Photocatalytic Initiation of Radical Thiol–ene Reactions Using Carbon-Bi2O3 Nanocomposites
Source abstract
Abstract
A mild, inexpensive, and general photocatalytic initiation protocol for anti-Markovnikov hydrothiolation of olefins using carbon nanomaterial/metal oxide (carbon NM-MO) composites is reported. Graphene oxide (GO), nanodiamonds (ND), and carbon nano-onions (CNO) displaying bismuth or tungsten oxide nanoparticles adhered to the surface and function as highly efficient photocatalysts for thiol–ene ligation under both UV and visible-light-mediated conditions. The straightforward catalyst preparation, excellent overall yields, ease of purification, and broad substrate scope render this a highly versatile method for bioconjugation.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advanced Photocatalysis Techniques · Sulfur-Based Synthesis Techniques · Polyoxometalates: Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Nano Carbon Materials, Istituto Italiano di Tecnologia (IIT), Via Livorno 60, Turin 10144, Italy
Department of Chemistry and Industrial Chemistry, University of Genoa, via Dodecaneso 31, Genoa 16145, Italy
School of Chemistry and Trinity Biomedical Sciences Institute (TBSI), Trinity College Dublin, The University of Dublin, Dublin 2, Ireland
Department of Chemistry, University of Turin, Via Giuria 7, Turin 10125, Italy
Funding
Science Foundation Ireland · Istituto Italiano di Tecnologia
References (49)
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