Estimation of the S/G ratios of the lignins in three widely used North American hardwoods

Sugar maple (Acer saccharum), aspen (Populus tremuloides), and white birch (Betula papyrifera) are three hardwoods that are widely used by the North American pulp and paper industry. Because of their abundance, these species are also likely to be used by some of the biorefinery processes that are being developed. A significant amount of evidence indicates that the syringyl to guaiacyl (S/G) ratio of the lignin in a hardwood is a governing parameter regarding its ease of delignification. Credible data also show that among poplars the S/G ratio of the lignin significantly influences the ease of saccharification of the carbohydrate polymers to sugar monomers. Although the S/G ratio appears to be a key parameter for hardwoods, values accepted by most practitioners are not available for the three species. In this investigation, those ratios were estimated by an extensive literature review followed by S/G determination by nitrobenzene oxidation (NBO) and methoxyl analyses of organosolv lignin (OSL) from the ethanol/ water/sulfuric acid pulping process. The S/G values were approximately 1.4 for sugar maple, and 2.0 for aspen and white birch. Data are also included showing that sugar maple and white birch were equally reactive in kraft pulping. Thus, it is unclear whether or not the S/G ratio is indeed a governing parameter in this delignification process.