journal article·2003-04

Hydroiminonitroxide Complexes with Metal Hexafluoroacetylacetonates

Tomoaki Ise, Takayuki Ishida, Takashi Nogami

Synthetic Metals· Volume 137· Issue 1-3
Publisher page

Abstract

Hybrid metal-radical magnetic solids, Cu(hfac) 2 .HIN (1) and Mn(hfac) 2 .HIN (2) were synthesized, where HIN denotes 4,4,5,5-tetramethylimidazolin-1-oxyl. X-ray diffraction measurements of 1 and 2 showed 1-dimensional metal-radical alternating chain structures. Magnetic data of 1 and 2 could be analyzed by 1-D ferro- and ferrimagnetic chain models, respectively.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnetism in coordination complexes · Electron Spin Resonance Studies · Metal-Catalyzed Oxygenation Mechanisms

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