., et al., Holzforschung 56:
18. 380(2002). https://doi.org/10.1515/HF.2002.060.10.1515/HF.2002.060 ↗
19. 18. Saarela, K.-E., Harju, L., Rajander, J., et al., Sci. Total Environ. 343: 231(2005). https://doi.org/10.1016/j.scitotenv.2004.09.043.10.1016/j.scitotenv.2004.09.043 ↗
20. 19. Abe, H., Tsuchiya, Y., Kagawa, A., et al., “Potassium content
21. in the wood and bark of 38 tree species,” IUFRO World Congr., International Union of Forest Research Organizations, Vienna, 2019.
22. 20. Salmenoja, K., Kivilinna, V.-A., Hupa, M., et al., “Chemical bal-ance of non-process elements in five Finnish pulp mills,” Int. Chem. Recovery Conf., TAPPI Press, Atlanta, 2004.
23. 21. Bialik, M., Jensen, A., and Ahlroth, M., TAPPI J. 14(7): 421(2015). https://doi.org/10.32964/TJ14.7.421.10.32964/TJ14.7.421 ↗
24. 22. Schowalter, T.D. and Morrell, J.J., Wood Fiber Sci. 34(1): 158(2002).
25. 23. Werkelin, J., Skrifvars, B.-J., Zevenhoven, M., et al., Fuel 89: 481(2010). https://doi.org/10.1016/j.fuel.2009.09.005.10.1016/j.fuel.2009.09.005 ↗
26. 24. Hartler N. and Libert J., Sven. Papperstidn. 76(12): 454(1973).
27. 25. Empie, H.J., Ellis, M., and Amundsen, M., “Fundamentals of dregs removal,” Final Report, Project F01707, Institute of Paper Science and Technology, Atlanta, 1999.
28. 26. Karlemo, C., “Non-process elements in the recovery cycle of six Finnish kraft pulp mills,” Master’s thesis, Åbo Akademi University, Turku, Finland, 2019.
29. 27. Hildén, L. and Persson, E., “Seasonal extractive variations in tree, chips and TMP,” Int. Mech. Pulping Conf., 2007.
30. 28. Nisula, L., “Wood extractives in conifers,” Ph.D. thesis, Åbo Akademi University, Turku, Finland, 2018.
31. 29. Chen, T., Wang, Z., Zhou, Y., et al., TAPPI J. 78(10): 143(1995).
32. 30. Nugent, H.M., Allen, L.H., and Bolker, H.I., Trans. Tech. Sect. Can. Pulp Pap. Assoc. 3(4): 103(1977).
33. 31. Allen, L.H., Sitholé, B.B., MacLeod, J.M., et al., J. Pulp Pap. Sci. 17(3): J85(1991).
34. 32. Lindgren, R.M. and Eslyn, W.E., TAPPI J. 44(6): 419(1961).
35. 33. Halmemies, E.S., Alén, R., Hellström, J., et al., Molecules 27: 1186(2022). https://doi.org/10.3390/molecules27041186.10.3390/molecules27041186 ↗
36. 34. Foran, C.D., “Tall oil soap recovery,” TAPPI Kraft Recovery Operations Course, TAPPI Press, Peachtree Corners, GA, USA, 2023.
37. 35. Foran, C.D., “Tall oil soap recovery,” TAPPI Kraft Recovery Operations Course, TAPPI Press, Atlanta, 2008.
38. 36. Kaila, J. “Black liquor evaporators — troubleshooting and opti-mization,” TAPPI Kraft Recovery Operations Course, TAPPI Press, Peachtree Corners, GA, USA, 2023.
39. 37. Tikka, P., Kovasin, K., and Laxén, T., Pulp Pap. Can. 103(6):T149(2002).
40. 38. Meyer, T., Faria, T., Xavier, C.B., et al., TAPPI J. 23(5): 305(2024). https://doi.org/10.32964/TJ23.6.305.10.32964/TJ23.6.305 ↗
41. 39. Laxén, T. and Tikka, P., “Soap and tall oil,” in Chemical Pulping Part 2, Recovery of Chemicals and Energy (P. Tikka, Ed.), Papermaking Science and Technology Series, Paperi ja Puu Oy, Helsinki, 2008.
42. 40. Clay, D.T., “Evaporator fouling,” TAPPI Kraft Recovery Operations Course, TAPPI Press, Atlanta, 2008.
