A synthetic study of a homospin diradical based on 6-oxophenalenoxyl
Source abstract
Abstract
A novel homospin diradical, 8,8'-bis(2,5-di-tert-butyl-6-oxophenalenoxyl) was designed based on 6-oxophenalenoxyl. A diradical precursor, an 8,8'-bis(6-hydroxyphenalenone) derivative was synthesized by the coupling reaction of the lithium enolate of phenalanone derivative as a key step. The monoradical of the precursor was generated and characterized in terms of ESR/ 1 H-ENDOR/TRIPLE measurements and the DFT calculations.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Molecular spectroscopy and chirality · Axial and Atropisomeric Chirality Synthesis · Electron Spin Resonance Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References
Reference metadata was not supplied for this record.