Small-Angle Rotation in Individual Colloidal CdSe Quantum Rods

CdSe quantum rods (QRs) are very promising novel materials with unique electronic and optical properties. In this paper, we utilize a broad spectrum of techniques including high-resolution annular dark field scanning transmission electron microscope imaging, electron nanodiffraction, and computer simulations to study the internal structure of individual QRs. Random small-angle rotations are commonly found between various sections within individual QRs which can be resolved into twists around the c-axis and bends. The possible origins of these small-angle rotations are further studied. We propose that imperfect oriented attachment coupled with electrostatic interactions between smaller nanoparticles during the growth process results in such small-angle rotations. These small-angle rotations may significantly affect the electronic and mechanical properties of CdSe QRs.