journal article·2009-08-01

Reduction of Organic Pollutants with Recovery of Value-Added Products From Soda Black Liquor of Agricultural Residues by Electrolysis

Himadri Roy Ghatak

TAPPI Journal· Volume 8· Issue 7
Publisher page

Abstract

Batch electrolysis experiments were carried out on soda black liquors from agricultural residues at different interelectrode potentials. At low potential, the process was slow but energy-efficient, providing partial COD removal. It produced lignin at the anode with the exclusion of oxygen evolution. Hydrogen was produced at the cathode as a value-added product. At high interelectrode potential, the nascent oxygen produced at the anode led to oxidation of the organics. With prolonged electrolysis, complete removal of COD was possible, with a solution of sodium carbonate remaining. Low-potential electrolysis required about 2000 J of electricity per gram of COD removed, producing 180–190 mL hydrogen and approximately 0.55 g lignin. Electricity requirement per gram of COD removed in high-potential electrolysis varied from approximately 17,700 J at 1.5 V to approximately 149,000 J at 12 V. Approximately 1365 mL of hydrogen was produced for every gram of COD removed.
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Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced battery technologies research · Supercapacitor Materials and Fabrication

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