journal article·2020-12-01

The use of hollow sphere pigments as strength additives in paper and paperboard coatings—Part 2: Optimization in paperboard formulations for opacity and strength

BRIAN EINSLA, ETHAN GLOR, JOHN ROPER, JEFF LEITINGER, NICK NICHOLAS, SAMANTHA WOODFIN

TAPPI Journal· Volume 19· Issue 11
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Abstract

This report aims to summarize the efforts in testing the properties of coatings for paperboard utilizing hollow sphere pigments (HSPs). HSPs are known to effectively scatter light and replace titanium dioxide (TiO2) in architectural coating formulations. The effect of the particle size and void fraction was evaluated, along with many coating parameters, including level of addition, binder chemistry, and blends of two HSPs. The small HSPs that have optimized voids for scattering light showed equivalent strength to the TiO2-containing control. The strength data was surprising, particularly the improvement in strength for coatings containing large particle size HSPs. Because of this increase in strength, four parts of binder could be removed, which allowed for higher brightness while not compromising other properties, including hot melt glueability. These trends held true using different binder chemistries (styrene acrylic, vinyl acrylic, and styrene butadiene). Upon refining the formulations further, blends of two HSPs showed further benefit.
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Research context

OpenAlex topics: Material Properties and Processing · Recycling and Waste Management Techniques · Corrosion Behavior and Inhibition

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References (9)

Show source-provided references
1. Blankenship, R.M., U.S. pat. 5,545,695 (Aug. 13, 2996).
2. Blankenship, R.M. and Bardman, J.K., U.S. pat. 6,020,435 (Feb. 1, 2000).
3. Blankenship, R.M. and Bardman, J.K., U.S. pat. 6,252,004. (June 26, 2001).
4. Cardina, C.M., Francis, L.F., and Scriven, L.E., J. Coat. Technol. Res. 6(4): 457(2009). https://doi.org/10.1007/s11998-009-9167-3.10.1007/s11998-009-9167-3 ↗
5. Einsla, B., “Voided polymer imaging technology,” 255th ACS Natl. Meet., American Chemical Society, Washington, DC, 2018.
6. Keefe, M.H., Galloway, J.G., Drumright, R.E., et al., U.S. pat. 8,912,251 B2 (Dec. 16, 2014).
7. Glor, E., Einsla, B., Roper, J., et al., TAPPI J. 19(11): 585(2020).10.32964/TJ19.11.585 ↗
8. Mani, I., U.S. pat. 4,521,494 (Jun. 4, 1985).
9. Schmidt-Thümmes, J., Wirth, T., and Kirsch, S., U.S. pat. 6,447,926 B2 (Sep. 10, 2002).