journal article·2017-08-22Open access

How the Toughest Inorganic Fullerene Cages Absorb Shockwave Pressures in a Protective Nanocomposite: Experimental Evidence from Two In Situ Investigations

Fang Xu, Takamichi Kobayashi, Zhuxian Yang, Toshimori Sekine, Hong Chang, Nannan Wang, Yongde Xia, Yanqiu Zhu

ACS Nano· Volume 11· Issue 8

Abstract

High Resolution Image Download MS PowerPoint Slide Nanocomposites fabricated using the toughest caged inorganic fullerene WS 2 (IF-WS 2 ) nanoparticles could offer ultimate protection via absorbing shockwaves; however, if the IF-WS 2 nanomaterials really work, how they behave and what they experience within the nanocomposites at the right moment of impact have never been investigated effectively, due to the limitations of existing investigation techniques that are unable to elucidate the true characteristics of high-speed impacts in composites. We first fabricated Al matrix model nanocomposites and then unlocked the exact roles of IF-WS 2 in it at the exact moment of impact, at a time resolution that has never been attempted before, using two in situ techniques. We find that the presence of IF-WS 2 reduced the impact velocity by over 100 m/s and in pressure by at least 2 GPa against those Al and hexagonal WS 2 platelet composites at an impact speed of 1000 m/s. The IF-WS 2 composites achieved an intriguing inelastic impact and outperformed other reference composites, all originating from the “balloon effect” by absorbing the shockwave pressures. This study not only provides fundamental understanding for the dynamic performance of composites but also benefits the development of protective nanocomposite engineering.
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Research context

OpenAlex topics: Energetic Materials and Combustion · Diamond and Carbon-based Materials Research · High-Velocity Impact and Material Behavior

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

CEMPS, University of Exeter, Exeter EX4 4QF, United Kingdom

Faculty of Engineering, The University of Nottingham, Nottingham NG7 2RD, United Kingdom

National Institute for Materials Science, Tsukuba, Ibaraki 305-0044, Japan

Department of Earth and Planetary Systems Science, Hiroshima University, Higashi-Hiroshima 739-8526, Japan

Centre for High Pressure Science and Technology Advanced Research, Shanghai 201203, People’s Republic of China

Funding

Engineering and Physical Sciences Research Council

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