journal article·2002-04-01

Structure and Ferromagnetism in Mn4+ Spinels: AM0.5Mn1.5O4 (A = Li, Cu; M = Ni, Mg)

W. Branford, M. A. Green, D. A. Neumann

Chemistry of Materials· Volume 14· Issue 4
Publisher page

Abstract

The structure and electronic properties of a series of Mn IV spinel oxides, with the general formula, AM 0.5 Mn 1.5 O 4 (A = Li, Cu; M = Ni, Mg), are investigated. These materials form an interesting analogy to pyrochlore structures that show colossal magnetoresistance properties. Studies of all the compounds show spontaneous magnetization at a well-defined transition temperature and their semiconducting nature.
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Research context

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Advanced Condensed Matter Physics · Multiferroics and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Davy Faraday Research Laboratory, Royal Institution of Great Britain, 21 Albemarle Street, London, W1X 4BS United Kingdom, and Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ United Kingdom

Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899

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