journal article·2022-11-22

Tuning Interface Mechanics Via β-Configuration Dominant Amyloid Aggregates for Lithium Metal Batteries

Shuaitong Liang, Junping Miao, Haiting Shi, Ming Zeng, Hanwen An, Tianshuai Ma, Tianyu Li, Zhiwei Xu

ACS Nano· Volume 16· Issue 11
Publisher page

Abstract

Owing to abundant polar groups and good lithiophilicity, protein materials regain interest for application in lithium metal batteries (LMBs). Current proteins with an α-conformation for modifying lithium (Li) anodes possess typically poor mechanical properties, and there is therefore a significant need for advanced protein materials. Herein, a lysozyme-modified layer is coated onto the poly(vinylidene fluoride) electrospun mat for high mechanical strength and uniform Li-ion flux. The lysozyme membrane can regulate Li+ deposition behavior due to complete β-sheet configuration, high lithiophilicity sulfhydryl groups, and columnar nanopores. As a result, the lysozyme-modified Li metal anode exhibits a high stability performance of Li–Li symmetric cells (2800 h) and Li-LiFePO4 full cell (1450 cycles). Our strategy pushes the protein with β-sheet configuration toward the applications of next-generation LMBs.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Separation Membranes and Membrane Processes, School of Textiles Science and Engineering, Tiangong University, Tianjin300387, China

International Joint Laboratory of New Textile Materials and Textiles of Henan Province, Zhongyuan University of Technology, Zhengzhou450007, China

State Key Laboratory of Separation Membranes and Membrane Processes, School of Material Science and Engineering, Tiangong University, Tianjin300387, China

MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin150001, China

Funding

National Natural Science Foundation of China

References (41)

Show source-provided references
1. 10.1002/adma.20200072110.1002/adma.202000721 ↗
2. 10.1002/aenm.20200325010.1002/aenm.202003250 ↗
3. 10.1021/jacs.0c0549810.1021/jacs.0c05498 ↗
4. 10.1002/ange.20191099310.1002/ange.201910993 ↗
5. 10.1016/j.cej.2021.13104110.1016/j.cej.2021.131041 ↗
6. 10.1016/j.nanoen.2021.10672010.1016/j.nanoen.2021.106720 ↗
7. 10.1002/adfm.20210293810.1002/adfm.202102938 ↗
8. 10.1002/advs.20210343310.1002/advs.202103433 ↗
9. 10.1002/anie.20210795710.1002/anie.202107957 ↗
10. 10.1002/adfm.20201026110.1002/adfm.202010261 ↗
11. 10.1002/aenm.20200349610.1002/aenm.202003496 ↗
12. 10.1002/adma.20200392010.1002/adma.202003920 ↗
13. 10.1038/srep0705610.1038/srep07056 ↗
14. 10.1002/adfm.20210222810.1002/adfm.202102228 ↗
15. 10.1021/acsnano.7b0208510.1021/acsnano.7b02085 ↗
16. 10.1016/j.ensm.2018.10.01510.1016/j.ensm.2018.10.015 ↗
17. 10.1016/j.jpowsour.2019.02.03310.1016/j.jpowsour.2019.02.033 ↗
18. 10.1002/adfm.20210053710.1002/adfm.202100537 ↗
19. 10.1039/D0TA09753E10.1039/D0TA09753E ↗
20. 10.1038/s41467-020-19246-210.1038/s41467-020-19246-2 ↗
21. 10.1016/j.ensm.2021.07.01010.1016/j.ensm.2021.07.010 ↗
22. 10.1126/sciadv.abb134210.1126/sciadv.abb1342 ↗
23. 10.1002/adma.20180285110.1002/adma.201802851 ↗
24. 10.1038/s41467-018-07888-210.1038/s41467-018-07888-2 ↗
25. 10.1002/adma.20210418710.1002/adma.202104187 ↗
26. 10.1002/adma.20180337710.1002/adma.201803377 ↗
27. 10.1039/C7RA11968B10.1039/C7RA11968B ↗
28. 10.1021/acsnano.1c0449310.1021/acsnano.1c04493 ↗
29. 10.1038/s41563-020-0655-210.1038/s41563-020-0655-2 ↗
30. 10.1002/adfm.20170583810.1002/adfm.201705838 ↗
31. 10.1016/j.chempr.2020.07.01410.1016/j.chempr.2020.07.014 ↗
32. 10.1002/aenm.20180235210.1002/aenm.201802352 ↗
33. 10.1002/anie.20170684310.1002/anie.201706843 ↗
34. 10.1002/aenm.20180393510.1002/aenm.201803935 ↗
35. 10.1039/C7BM01124E10.1039/C7BM01124E ↗
36. 10.1016/j.ensm.2020.10.01710.1016/j.ensm.2020.10.017 ↗
37. 10.1002/ange.20170209910.1002/ange.201702099 ↗
38. 10.1038/s41467-020-16824-210.1038/s41467-020-16824-2 ↗
39. 10.1016/j.matt.2020.10.01410.1016/j.matt.2020.10.014 ↗
40. 10.1016/j.electacta.2019.13469610.1016/j.electacta.2019.134696 ↗
41. 10.1021/acsenergylett.9b0134710.1021/acsenergylett.9b01347 ↗