journal article·2026-02Open access

Metal–organic frameworks as active layers in molecular electronics: The case of HKUST-1

Tahir Ahmad Mir, Frederic Lafolet, Charlli Betkou, Sarra Gam Derouich, Zakaria Ziani, Jean-Christophe Lacroix

Synthetic Metals· Volume 317

Abstract

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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Supramolecular Chemistry and Complexes · Magnetism in coordination complexes

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References (78)

Show source-provided references
1. The chemistry and applications of metal-organic frameworks10.1126/science.1230444 ↗
2. Metal-organic frameworks10.1039/b200393g ↗
3. Metal–organic framework thin films: review of their room-temperature synthesis and applications10.1039/D3TC04366E ↗
4. Review on metal–organic framework classification, synthetic approaches, and influencing factors: applications in energy, drug delivery, and wastewater treatment10.1021/acsomega.2c05310 ↗
5. Hydrothermal synthesis of a metal-organic framework containing large rectangular channels10.1021/ja00146a033 ↗
6. Construction of porous solids from hydrogen-bonded metal complexes of 1,3,5-Benzenetricarboxylic acid10.1021/ja960746q ↗
7. Establishing microporosity in open metal−organic frameworks: gas sorption isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate)10.1021/ja981669x ↗
8. Hydrogen storage in microporous metal-organic frameworks10.1126/science.1083440 ↗
9. Densified HKUST-1 monoliths as a route to high volumetric and gravimetric hydrogen storage capacity10.1021/jacs.2c04608 ↗
10. Molecular catalysis of energy relevance in metal–organic frameworks: from higher coordination sphere to system effects10.1021/acs.chemrev.2c00587 ↗
11. Metal–organic frameworks as catalysts for organic synthesis: a critical perspective10.1021/jacs.9b00733 ↗
12. Metal–organic frameworks for heterogeneous basic catalysis10.1021/acs.chemrev.7b00091 ↗
13. Metal–organic framework materials as chemical sensors10.1021/cr200324t ↗
14. Luminescent sensors based on metal-organic frameworks10.1016/j.ccr.2017.06.007 ↗
15. Metal-organic frameworks and their derived materials for electrochemical energy storage and conversion: promises and challenges10.1126/sciadv.aap9252 ↗
16. Pristine metal–organic frameworks and their composites for energy storage and conversion
17. Metal–organic framework supercapacitors: challenges and opportunities10.1002/adfm.202308497 ↗
18. Electrically conductive metal–organic frameworks10.1021/acs.chemrev.9b00766 ↗
19. Metal-organic frameworks in semiconductor devices10.1002/anie.202317413 ↗
20. Design strategies for dielectric metal–organic frameworks and their applications in microelectronic devices10.1016/j.ccr.2023.215596 ↗
21. Highly hydrophobic metal–organic framework for self-protecting gate dielectrics10.1039/D0TA00605J ↗
22. Elucidating the correlation between the redox potential, spin state, and crystal structure in a series of ferrous complexes with redox-active ligands10.1002/anie.202506965 ↗
23. Electron-transfer-induced structural modification in a thermochromic hofmann clathrate derivative10.1021/acs.inorgchem.4c04155 ↗
24. Combining electron transfer, spin crossover, and redox properties in metal-organic frameworks10.1038/s41467-024-51385-8 ↗
25. A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n10.1126/science.283.5405.1148 ↗
26. Electrografted monolayer based on a naphthalene diimide–ruthenium terpyridine complex dyad: efficient creation of large-area molecular junctions with high current densities10.1039/C7CC04972B ↗
27. Control of rectification in molecular junctions: contact effects and molecular signature10.1021/jacs.7b05732 ↗
28. Counterions drive memory functionality in two-terminal viologen-based molecular junctions10.1002/smll.202503767 ↗
29. Molecular diodes with rectification ratios exceeding 105 driven by electrostatic interactions10.1038/nnano.2017.110 ↗
30. Controlling the direction of rectification in a molecular diode10.1038/ncomms7324 ↗
31. Molecular rectification in metal−SAM−metal oxide−metal junctions10.1021/ja9048898 ↗
32. Unimolecular electrical rectification in hexadecylquinolinium tricyanoquinodimethanide10.1021/ja971811e ↗
33. Mapping the extended ground state reactivity landscape of a photoswitchable molecule at a single molecular level
34. Unprecedented ON/OFF ratios in photoactive diarylethene-bisthienylbenzene molecular junctions10.1021/acs.nanolett.1c01983 ↗
35. Highly efficient photoswitch in diarylethene-based molecular junctions10.1021/jacs.0c01213 ↗
36. Electrochemically grafted molecular layers as on-chip energy storage molecular junctions10.1039/D4SC04745A ↗
37. Charge disproportionate molecular redox for discrete memristive and memcapacitive switching10.1038/s41565-020-0653-1 ↗
38. Robust resistive memory devices using solution-processable metal-coordinated azo aromatics10.1038/nmat5009 ↗
39. Lacaze · 2014
40. Two-State, Nonvolatile Memristors and Light-Assisted Logic-In Operation from Diarylethene-Based Single-Molecule Junctions10.1021/jacs.5c06991 ↗
