journal article·2019-06-25

Amorphous Tin Oxide Nanohelix Structure Based Electrode for Highly Reversible Na-Ion Batteries

Il Yong Choi, Changshin Jo, Won-Gwang Lim, Jong-Chan Han, Byeong-Gyu Chae, Chan Gyung Park, Jinwoo Lee, Jong Kyu Kim

ACS Nano· Volume 13· Issue 6
Publisher page

Abstract

An array of amorphous tin oxide (a-SnOx) nanohelixes (NHs) was fabricated on copper foil as an electrode for Na-ion batteries via the oblique angle deposition method, a solution- and surfactant-free process. The combination of the amorphous phase SnOx with a low oxidation number and its vertically aligned NH geometry with a large surface area and high porosity, which facilitate Na-ion dynamics and accommodate the volume changes, enabled a reversible capacity of up to 915 mA h g–1 after 50 cycles, fast rate capability with 48.1% retention at 2 A g–1, and high stability, which are superior to those of crystalline nanoparticle-based electrodes.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Technologies Research · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Engineering, Pohang University of Science and Technology (POSTECH), Pohang 37673, Republic of Korea

Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), Pohang 37673, Republic of Korea

Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea

Funding

National Research Foundation of Korea

References (38)

Show source-provided references
1. 10.1002/aenm.20150251410.1002/aenm.201502514 ↗
2. 10.1038/natrevmats.2018.1310.1038/natrevmats.2018.13 ↗
3. 10.1149/1.222115310.1149/1.2221153 ↗
4. 10.1016/S0013-4686(02)00250-510.1016/S0013-4686(02)00250-5 ↗
5. 10.1021/acsami.5b0318610.1021/acsami.5b03186 ↗
6. 10.1039/C5EE02051D10.1039/C5EE02051D ↗
7. 10.1002/chem.20140251110.1002/chem.201402511 ↗
8. 10.1021/cm502560310.1021/cm5025603 ↗
9. 10.1016/j.jpowsour.2017.05.06410.1016/j.jpowsour.2017.05.064 ↗
10. 10.1039/C6TA03541H10.1039/C6TA03541H ↗
11. 10.1002/aenm.20150205710.1002/aenm.201502057 ↗
12. 10.1002/adfm.20110266910.1002/adfm.201102669 ↗
13. 10.1021/cm502268u10.1021/cm502268u ↗
14. 10.1021/ja905488x10.1021/ja905488x ↗
15. 10.1039/c3ee41880d10.1039/c3ee41880d ↗
16. 10.1149/1.272475610.1149/1.2724756 ↗
17. 10.1016/j.jpowsour.2015.12.11810.1016/j.jpowsour.2015.12.118 ↗
18. 10.1016/j.nanoen.2015.07.01010.1016/j.nanoen.2015.07.010 ↗
19. 10.1021/acsami.5b0433810.1021/acsami.5b04338 ↗
20. 10.1039/c3cp52037d10.1039/c3cp52037d ↗
21. 10.1021/nl402633n10.1021/nl402633n ↗
22. 10.1002/adfm.20180413210.1002/adfm.201804132 ↗
23. 10.1116/1.205274710.1116/1.2052747 ↗
24. 10.1016/j.jallcom.2014.04.18710.1016/j.jallcom.2014.04.187 ↗
25. 10.1063/1.481598410.1063/1.4815984 ↗
26. 10.1021/ja00255a03210.1021/ja00255a032 ↗
27. 10.1007/s00216-003-1982-210.1007/s00216-003-1982-2 ↗
28. 10.1021/acsnano.5b0081710.1021/acsnano.5b00817 ↗
29. 10.1039/c1cp20940j10.1039/c1cp20940j ↗
30. 10.1021/jp203698210.1021/jp2036982 ↗
31. 10.1016/j.nanoen.2017.06.00510.1016/j.nanoen.2017.06.005 ↗
32. 10.1016/j.electacta.2014.11.00910.1016/j.electacta.2014.11.009 ↗
33. 10.1039/C5RA02834E10.1039/C5RA02834E ↗
34. 10.1021/acs.nanolett.6b0528010.1021/acs.nanolett.6b05280 ↗
35. 10.1002/anie.20151097810.1002/anie.201510978 ↗
36. 10.1016/j.jpowsour.2015.03.04210.1016/j.jpowsour.2015.03.042 ↗
37. 10.1016/j.nanoen.2016.08.04410.1016/j.nanoen.2016.08.044 ↗
38. 10.1016/j.elecom.2016.09.01210.1016/j.elecom.2016.09.012 ↗