journal article·2019Open access

Adsorption performance of magnetic aminated lignin for the removal of Cu(II) and Cd(II)

Dafeng Zheng, Yingzhi Ma, Xueqing Qiu, Xuejun Pan

TAPPI Journal· Volume 18· Issue 01

Abstract

The adsorption behavior of Cu(II) and Cd(II) onto a magnetic lignin-based nanomaterial (MLN) was investigated in detail. The results showed that the adsorption isotherm was better described by the Langmuir model, showing monolayer adsorption with a maximum adsorption capacity of 135.7 and 156.5 mg/g. The kinetics fit the pseudo-second-order model. The thermodynamics showed the enthalpy change of the adsorption for Cu(II) and Cd(II) was 24.12 and 36.49 kJ/mol, with entropy change of 85.12 and 130.3 J/mol·K, respectively; thus, the adsorption was endothermic and spontaneous in the range of 25°C–45°C. Additionally, the adsorbent was easy to regenerate. This study shows that MLN is a capable, sustainable absorbent for the removal of heavy metals.
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Research context

OpenAlex topics: Adsorption and biosorption for pollutant removal · Nanomaterials for catalytic reactions · Environmental remediation with nanomaterials

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