41. A Roadmap to Implementing Metal–Organic Frameworks in Electronic Devices: Challenges and Critical Directions10.1002/chem.201101595 ↗
42. Thickness-Dependent Charge Transport in Three Dimensional Ru(II)– Tris(phenanthroline)-Based Molecular Assemblies10.1021/acs.nanolett.3c03256 ↗
43. Coordination-driven opto-electroactive molecular thin films in electronic circuits10.1039/D2TC02238A ↗
44. Direct Patterning of Oriented Metal–Organic Framework Crystals via Control over Crystallization Kinetics in Clear Precursor Solutions10.1002/adma.200903867 ↗
45. Rapid Room-Temperature Synthesis of Metal–Organic Framework HKUST-1 Crystals in Bulk and as Oriented and Patterned Thin Films10.1002/adfm.201002529 ↗
46. HKUST-1 Thin Film Layer-by-Layer Liquid Phase Epitaxial Growth: Film Properties and Stability Dependence on Layer Number10.1021/acs.cgd.5b00384 ↗
47. Inkjet-Printed, Coplanar Electrolyte-Gated Organic Field-Effect Transistors on Flexible Substrates: Fabrication, Modeling, and Applications in Biodetection10.1002/admt.202200300 ↗
48. Unprecedented Self-Organized Monolayer of a Ru(II) Complex by Diazonium Electroreduction10.1021/jacs.6b04827 ↗
49. Statistical analysis of electronic properties of alkanethiols in metal–molecule–metal junctions10.1088/0957-4484/18/31/315204 ↗
50. Upscaling, integration and electrical characterization of molecular junctions10.1038/nnano.2008.305 ↗
51. Smart eutectic gallium–indium: from properties to applications
52. Extreme long-lifetime self-assembled monolayer for air-stable molecular junctions10.1126/sciadv.adh3412 ↗
53. AFM manipulation of EGaIn microdroplets to generate controlled, on-demand contacts on molecular self-assembled monolayers10.1021/acsnano.2c04667 ↗
54. Reversible soft top-contacts to yield molecular junctions with precise and reproducible electrical characteristics10.1002/adfm.201304237 ↗
55. Attachment of organic layers to conductive or semiconductive surfaces by reduction of diazonium salts10.1039/b406228k ↗
56. Grafting π-conjugated oligomers incorporating 3,4-ethylenedioxythiophene (EDOT) and thiophene units on surfaces by diazonium electroreduction10.1021/acs.jpcc.5b05456 ↗
57. Microfabrication and integration of diazonium-based aromatic molecular junctions10.1021/am100833e ↗
58. Musical molecules: the molecular junction as an active component in audio distortion circuits10.1088/0953-8984/28/9/094011 ↗
59. Molecular signature and activationless transport in cobalt-terpyridine-based molecular junctions
60. Electrochemistry does the impossible: robust and reliable large area molecular junctions10.1016/j.coelec.2017.11.017 ↗
61. Bidirectional light-induced conductance switching in molecular wires containing a dimethyldihydropyrene unit10.1039/C7NR09551A ↗
62. Stepwise fabrication of donor/acceptor thin films with a charge-transfer molecular wire motif10.1039/C6CC08310B ↗
63. Advanced analysis of copper X-ray photoelectron spectra10.1002/sia.6239 ↗
64. Cu2 (trz-ia)2]─An ultramicroporous Cu2 paddle wheel triazolyl isophthalate MOF: a comparative study of its properties in dihydrogen adsorption and isotopologue separation10.1021/acs.inorgchem.4c05225 ↗
65. Conducting-polymer electrochemical switching as an easy means for control of the molecular properties of grafted transition metal complexes10.1002/1521-3765(20011203)7:23<5029::AID-CHEM5029>3.0.CO;2-# ↗
66. XPS as a probe for the bonding nature in metal acetates10.1039/D2NJ01905A ↗
67. Adsorption, desorption, and decomposition of formic acid on Cu(977): the importance of facet of the step10.1021/acs.jpcc.2c01948 ↗
68. Local structure of framework Cu(II) in HKUST-1 metallorganic framework: spectroscopic characterization upon activation and interaction with adsorbates10.1021/cm052191g ↗
69. Environmentally Benign synthesis of copper benzenetricarboxylic acid MOF as an Electrocatalyst for overall water splitting and CO2 reduction10.1149/2754-2734/ac6ad5 ↗
70. Effect of graphene type in Cu-BTC/graphene hybrid adsorbents with ultra-low graphene content for hydrogen sulfide removal10.1016/j.jece.2025.117443 ↗
71. Identifying structure and texture of metal–organic framework Cu2 (bdc)2(dabco) thin films by combining X-ray diffraction and quantum mechanical modeling10.1021/acs.cgd.4c01433 ↗
72. HKUST-1 as a positive electrode material for supercapattery10.3390/en16207072 ↗
73. Cu-based metal–organic framework HKUST-1 as effective catalyst for highly sensitive determination of ascorbic acid10.1039/D0RA01260B ↗
74. Charge transfer at partially blocked surfaces10.1016/S0022-0728(83)80055-2 ↗
75. Highly efficient long-range electron transport in a viologen-based molecular junction10.1021/jacs.8b05589 ↗
76. Electric transport properties of surface-anchored metal–organic frameworks and the effect of ferrocene loading10.1021/acsami.5b01792 ↗
77. Activationless charge transport across 4.5–22 nm in molecular electronic junctions10.1073/pnas.1221643110 ↗
78. Experimental and theoretical investigations of the electronic band structure of metal-organic frameworks of HKUST-1 type10.1063/1.4934737 ↗