DataVXACS NanoPaper
journal article·2019-06-25

Tip-Induced Control of Charge and Molecular Bonding of Oxygen Atoms on the Rutile TiO2 (110) Surface with Atomic Force Microscopy

Yuuki Adachi, Huan Fei Wen, Quanzhen Zhang, Masato Miyazaki, Yasuhiro Sugawara, Hongqian Sang, Ján Brndiar, Lev Kantorovich, Ivan Štich, Yan Jun Li

ACS Nano· Volume 13· Issue 6
Publisher page
Source abstract

Abstract

(110)-(1 × 1) surface. The reaction is activated by charge transfer from two sources, natural surface/subsurface polarons and experimental Kelvin probe force spectroscopy as a tool for electronic charge manipulation with single electron precision. We demonstrate a complete control over the oxygen species not attainable previously, allowing us to deliberately discriminate in favor of charge or bond manipulation, using either direct charge injection/removal through the tip-oxygen adatom junction or indirectly via polarons. Comparing our ab initio calculations with experiment, we speculate that we may have also manipulated the spin on the oxygens, allowing us to deal with the singlet/triplet complexities associated with the oxygen molecule formation. We show that the manipulation outcome is fully governed by three experimental parameters, vertical and lateral tip positions and the bias voltage.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Force Microscopy Techniques and Applications · Electronic and Structural Properties of Oxides · Surface and Thin Film Phenomena

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Applied Physics, Osaka University, Yamada-oka 2-1, Suita 565-0871, Japan

Department of Physics, School of Natural and Mathematical Sciences, King’s College London, The Strand, London, WC2R 2LS, United Kingdom

Institute for Interdisciplinary Research, Jianghan University, Wuhan 430056, China

CCMS, Institute of Physics, Slovak Academy of Sciences, 84511 Bratislava, Slovakia

Department of Natural Sciences, University of Ss. Cyril and Methodius, 91701 Trnava, Slovakia

Funding

Osaka University · Vedeck? Grantov? Agent?ra M?VVa? SR a SAV · Japan Society for the Promotion of Science · Agent?ra na Podporu V?skumu a V?voja

References (33)

Show source-provided references
1. 10.1021/cr010371d10.1021/cr010371d ↗
2. 10.1016/S0040-4020(03)00944-X10.1016/S0040-4020(03)00944-X ↗
3. 10.1016/S0167-5729(02)00100-010.1016/S0167-5729(02)00100-0 ↗
4. 10.1021/nn800824510.1021/nn8008245 ↗
5. 10.1021/ja110375n10.1021/ja110375n ↗
6. 10.1021/jz101535f10.1021/jz101535f ↗
7. 10.1039/c000250j10.1039/c000250j ↗
8. 10.1016/j.susc.2010.08.00410.1016/j.susc.2010.08.004 ↗
9. 10.1021/jacs.8b0774510.1021/jacs.8b07745 ↗
10. 10.1103/PhysRevLett.100.19610210.1103/PhysRevLett.100.196102 ↗
11. 10.1021/jz201405510.1021/jz2014055 ↗
12. 10.1073/pnas.161872311410.1073/pnas.1618723114 ↗
13. 10.1038/s41565-018-0104-410.1038/s41565-018-0104-4 ↗
14. 10.1038/nnano.2009.34710.1038/nnano.2009.347 ↗
15. 10.1038/ncomms547610.1038/ncomms5476 ↗
16. 10.1038/nchem.243810.1038/nchem.2438 ↗
17. 10.1038/nnano.2012.2010.1038/nnano.2012.20 ↗
18. 10.1126/science.117227310.1126/science.1172273 ↗
19. 10.1038/ncomms935310.1038/ncomms9353 ↗
20. 10.1103/PhysRevLett.114.03680110.1103/PhysRevLett.114.036801 ↗
21. 10.1038/s41565-018-0087-110.1038/s41565-018-0087-1 ↗
22. 10.1103/PhysRevLett.121.22610110.1103/PhysRevLett.121.226101 ↗
23. 10.1126/science.112607310.1126/science.1126073 ↗
24. 10.1103/PhysRevLett.117.11640210.1103/PhysRevLett.117.116402 ↗
25. 10.1103/PhysRevLett.122.01680510.1103/PhysRevLett.122.016805 ↗
26. 10.1039/C6NR07550A10.1039/C6NR07550A ↗
27. 10.1103/PhysRevLett.115.02610110.1103/PhysRevLett.115.026101 ↗
28. 10.1021/acs.nanolett.5b0071110.1021/acs.nanolett.5b00711 ↗
29. 10.1063/1.312750310.1063/1.3127503 ↗
30. 10.1103/PhysRevB.50.1795310.1103/PhysRevB.50.17953 ↗
31. 10.1063/1.240466310.1063/1.2404663 ↗
32. 10.1016/0927-0256(96)00008-010.1016/0927-0256(96)00008-0 ↗
33. 10.1063/1.132967210.1063/1.1329672 ↗