Holey Graphene as a Weed Barrier for Molecules
Source abstract
Abstract
We demonstrate the use of "holey" graphene as a mask against molecular adsorption. Prepared porous graphene is transferred onto a Au{111} substrate, annealed, and then exposed to dilute solutions of 1-adamantanethiol. In the pores of the graphene lattice, we find islands of organized, self-assembled molecules. The bare Au in the pores can be regenerated by postdeposition annealing, and new molecules can be self-assembled in the exposed Au region. Graphene can serve as a robust, patternable mask against the deposition of self-assembled monolayers.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Graphene research and applications · Molecular Junctions and Nanostructures · Surface Chemistry and Catalysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Materials and Process Simulation Center and ‡Department of Biological Engineering, California Institute of Technology, Pasadena, California 91125, United States
Department of Chemistry and Biochemistry and California NanoSystems Institute and ⊥Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles, California 90095, United States
Department of Chemistry, and #Department of Materials Science, Chemistry, California Institute of Technology, Pasadena, California 91125, United States
Funding
Division of Emerging Frontiers in Research and Innovation · University of California, Los Angeles · Caltech EAS Discovery Fund
References (71)
Show source-provided references
1. 10.1126/science.110289610.1126/science.1102896 ↗
2. 10.1021/cr900070d10.1021/cr900070d ↗
3. 10.1021/nl801457b10.1021/nl801457b ↗
4. 10.1016/j.carbon.2013.05.05210.1016/j.carbon.2013.05.052 ↗
5. 10.1021/nn203507y10.1021/nn203507y ↗
6. 10.1021/nn304058810.1021/nn3040588 ↗
7. 10.1021/nn401435610.1021/nn4014356 ↗
8. 10.1021/ja804409f10.1021/ja804409f ↗
9. 10.1021/nl102069z10.1021/nl102069z ↗
10. 10.1021/nl101046t10.1021/nl101046t ↗
11. 10.1038/nature0937910.1038/nature09379 ↗
12. 10.1038/nnano.2010.19810.1038/nnano.2010.198 ↗
13. 10.1021/nl301285310.1021/nl3012853 ↗
14. 10.1007/BF0335375710.1007/BF03353757 ↗
15. 10.1021/cr950235710.1021/cr9502357 ↗
16. 10.1021/cr960074m10.1021/cr960074m ↗
17. 10.1016/j.progsurf.2003.12.00110.1016/j.progsurf.2003.12.001 ↗
18. 10.1021/cr030078910.1021/cr0300789 ↗
19. 10.1039/C2CS35365B10.1039/C2CS35365B ↗
20. 10.1126/science.106029410.1126/science.1060294 ↗
21. 10.1002/adma.20070008210.1002/adma.200700082 ↗
22. 10.1021/ar800144310.1021/ar8001443 ↗
23. 10.1021/cr030076o10.1021/cr030076o ↗
24. 10.1021/nn700079910.1021/nn7000799 ↗
25. 10.1021/nn800410c10.1021/nn800410c ↗
26. 10.1088/0034-4885/73/3/03650110.1088/0034-4885/73/3/036501 ↗
27. 10.1126/science.122177410.1126/science.1221774 ↗
28. 10.1021/la302943t10.1021/la302943t ↗
29. 10.1039/C1CS15193B10.1039/C1CS15193B ↗
30. 10.1063/1.298051810.1063/1.2980518 ↗
31. Jin Z. · 2009 · 6 · 53
32. 10.1038/nnano.2010.810.1038/nnano.2010.8 ↗
33. 10.1021/nl200369r10.1021/nl200369r ↗
34. 10.1021/jp303265d10.1021/jp303265d ↗
35. 10.1021/nn401794k10.1021/nn401794k ↗
36. 10.1021/nn305358210.1021/nn3053582 ↗
37. 10.1021/nn502635y10.1021/nn502635y ↗
38. 10.1021/nl503159d10.1021/nl503159d ↗
39. 10.1063/1.492162010.1063/1.4921620 ↗
40. 10.1021/ja049113z10.1021/ja049113z ↗
41. 10.1021/ja047233110.1021/ja0472331 ↗
42. 10.1021/jp066355810.1021/jp0663558 ↗
43. 10.1038/nchem.157210.1038/nchem.1572 ↗
44. 10.1021/nl070613a10.1021/nl070613a ↗
45. 10.1021/nl100840z10.1021/nl100840z ↗
46. 10.1088/0957-4484/21/1/01570510.1088/0957-4484/21/1/015705 ↗
47. 10.1021/nn203377t10.1021/nn203377t ↗
48. 10.1021/jp044186q10.1021/jp044186q ↗
49. 10.1021/nn901030x10.1021/nn901030x ↗
50. 10.1021/nn103298x10.1021/nn103298x ↗
51. 10.1021/ja982157l10.1021/ja982157l ↗
52. 10.1103/PhysRevB.79.19542510.1103/PhysRevB.79.195425 ↗
53. 10.1088/1367-2630/14/5/05300810.1088/1367-2630/14/5/053008 ↗
54. 10.1021/ja035036g10.1021/ja035036g ↗
55. 10.1021/ja042621o10.1021/ja042621o ↗
56. 10.1021/jp065369a10.1021/jp065369a ↗
57. 10.1021/jp065368i10.1021/jp065368i ↗
58. 10.1021/ja071116z10.1021/ja071116z ↗
59. 10.1021/ja026214t10.1021/ja026214t ↗
60. 10.1021/jp980175j10.1021/jp980175j ↗
61. 10.1063/1.47930210.1063/1.479302 ↗
62. 10.1038/ncomms170210.1038/ncomms1702 ↗
63. 10.1021/nn201207c10.1021/nn201207c ↗
64. 10.1021/nn301207d10.1021/nn301207d ↗
65. 10.1016/j.carbon.2013.01.01110.1016/j.carbon.2013.01.011 ↗
66. 10.1021/nn503283d10.1021/nn503283d ↗
67. 10.1021/nn502864210.1021/nn5028642 ↗
68. 10.1021/nn504901410.1021/nn5049014 ↗
69. 10.1021/acsnano.5b0367610.1021/acsnano.5b03676 ↗
70. 10.1021/nl500999r10.1021/nl500999r ↗
71. 10.1021/nn800673d10.1021/nn800673d ↗