Platinum(II) Complex with S=1/2 Organic Radical Ligand
Source abstract
Abstract
A platinum(II) complex with organic radical ligand p-NNpy (=2-(4'-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) is synthesized. X-ray crystallographic analysis revealed that it has a square-planer four-coordinate anionic structure with formula of [Pt(p-NNpy)Cl 3 ] - . Paramagnetic behavior which correspond to S=1/2 was observed with weak intermolecular antiferromagnetic interaction in the temperature range of 2-300 K. The structure, magnetic property and spectroscopic data will be reported.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Magnetism in coordination complexes · Metal complexes synthesis and properties · Thermal and Kinetic Analysis
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