journal article·2022-07

Fluoride-ion batteries: State-of-the-art and future perspectives

Sumol V. Gopinadh, Peddinti V.R.L. Phanendra, Bibin John, T.D. Mercy

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Abstract

The ever-growing demand for efficient energy storage devices has prompted researchers to explore alternative systems which are capable of providing better performance than the currently used Li-ion battery (LIB) technology. Recently, the most electronegative fluoride ion mediated reversible batteries are identified to outperform today`s LIBs, particularly in terms of energy density. With suitable electrode and electrolyte combinations, Fluoride Ion Batteries (FIBs) can theoretically provide volumetric energy density more than eight times the energy density of current LIBs. However, FIBs are still at the infancy stage of development and vast improvements need to be done concerning the performance of the electrode, as well as the electrolyte. This review deals with various aspects of FIBs including electrode materials, electrolytes, performance characteristics, challenges and advances in FIBs.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Inorganic Fluorides and Related Compounds · Advanced Battery Materials and Technologies · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (74)

Show source-provided references
1. Potassium intercalation into graphite to realize high-voltage/high-power potassium-ion batteries and potassium-ion capacitors10.1016/j.elecom.2015.09.002 ↗
2. Porous carbon composites for next generation rechargeable lithium batteries10.1002/aenm.201700283 ↗
3. Current progress achieved in novel materials for supercapacitor electrodes: Mini review10.1039/C9NA00345B ↗
4. Strategies to reach ultrahigh capacitance values for supercapacitors: materials design10.3906/fiz-2104-14 ↗
5. Potassium-ion batteries: key to future large-scale energy storage?10.1021/acsaem.0c01574 ↗
6. Lithium-ion batteries: outlook on present, future, and hybridized technologies10.1039/C8TA10513H ↗
7. A journey through layered cathode materials for lithium ion cells – from lithium cobalt oxide to lithium-rich transition metal oxides10.1016/j.jallcom.2021.159239 ↗
8. Synthesis of Li1.5Ni0.25Mn0.75O2.5 cathode material via carbonate co-precipitation method and its electrochemical properties10.1016/j.inoche.2020.108434 ↗
9. Promising anode material for lithium-ion cells based on cobalt oxide synthesized by microwave heating10.1007/s11581-017-2015-z ↗
10. Sn/Al2O3/C/CNT composite prepared by wet milling as anode material for lithium-ion cells10.1016/j.jsamd.2017.04.003 ↗
11. Synthesis, characterisation and electrochemical evaluation of lithium titanate anode for lithium ion cells
12. Nano energy fluoride ion batteries : designing flexible M2CH2 (M ¼ Ti or V) MXenes as high-capacity cathode materials10.1016/j.nanoen.2020.104911 ↗
13. Recent progress of emerging cathode materials for sodium ion batteries10.1039/D1QM00179E ↗
14. Fluoride ion batteries: theoretical performance, safety, toxicity, and a combinatorial screening of new electrodes10.1016/j.jfluchem.2015.12.002 ↗
15. Room-temperature cycling of metal fluoride electrodes: liquid electrolytes for high-energy fluoride ion cells10.1126/science.aat7070 ↗
16. LaSrMnO4 : Reversible electrochemical intercalation of fluoride ions in the context of fluoride ion batteries10.1021/acs.chemmater.6b05075 ↗
17. Conductivity optimization of Tysonite-type La1-xBaxF3-x solid electrolytes for advanced fluoride ion battery10.1021/acsami.7b04936 ↗
18. Parametric investigation of room-temperature fluoride-ion batteries: assessment of electrolytes, Mg-based anodes, and BiF3-cathodes10.1039/C4TA06625A ↗
