journal article·2001-03

Density wave-like charge dynamics in conducting polypyrrole

Kwanghee Lee, Reghu Menon, A.J. Heeger

Synthetic Metals· Volume 119· Issue 1-3
Publisher page

Abstract

Reflectance spectra of polypyrrole (PPy) doped with PF 6 , obtained at 250K and below, show the formation of a peak in the joint density of states at 110 cm -1 and an associated redistribution of oscillator strength. In addition, a Fano-like resonance is observed at 70 cm -1 . We discuss the results in terms of a transition to a density-wave ground state characterized by an energy gap (2Δ/hc 100 cm -1 ) and a pinned collective mode (at 70 cm -1 ).
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Research context

OpenAlex topics: Conducting polymers and applications · Analytical Chemistry and Sensors · Electrochemical Analysis and Applications

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