journal article·2016-05-24Open access

Mapping Buried Hydrogen-Bonding Networks

John C. Thomas, Dominic P. Goronzy, Konstantin Dragomiretskiy, Dominique Zosso, Jérôme Gilles, Stanley J. Osher, Andrea L. Bertozzi, Paul S. Weiss

ACS Nano· Volume 10· Issue 5

Abstract

We map buried hydrogen-bonding networks within self-assembled monolayers of 3-mercapto-N-nonylpropionamide on Au{111}. The contributing interactions include the buried S-Au bonds at the substrate surface and the buried plane of linear networks of hydrogen bonds. Both are simultaneously mapped with submolecular resolution, in addition to the exposed interface, to determine the orientations of molecular segments and directional bonding. Two-dimensional mode-decomposition techniques are used to elucidate the directionality of these networks. We find that amide-based hydrogen bonds cross molecular domain boundaries and areas of local disorder.
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Research context

OpenAlex topics: Molecular Junctions and Nanostructures · Surface Chemistry and Catalysis · Spectroscopy and Quantum Chemical Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, California 90095, United States

California NanoSystems Institute, University of California, Los Angeles, Los Angeles, California 90095, United States

Department of Mathematics, University of California, Los Angeles, Los Angeles, California 90095, United States

Department of Mathematics and Statistics, San Diego State University, San Diego, California 92182, United States

Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles, California 90095, United States

Funding

Basic Energy Sciences · University of California, Los Angeles · W.M. Keck Foundation

References (53)

Show source-provided references
1. 10.1021/cr950235710.1021/cr9502357 ↗
2. 10.1021/cr030078910.1021/cr0300789 ↗
3. 10.1021/ar800144310.1021/ar8001443 ↗
4. 10.1039/C2CS35365B10.1039/C2CS35365B ↗
5. 10.1039/b907301a10.1039/b907301a ↗
6. 10.1021/nl501081q10.1021/nl501081q ↗
7. 10.1021/acsnano.5b0121110.1021/acsnano.5b01211 ↗
8. 10.1126/science.262.5138.142510.1126/science.262.5138.1425 ↗
9. 10.1021/j100058a00810.1021/j100058a008 ↗
10. 10.1021/cr970110x10.1021/cr970110x ↗
11. 10.1126/science.106029410.1126/science.1060294 ↗
12. 10.1126/science.112488110.1126/science.1124881 ↗
13. 10.1021/nn103298x10.1021/nn103298x ↗
14. 10.1126/science.120083010.1126/science.1200830 ↗
15. 10.1103/RevModPhys.84.134310.1103/RevModPhys.84.1343 ↗
16. 10.1021/la00011a03310.1021/la00011a033 ↗
17. 10.1021/ja980027710.1021/ja9800277 ↗
18. 10.1021/ja990101110.1021/ja9901011 ↗
19. 10.1021/jp010854l10.1021/jp010854l ↗
20. 10.1021/jp003512910.1021/jp0035129 ↗
21. 10.1021/ja038622i10.1021/ja038622i ↗
22. 10.1021/ja055787d10.1021/ja055787d ↗
23. 10.1021/jp106211y10.1021/jp106211y ↗
24. 10.1126/science.280.5370.173210.1126/science.280.5370.1732 ↗
25. 10.1103/PhysRevB.61.R1634710.1103/PhysRevB.61.R16347 ↗
26. 10.1021/ar068021710.1021/ar0680217 ↗
27. 10.1021/nn900411n10.1021/nn900411n ↗
28. 10.1021/nn901030x10.1021/nn901030x ↗
29. 10.1021/acsnano.5b0132910.1021/acsnano.5b01329 ↗
30. 10.1021/nn502864210.1021/nn5028642 ↗
31. 10.1126/science.124260310.1126/science.1242603 ↗
32. 10.1103/PhysRevB.37.1039510.1103/PhysRevB.37.10395 ↗
33. 10.1021/jp044186q10.1021/jp044186q ↗
34. 10.1021/ja408550a10.1021/ja408550a ↗
35. 10.1039/c3tb20193g10.1039/c3tb20193g ↗
36. 10.1002/cmdc.20120051210.1002/cmdc.201200512 ↗
37. 10.1073/pnas.080612910510.1073/pnas.0806129105 ↗
38. 10.1021/ar00172a00510.1021/ar00172a005 ↗
39. 10.1002/1521-3773(20020104)41:1<48::AID-ANIE48>3.0.CO;2-U10.1002/1521-3773(20020104)41:1<48::AID-ANIE48>3.0.CO;2-U ↗
40. 10.1126/science.122177410.1126/science.1221774 ↗
41. 10.1021/j100785a01010.1021/j100785a010 ↗
42. 10.1021/ja00074a00410.1021/ja00074a004 ↗
43. 10.1021/nl202728j10.1021/nl202728j ↗
44. 10.1063/1.114900010.1063/1.1149000 ↗
45. 10.1109/TSP.2013.228867510.1109/TSP.2013.2288675 ↗
46. Dragomiretskiy K. · 2015 · 197
47. 10.1098/rspa.1998.019310.1098/rspa.1998.0193 ↗
48. 10.1109/TCOM.1981.109495010.1109/TCOM.1981.1094950 ↗
49. 10.2172/89846010.2172/898460 ↗
50. 10.1021/ja807648g10.1021/ja807648g ↗
51. 10.1021/acs.accounts.6b0003410.1021/acs.accounts.6b00034 ↗
52. 10.1021/cr960074m10.1021/cr960074m ↗
53. 10.1021/ja049113z10.1021/ja049113z ↗