19. Batteries based on fluoride shuttle10.1039/c1jm13535j ↗
20. Study of all solid-state rechargeable fluoride ion batteries based on thin-film electrolyte10.1007/s10008-016-3479-x ↗
21. Molaiyan · 2020
22. Modified coin cells to evaluate the electrochemical properties of solid-state fluoride-ion batteries at 150 °C10.1016/j.jfluchem.2016.09.006 ↗
23. Aqueous rechargeable dual-ion battery based on fluoride ion and sodium ion electrochemistry10.1039/C8TA01525B ↗
24. Mechanical synthesis and structural properties of the fast fluoride-ion conductor PbSnF410.1016/j.jssc.2017.06.007 ↗
25. La2CoO4: a new intercalation based cathode material for fluoride ion batteries with improved cycling stability10.1039/C7TA09427B ↗
26. Fluoride-ion conductors
27. I. Darolles, C.M. Wiess, M. M. Alam, A. Tiruvannamalai, S.C.Jones, Fluoride Ion Battery Compositions, US Patent 9,166,249 B2, Oct. 20, 2015.
28. Development of tysonite-type fluoride conducting thin film electrolytes for fluoride ion batteries10.1016/j.ssi.2014.12.010 ↗
29. CuF2 as reversible cathode for fluoride ion batteries10.1002/adfm.201701051 ↗
30. Electrochemical performance of a bismuth fluoride electrode in a reserve-type fluoride shuttle battery10.1149/2.0931714jes ↗
31. High cycle life all-solid-state fluoride ion battery with La2NiO4+d high voltage cathode10.1038/s43246-020-0030-5 ↗
32. Fluoride ion batteries - past, present, and future10.1039/D0TA11656D ↗
33. Electrochemical reactions in fluoride-ion batteries: mechanistic insights from pair distribution function analysis10.1039/C7TA04005A ↗
34. Improved electrochemical performances in a bismuth fluoride electrode prepared using a high energy ball mill with carbon for fluoride shuttle batteries10.1016/j.jelechem.2019.03.028 ↗
35. Electrochemical performance of BiF3-BaF2 solid solution with three different phases on a fluoride shuttle battery system10.1002/slct.202000713 ↗
36. SnF2-based fluoride ion electrolytes MSnF4 (M= Ba, Pb) for the application of room-temperature solid-state fluoride ion batteries
37. Reactivity and mechanisms in fluoride shuttle battery reactions: difference between orthorhombic and cubic BiF3 single microparticles10.1021/acsaem.9b01803 ↗
38. Evolution of reactions of a fluoride shuttle battery at the surfaces of BiF3 microclusters studied by in situ Raman microscopy10.1002/cssc.201802209 ↗
39. Reversible charge/discharge reaction of a ternary metal fluoride, Pb2 CuF6 : A highly conductive cathode material for fluoride-ion batteries10.1021/acsaem.1c03375 ↗
40. Reversible and fast (De) fluorination of high-capacity Cu2O cathode : one step toward practically applicable all-solid-state fluoride-ion battery10.1002/aenm.202102285 ↗
41. Synthesis of fast fluoride-ion-conductive fluorite-type Ba1-xSbxF2+x (0.1 ≤ x ≤0.4): a potential solid electrolyte for fluoride-ion batteries10.1021/acsami.8b04108 ↗
42. Understanding the reaction mechanism and performances of 3d transition metal cathodes for all-solid-state fluoride ion batteries10.1039/D0TA08824B ↗
43. Fluoride-ion shuttle battery with high volumetric energy density10.1021/acs.chemmater.0c04570 ↗
44. Development of new anode composite materials for fluoride ion batteries10.1039/C4TA02840F ↗
45. A fluoride-doped PEG matrix as an electrolyte for anion transportation in a roomerature fluoride ion battery10.1039/C3TA13881J ↗
46. Electrochemical performance of all solid-state fluoride-ion batteries based on thin-film electrolyte using alternative conductive additives and anodes10.1007/s10008-017-3838-2 ↗
47. Initiating a room-temperature rechargeable aqueous fluoride-ion battery with long lifespan through a rational buffering phase design10.1002/aenm.202003714 ↗
