journal article·2020-01-28Open access

Origin of the Flat Band in Heavily Cs-Doped Graphene

Niels Ehlen, Martin Hell, Giovanni Marini, Eddwi Hesky Hasdeo, Riichiro Saito, Yannic Falke, Mark Oliver Goerbig, Giovanni Di Santo, Luca Petaccia, Gianni Profeta, Alexander Grüneis

ACS Nano· Volume 14· Issue 1

Abstract

A flat energy dispersion of electrons at the Fermi level of a material leads to instabilities in the electronic system and can drive phase transitions. Here we show that the flat band in graphene can be achieved by sandwiching a graphene monolayer by two cesium (Cs) layers. We investigate the flat band by a combination of angle-resolved photoemission spectroscopy experiment and the calculations. Our work highlights that charge transfer, zone folding of graphene bands, and the covalent bonding between C and Cs atoms are the origin of the flat energy band formation. Analysis of the Stoner criterion for the flat band suggests the presence of a ferromagnetic instability. The presented approach is an alternative route for obtaining flat band materials to twisting bilayer graphene which yields thermodynamically stable flat band materials in large areas.
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Research context

OpenAlex topics: Graphene research and applications · 2D Materials and Applications · Boron and Carbon Nanomaterials Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

II. Physikalisches Institut, Universität zu Köln, Zülpicher Strasse 77, 50937 Cologne, Germany

Department of Physical and Chemical Sciences and SPIN-CNR, University of L’Aquila, Via Vetoio 10, I-67100 Coppito, Italy

Research Center for Physics, Indonesian Institute of Sciences, Kawasan Puspiptek Serpong, Tangerang Selatan, 15314, Indonesia

Department of Physics, Tohoku University, Sendai 980-8578, Japan

Laboratoire de Physique des Solides, CNRS UMR 8502, Université Paris-Saclay, 91405 Orsay Cedex, France

Elettra Sincrotrone Trieste, Strada Statale 14 km 163.5, 34149 Trieste, Italy

Funding

Deutscher Akademischer Austauschdienst · Deutsche Forschungsgemeinschaft · Japan Society for the Promotion of Science · H2020 Excellent Science · Quantum Matter and Materials

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