journal article·2017

Decision-making process for the identification of preferred lignin-based biorefinery strategies

Cedric Diffo Teguia, Sophie D'Amours, Rod Albers, Paul Stuart

TAPPI Journal· Volume 16· Issue 04
Publisher page

Abstract

The lignin biorefinery is emerging; there has been significant progress in recent years regarding lignin extraction and conversion processes, their implementation at the commercial scale, and the validation of lignin substitution potential in various applications. In this paper, seven strategies for implementing the lignin-based biorefinery into a kraft pulp mill were considered, and different performance metrics for these strategies were calculated in order to identify the “most preferred”. The different options addressed two distinctly different objectives that companies can consider regarding their biorefinery strategy, either (1) a near-term mill-level profitability improvement vision, or (2) a longer-term revenue growth-oriented vision. A phased-implementation approach was systematically defined for each option in order to mitigate technology and market risks. Lignin product applications that were considered included phenol replacement in phenol-formaldehyde (PF) resins, polyols replacement in polyurethane (PU) foams, and polyacrylonitrile (PAN) replacement in carbon fiber. A Multi-Criteria Decision-Making (MCDM) panel was executed for evaluating the seven lignin-based biorefinery strategies, using a set of economic, market risk, and competitiveness criteria. Although the panel selected Internal Rate of Return (IRR) as the most important criterion, Competitiveness on Production Costs (CPC) appeared to be the most important factor for distinguishing between lignin strategy options. CPC reflects the robustness of the biorefinery strategy relative to an aggressive price-cutting strategy from the competition. Overall, strategies involving lignin precipitation were more attractive economically, while those involving larger-scale solvent pulping processes and the associated larger revenue streams were considered better long-term strategies. The most preferred strategy considered by the panel was for precipitated lignin sold for both PF resin and PU foam applications. The next preferred strategy considered lignin sales to the same market segments, but at larger volumes. The next closely-ranked strategy considered the production of a lignin-based PF resin at the host mill. These three strategies were identified as “preferred,” for further, more detailed assessment.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Lignin and Wood Chemistry · Biofuel production and bioconversion · Catalysis for Biomass Conversion

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (39)