43. 41. Grace, T.M., “A survey of evaporator scaling in the alkaline pulp industry,” Project 3234, Report One, The Institute of Paper Chemistry, Appleton, WI, USA, 22 September 1975.
44. 42. Karlsson, E.; Åkesjö, A., Nord. Pulp Pap. Res. J. 36(1): 1(2020). https://doi.org/10.1515/npprj-2020-0081.10.1515/npprj-2020-0081 ↗
45. 43. Nwaeri, M., “Effect of resin acids and fatty acids on sodium salt scaling,” MASc thesis, University of Toronto, Toronto, 2021.10.1016/j.ces.2021.116989 ↗
46. 44. Niemi, P., Haaga, K., Välimäki, E., “Operational experiences from burning soap in recovery boiler,” Int. Chem. Recovery Conf., TAPPI/PAPTAC, Atlanta/Montreal, 2010.
47. 45. Hupa, M., “Black liquor burning processes,” in Kraft Recovery Boilers (H. Tran, Ed.), TAPPI Press, Peachtree Corners, GA, USA, 2019.
48. 46. Allen, L. and Uloth, V., “Operational extractives management from mountain pine beetle-attacked lodgepole pine for pulp and paper-making,” Mountain Pine Beetle Initiative Working Paper 2007-15, Paprican/Natural Resources Canada, Pointe-Claire, QC/Ottawa, 2007.
49. 47. Zhao, L., Cortes, D., and Tran, H., TAPPI J. 15(7): 479(2016). https://doi.org/10.32964/TJ15.7.479.10.32964/TJ15.7.479 ↗
50. 48. Frederick, W.J. and Buchanan, M., “Black liquor properties,” in Kraft Recovery Boilers (H. Tran, Ed.), TAPPI Press, Peachtree Corners, GA, USA, 2019.
51. 49. Mkhize, N.M., Sitholé, B.B., and Ntunka, M.G., J. Wood Chem. Technol. 35: 374(2015). https://doi.org/10.1080/02773813.2014.98407.10.1080/02773813.2014.984079 ↗
52. 50. Ahmad, Z., Dajani, W.W.A., Paleologou, M., et al., Molecules 25: 2329(2020). https://doi.org/10.3390/molecules25102329.10.3390/molecules25102329 ↗
53. 51. Stewart, J.J., Kadla, J.F., Mansfield, S.D., Holzforschung 60:111(2006). https://doi.org/10.1515/HF.2006.019.10.1515/HF.2006.019 ↗
54. 52. Govender, L., “Seasonal variation of microflora and their effects on the quality of wood chips intended for pulping,” MSc thesis, School of Life Sciences, University of KwaZulu-Natal, Durban, South Africa, 2013.
55. 53. Frederick, W.J., “Properties relevant to evaporation,” in Black Liquor Evaporation (W.J. Frederick and N. DeMartini, Eds.), TAPPI Press, Peachtree Corners, GA, USA, 2019.
56. 54. “Pulping system sensitivity to chip quality,” Acrowood Corp., Everett, WA, USA. Available [Online] https://acrowood.com/case-studies/pulping-system-sensitivity-chip-quality <02January2025>.
57. 55. Quinde, A., “Chip considerations: papermaking processes start with wood chip quality,” Pulp Pap. Can., Winter 2020.
58. 56. Brännvall, E. and Kulander, I., Nord. Pulp Pap. Res. J. 34(1): 28(2019). https://doi.org/10.1515/npprj-2018-0026.10.1515/npprj-2018-0026 ↗
59. 57. Anaya, A. and Singh, P.M., “Effect of wood species on corrosiv-ity of black liquors,” IPST Technical Paper Series Number 885, Institute of Paper Science and Technology, Atlanta, November 2000.
60. 58. Zaman, A.A. and Fricke, A.L., Ind. Eng. Chem. Res. 35: 590(1996). https://doi.org/10.1021/ie950202h.10.1021/ie950202h ↗
61. 59. Karlsson, E., Gourdon, M., Olausson, L., et al., Int. J. Heat Mass Transfer 65: 907(2013). https://doi.org/10.1016/j.ijheatmasstransfer.2013.07.003.10.1016/j.ijheatmasstransfer.2013.07.003 ↗
62. 60. Meyer, T., Goel, R., and Chowdhury, A., et al., J-FOR 7(2): 53(2017).
63. 61. Meyer, T., Goel, R., and Chowdhury, A., et al., “Operating param-eters affecting black liquor combustibility,” Int. Chem. Recovery Conf., PAPTAC, Brossard, QC, Canada, 2017.