129I Mössbauer spectroscopic study of a one-dimensional halogen-bridged binuclear complex, Pt2(dtp)4I (dtp=C2H5CS2-)
Source abstract
Abstract
129 I Mossbauer spectroscopic measurement was made for the title complex to investigate the insulating phase below a metal-insulator transition (T M-1 = 205 K). Two chemically independent sites of iodine were observed, suggesting that the insulating phase is in alternate charge-polarization state of -Pt 2+ -Pt 3+ -I-Pt 3+ -Pt 2+ -I-Pt 2+ -Pt 3+ -I-Pr 3+ -Pt 2+ -I-.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Magnetism in coordination complexes · Organic and Molecular Conductors Research · Advanced Chemical Physics Studies
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