Show source-provided references
1. Ragauskas, A., “Lignin Overview,” Institute of Paper Science and Technology, Atlanta, GA, USA. Available [Online] http://www.ipst.gatech.edu/faculty/ragauskas_art/technical_reviews/Lignin%20Overview.pdf <18April2017>.
2. Zhang, Y.-H., J. Ind. Microbiol. Biotechnol. 35(5): 367(2008).10.1007/s10295-007-0293-6 ↗
3. Macdonald, C., Pulp Pap. Can. 117(5): 16(2016).10.1007/978-3-319-41375-4_12 ↗
4. Kouisni, L., Gagné, A., Maki, K., et al., ACS Sustainable Chem. Eng. 4(10): 5152(2016).10.1021/acssuschemeng.6b00907 ↗
5. Öhman, F., Theliander, H., Tomani, P., et al., pat. WO 2006031175 A1 (March 23, 2006).
6. Kouisni, L. and Paleologou, M., pat. US20110297340 A1 (Dec. 8, 2011).
7. Agbor, V.B., Cicek, N., Sparling, R., et al., Biotechnol. Adv. 29(6): 675(2011).10.1016/j.biotechadv.2011.05.005 ↗
8. Diffo Téguia, C., Albers, R., and Stuart, P., TAPPI J. 16(3): 157(2017).10.32964/TJ16.3.157 ↗
9. Holladay, J.E., Bozell, J.J., White, J.F., et al., Top Value-Added Chemicals from Biomass Volume II—Results of Screening for Potential Candidates from Biorefinery Lignin, U.S. Department of Energy, Oak Ridge, TN, USA, 2007.10.2172/921839 ↗
10. Smolarski, N., “High-Value Opportunities for Lignin: Unlocking its Potential,” Frost & Sullivan, San Antonio, TX, USA, 2012. Available [Online] http://www.greenmaterials.fr/wp-content/uploads/2013/01/High-value-Opportunities-for-Lignin-Unlocking-its-Potential-Market-Insights.pdf <12April2017>.
11. LigniMatch, “Future use of lignin in value added products,”Chalmers University of Technology/University of Gothenburg, Gothenburg, Sweden. Available [Online] http://www.gmv.chalmers.gu.se/digitalAssets/1448/1448662_roadmap.pdf <12April2017>.
12. Gosselink, R., “Future perspectives of organosolv lignins,” DLOBIOCORE, Wageningen, Netherlands, 2014. Available [Online] http://www.biocore-europe.org/file/2_1%20BIOCORE%20R%20Gosselink%20DLO%20Organosolv%20lignins.pdf <18April2017>.
13. Wang, M., Leitch, M., and Xu, X., Eur. Polym. J. 45(12): 3380(2009).10.1016/j.eurpolymj.2009.10.003 ↗
14. Çetin, N.S. and Özmen, N., Int. J. Adhes. Adhes. 22(6): 477(2002).
15. Matsushita, Y., J. Wood Sci. 61(3): 230(2015).10.1007/s10086-015-1470-2 ↗
16. Mahmood, N., Yuan, Z., Schmidt, J., et al., Eur. Polym. J. 68:1(2015).10.1016/j.eurpolymj.2015.04.030 ↗
17. Naskar, A.K., “Developing low cost carbon fiber for automotivelightweight composites,” 32nd Annu. Meet. Counc. Chem. Res., Council for Chemical Research, Washington, D.C., 2011.
18. Nordström, Y., Norberg, I., Sjöholm, E., et al., J. Appl. Polym. Sci. 129(3):1274(2013).10.1002/app.38795 ↗
19. Kadla, J.F., Kubo, S., Venditti, R.A., et al., Carbon 40(15):2913(2002).10.1016/S0008-6223(02)00248-8 ↗
20. Norberg, I., “Carbon fibres from kraft lignin,” Ph.D. thesis, KTH Royal Institute of Technology, Stockholm, 2012.
21. Chambost, V., McNutt, J., and Stuart, P.R., Pulp Pap. Can. 109(7): 19(2008).
22. Diffo Téguia, C., Chambost, V., Sanaei, S., et al., in Forest Value ChainOptimization and Sustainability (S. D’Amours, Eds), CRC Press, Boca Raton,FL, USA, 2016, Chap. 3.
23. Archer, N.P. and Ghasemzadeh, F., Int. J. Proj. Manage. 17(4): 207(1999).10.1016/S0263-7863(98)00032-5 ↗
24. Henriksen, A.D. and Traynor, A.J., IEEE Trans. Eng. Manage. 46(2):158(1999).10.1109/17.759144 ↗
25. Verbano, C. and Nosella, A., Eur. J. Innovation Manage. 13(3): 355(2010).10.1108/14601061011060166 ↗
26. Thamhain, H.J., Eng. Manage. J. 6(3): 3(2014).10.1080/10429247.2014.11432015 ↗
27. Papalexandrou, M.A., Pilavachi, P.A., and Chatzimouratidis, A.I., Process Saf. Environ. Prot. 86(5): 360(2008).10.1016/j.psep.2008.03.003 ↗
28. Sacramento-Rivero, J.C., Biofuels Bioprod. Biorefin. 6(1): 32(2012).10.1002/bbb.335 ↗
29. Posada, J.A., Patel, A.D., Roes, A., et al., Bioresour. Technol. 135:490(2013).10.1016/j.biortech.2012.09.058 ↗
30. Niekamp, S., Bharadwaj, U.R., Sadhukhan, J., et al., J. Ind. Prod. Eng. 32(1):23(2015).10.1080/21681015.2014.1000401 ↗
31. Vincke, P., Multicriteria Decision Aid, John Wiley and Sons, New York, 1992.
32. Keeney, R.L. and Raiffa, H., Decisions with Multiple Objectives: Preferences and Value Trade-Offs, Cambridge University Press, New York, 1993.10.1017/cbo9781139174084 ↗
33. Roy, B., Méthodologie multicritère d’aide à la décision, Economica, Paris, 1985.
34. Roy, B. and Bouyssou, D., Aide multicritère à la décision: Méthodes et cas, Economica, Paris, 1993.
35. Hytönen, E. and Stuart, P.R., Pulp Pap. Can. 110(5): T58(2009).
36. International Energy Agency, “World Energy Outlook 2015 -Chapter 1: Introduction and scope,” 2015. Available [Online] http://www.worldenergyoutlook.org/media/weowebsite/2015/WEO2015_Chapter01.pdf <18April2017>.
37. U.S. Energy Information Administration, “Annual Energy Outlook 2015 with Projections to 2040,” 2015. Available [Online] https://www.eia.gov/outlooks/aeo/pdf/0383(2015).pdf <18April2017>.
38. Bouyssou, D., in Readings in Mutiple Criteria Decision Aid (C.A. Bana e Costa,Ed.), Springer Verlag, Berlin, Germany, 1990, pp. 58-80.10.1007/978-3-642-75935-2_4 ↗
39. Quintero-Bermudez, M.A., Janssen, M., Cohen, J., et al., TAPPI J. 11(11):9(2012).10.32964/TJ11.11.9 ↗