journal article·2025-09

Semiconducting-to-metallic transition leading to large n -type Seebeck coefficient in a copper thiolate-based coordination polymer

Chloé Andrade, Alexis Giraudon, Régis Debord, Nathalie Guillou, Erik Elkaim, Florent Perret, Thomas Niehaus, Aude Demessence, Stéphane Pailhès

Synthetic Metals· Volume 314
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Abstract

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OpenAlex topics: Magnetism in coordination complexes · Organic and Molecular Conductors Research · Metal-Organic Frameworks: Synthesis and Applications

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References (39)

Show source-provided references
1. High spatiotemporal resolution biomimetic thermoreceptors realizing by jointless p-n integration thermoelectric composites10.1002/adfm.202411490 ↗
2. Toward precision recognition of complex hand motions: Wearable thermoelectrics by synergistic 2D nanostructure confinement and controlled reduction10.1002/adfm.202206083 ↗
3. Hybrid organic–Inorganic thermoelectric materials and devices10.1002/anie.201901106 ↗
4. Thermoelectric porous MOF based hybrid materials10.1063/5.0004699 ↗
5. Minireview: Crystalline organic metal chalcogenides for thermoelectric conversion10.1016/j.coco.2021.100901 ↗
6. A microporous and naturally nanostructured thermoelectric metal-organic framework with ultralow thermal conductivity10.1016/j.joule.2017.07.018 ↗
7. From phonons to the thermal properties of complex thermoelectric crystals: The case of type-i clathrates10.1016/j.rinp.2023.106487 ↗
8. Strategies to improve electrical conductivity in metal–organic frameworks: A comparative study10.1021/acs.cgd.3c01162 ↗
9. Electrically conductive metal–organic frameworks10.1021/acs.chemrev.9b00766 ↗
10. Electrically conductive porous metal–organic frameworks10.1002/anie.201506219 ↗
11. Recent advances of 2D conductive metal–organic frameworks in thermoelectrics10.1039/D4TA01820F ↗
12. Recent progress in designing thermoelectric metal–organic frameworks10.1002/smll.202100505 ↗
13. Two-dimensional conjugated metal–organic frameworks (2D c-MOFs): chemistry and function for moftronics10.1039/D0CS01160F ↗
14. Highly conducting organic–Inorganic hybrid copper sulfides cuxc6s6 (x=4 or 5.5): Ligand-based oxidation-induced chemical and electronic structure modulation10.1002/anie.202009613 ↗
15. 2D single-layer π-conjugated nickel bis(dithiolene) complex: A good-electron-poor-phonon thermoelectric material10.1002/aelm.201800892 ↗
16. A porous, electrically conductive hexa-zirconium(iv) metal–organic framework10.1039/C8SC00961A ↗
17. Connecting wires: Photoinduced electronic structure modulation in metal–organic frameworks10.1021/jacs.8b13853 ↗
18. Pressure-induced metallicity and piezoreductive transition of metal-centres in conductive 2-dimensional metal–organic frameworks10.1039/C9CP04797B ↗
19. Room temperature metallic conductivity in a metal–organic framework induced by oxidation10.1021/jacs.9b06898 ↗
20. Metallic conductivity in a two-dimensional cobalt dithiolene metal–organic framework10.1021/jacs.7b05742 ↗
21. Ag nanoparticles-induced metallic conductivity in thin films of 2d metal–organic framework cu3(HHTP)210.1021/acs.nanolett.3c02522 ↗
22. Synthesis and structure of a non-van-der-waals two-dimensional coordination polymer with superconductivity10.1038/s41467-024-53786-1 ↗
23. Facile synthesis, precise species control and chemical transformation of highly conducting organic metal chalcogenides cuxbht (bht= benzenehexathiol; x=3, 4, and 5.5)10.1039/D1TC03614A ↗
24. Strongly correlated superconductivity in a copper-based metal-organic framework with a perfect kagome lattice10.1126/sciadv.abf3996 ↗
25. Superconductivity in a copper(II)-based coordination polymer with perfect kagome structure10.1002/anie.201707568 ↗
26. Engineering flat and dispersive bands in 2D layered COFs via interlayer stacking and donor–acceptor strategy10.1021/acs.chemmater.3c00510 ↗
27. How the layer alignment in two-dimensional nanoporous covalent organic frameworks impacts its electronic properties10.1021/acsanm.2c02647 ↗
28. A p-type semi-conducting copper (i)-1, 3-benzenedithiolate 2D coordination polymer with high seebeck coefficient10.1039/D3TC02379F ↗
29. Electric conduction in phosphorus doped silicon at low temperatures10.1143/JPSJ.22.859 ↗
30. Electrical properties of heavily doped silicon10.1063/1.1729180 ↗
31. Electrical properties and resonance scattering in heavily doped semiconductors10.1016/0038-1098(64)90286-8 ↗
32. Low-temperature dependence of the electrical resistivity of degenerate n-type germanium10.1103/PhysRevLett.15.828 ↗
33. Peak-fitting of Cu 2p photoemission spectra in Cu0, Cu1+, and Cu2+ oxides: A method for discriminating Cu0 from Cu1+10.1016/j.apsusc.2023.156960 ↗
34. The effects of X-ray irradiation and temperature on the formation and stability of chemical species on enargite surfaces during XPS10.1016/j.mineng.2013.01.009 ↗
35. A concise review on the progression of copper sulfide as a potential thermoelectric material: Synthesis and thermoelectric properties10.1088/2632-959X/ada6e7 ↗
36. Copper deficiency induced varying electronic structure and optoelectronic properties of cu(2-x)s thin films10.1016/j.apsusc.2019.05.235 ↗
37. Electrical conduction and phase transition of copper sulfides10.1143/JJAP.12.1130 ↗
38. Djurleite (Cu 1.94 s) and low chalcocite (Cu 2 s): New crystal structure studies10.1126/science.203.4378.356 ↗
39. Isostructural phase transition by point defect reorganization in the binary type-I clathrate Ba7.5Si4510.1016/j.actamat.2021.116824 ↗