journal article·2016-07-01Open access

Critical discussion on the thermal behavior of sulfated cellulose nanocrystals

GREGORY CHAUVE, DAMIEN MAURAN, CAROLE FRASCHINI, JEAN BOUCHARD

TAPPI Journal· Volume 15· Issue 6

Abstract

Cellulose nanocrystals (CNCs) have evolved from a laboratory curiosity to an industrial material manufactured at a scale of up to 1 ton/day. In order to maximize their use in various applications such as composites, it is critical to evaluate the influence of the surface chemistry on their thermal stability. The effect of temperature on native CNCs is heavily damaging to the material integrity, but the early stage temperature-catalyzed degradation process can be prevented by neutralization of the surface sulfate half-ester groups, either by organic or inorganic counterions. In addition, we studied the influence of the hydrolysis conditions on the CNCs’ resistance to elevated temperatures. The observations were carried out by thermogravimetric analysis (TGA). Finally, complementary work regarding color formation when CNCs are exposed to heat is presented.
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Research context

OpenAlex topics: Advanced Cellulose Research Studies · Lignin and Wood Chemistry · Polysaccharides and Plant Cell Walls

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