DataVXSynthetic MetalsPaper
journal article·2003-04

Tuning of spin density wave strength of Ni(III) complexes with strong electron-correlation

T. Ono, M. Yamashita, K. Yokoyama, S. Furukawa, T. Manabe, K. Sugiura, T. Ishii, H. Miyasaka, H. Matsuzaki, H. Kishida, H. Okamoto, K. Marumoto, H. Tanaka, Y. Hasegawa, S. Kuroda, H. Itou

Synthetic Metals· Volume 135-136
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Source abstract

Abstract

We have succeeded in synthesizing the Ni III complexes doped by Co III ions, [Ni 1-x Co x (chxn) 2 Br]Br 2 (x=0, 0.044, 0.098, 0.118) by using an electrochemical oxidation method. The reflectance spectrum of [Ni 1-x Co x (chxn) 2 Br]Br 2 shows intense charge transfer bands about 0.5eV, which are lower than that of [Ni(chxn) 2 Br]Br 2 . (1.3eV).
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnetism in coordination complexes · Organic and Molecular Conductors Research · Electron Spin Resonance Studies

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