48. Development of solid-state Fluoride-ion Batteries : cell design, electrolyte characterization and electrochemical mechanisms
49. Reversible room-temperature fluoride-ion insertion in a tunnel-structured transition metal oxide host10.1021/acsenergylett.0c01328 ↗
50. A new Bi0.7Fe1.3O1.5F1.7phase: crystal structure, magnetic properties, and cathode performance in fluoride-ion batteries10.1063/5.0005817 ↗
51. Electrochemical fluorination of perovskite type BaFeO2.510.1039/C4DT02485K ↗
52. Anion substitution at apical sites of Ruddlesden-popper-type cathodes toward high power density for all-solid-state fluoride-ion batteries10.1021/acs.chemmater.1c03189 ↗
53. Charge-discharge behavior of fluorine-intercalated graphite for the positive electrode of fluoride ion shuttle battery10.1016/j.elecom.2019.106626 ↗
54. ZnO and MXenes as electrode materials for supercapacitor devices10.3762/bjnano.12.4 ↗
55. Synthesis and structure of the new oxide fluoride Sr2TiO3F2 from the low temperature fluorination of Sr2TiO4: an example of a staged fluorine substitution/insertion reaction10.1039/b106574m ↗
56. Developing intercalation based anode materials for fluoride-ion batteries: topochemical reduction of Sr2TiO3F2 via a hydride based defluorination process10.1039/C8TA01012A ↗
57. Nanostructured fluorite-type fluorides as electrolytes for fluoride ion batteries10.1021/jp3117825 ↗
58. Preparation and performance of Eu3+-doped BaSnF4-based solid-state electrolytes for room-temperature fluoride-ion batteries10.1021/acssuschemeng.1c04523 ↗
59. Crystal phase and surface defect driven synthesis of Pb1 − x Snx F2 solid solution electrolyte for fluoride ion batteries10.1016/j.jelechem.2019.04.063 ↗
60. Superionic conductivity of the heterovalent solid solutions R1-xMxF3-x (R=REE, M=Ca, Ba) with tysonite-type structure10.1134/1.1131083 ↗
61. Electronic conductivity in La1−xBaxF3−x crystals10.1016/0167-2738(84)90031-6 ↗
62. Solid electrolytes for fluoride ion batteries: ionic conductivity in polycrystalline tysonite-type fluorides10.1021/am4052188 ↗
63. Fluoride-ion batteries: on the electrochemical stability of nanocrystalline La0.9Ba0.1F2.9 against metal electrodes10.3390/nano9111517 ↗
64. Experimental visualization of interstitialcy diffusion pathways in fast-fluoride-ion-conducting solid electrolyte Ba0.6La0.4F2.410.1021/acsaem.9b02494 ↗
65. Exploring efficient solid electrolyte based on Nd doped BaSnF4 for fluoride-ion batteries at atomic scale10.1016/j.jpowsour.2021.230718 ↗
66. Room temperature fluoride ion conductivity in defective β-KSb1-δF4-3δ polycrystals
67. Fluoride-ion conductivity analysis of Yb-F-S multiple-anion compounds10.1246/cl.200659 ↗
68. I. Darolles, C.M. Wiess, M. M. Alam, A. Tiruvannamalai, S.C.Jones, Fluoride Ion Battery Compositions, US Patent 2012/0164541 A1, Jun. 28, 2012.
69. H. Nakamoto, J. Yamaki, Z. Ogumi, Method for manufacturing fluoride ion conducting electrolyte solution and method for manufacturing fluoride ion battery, US Patent 10,622,679 B2, Apr. 14, 2020.
70. Improvement of cycling performance in bismuth fluoride electrodes by controlling electrolyte composition in fluoride shuttle batteries10.1007/s10800-018-1241-z ↗
71. Lactone-based liquid electrolytes for fluoride shuttle batteries10.1149/1945-7111/abdaff ↗
72. Fluoride shuttle batteries: on the performance of the BiF3 electrode in organic liquid electrolytes containing a mixture of lithium bis(oxalato)borate and triphenylboroxin10.1016/j.ssi.2020.115499 ↗
73. Electrolytes for room-temperature rechargeable fluoride shuttle batteries10.1021/acsaem.1c03623 ↗
74. Okazaki · 2017 · 2 · 1460