journal article·2026-09

Solvent-free surface engineering of LiNi0.6Mn0.2Co0.2O2 using a hydrophobic fluorosilane to enhance moisture stability

Lauren B. Levine, Artem Nikulin, Lander Rodriguez-Castaño, Rosalía Cid, Emilie Bekaert, Aitor Villaverde, Elena Palomo del Barrio, Eider Goikolea, Marta Cabello, Nicholas E. Drewett

Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Fiber-reinforced polymer composites · Advanced Battery Materials and Technologies · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (82)

Show source-provided references
1. Energy storage — a key technology for global energy sustainability10.1016/S0378-7753(01)00894-1 ↗
2. Advancing energy storage: the future trajectory of lithium-ion battery technologies10.1016/j.est.2025.116511 ↗
3. Lithium-ion batteries – Current state of the art and anticipated developments10.1016/j.jpowsour.2020.228708 ↗
4. Batteries and fuel cells for emerging electric vehicle markets10.1038/s41560-018-0108-1 ↗
5. The research and industrialization progress and prospects of sodium ion battery10.1016/j.jallcom.2023.170486 ↗
6. Air-stability of sodium-based layered-oxide cathode materials10.1007/s11426-022-1257-8 ↗
7. Unravelling air/moisture stability of cathode materials in sodium ion batteries: characterization, rational design, and perspectives10.1039/D4EE00796D ↗
8. Sodium-ion layered oxide cathode materials based on oxygen anion redox: mechanism study, voltage hysteresis, and air stability improvement
9. Air sensitivity of electrode materials in Li/Na ion batteries: issues and strategies10.1002/inf2.12305 ↗
10. Suppress moisture sensitivity of Ni-rich cathode materials by bioinspired self-assembly hydrophobic layer10.1016/j.cej.2023.146850 ↗
11. Air/water stability problems and solutions for lithium batteries10.34133/2022/9842651 ↗
12. A review of the origin, adverse influence and modification method of residual surface lithium in Ni-rich cathodes10.1016/j.ijoes.2023.100391 ↗
13. The effects of ambient storage conditions on the structural and electrochemical properties of NMC-811 cathodes for Li-ion batteries10.1016/j.electacta.2020.137358 ↗
14. Controlling residual lithium in high-nickel (>90 %) lithium layered oxides for cathodes in lithium-ion batteries10.1002/anie.202007436 ↗
15. Situ tuning residual lithium compounds and constructing TiO2 coating for surface modification of a nickel-rich cathode toward high-energy lithium-ion batteries10.1021/acsaem.0c02406 ↗
16. Destabilization of the surface structure of Ni-rich layered materials by water-washing process10.1016/j.ensm.2021.11.006 ↗
17. Structure and charge regulation strategy enabling superior cyclability for Ni-rich layered cathode materials10.1002/smll.202104282 ↗
18. Mass-scalable molecular monolayer for Ni-rich cathode powder: solution for microcrack failure in lithium-ion batteries10.1021/acsami.1c03680 ↗
19. Reinforcement of binder adhesion for nickel-rich layered oxide in lithium-ion batteries using perfluorinated molecular surface modification10.1016/j.cej.2022.137654 ↗
20. Elucidating and mitigating high-voltage degradation cascades in cobalt-free LiNiO(2) lithium-ion battery cathodes
21. Identification of critical moisture exposure for nickel-rich cathode active materials in lithium-ion battery production10.1016/j.jpowsour.2024.235661 ↗
22. Challenges and industrial perspectives on the development of sodium ion batteries10.1016/j.nanoen.2024.110052 ↗
23. Exploring the limitations and unlocking the potential of sodium-ion battery cathodes
24. Interface issues of layered transition metal oxide cathodes for sodium-ion batteries: current status, recent advances, strategies, and prospects10.3390/molecules29245988 ↗
25. Insights into extreme thermal runaway scenarios of lithium-ion batteries fire and explosion: a critical review10.1016/j.est.2024.111532 ↗
26. Current and future lithium-ion battery manufacturing
27. A mild surface washing method using protonated polyaniline for Ni-rich LiNi0.8Co0.1Mn0.1O2 material of lithium ion batteries10.1016/j.electacta.2017.07.169 ↗
28. Washing effects on electrochemical performance and storage characteristics of LiNi0.8Co0.1Mn0.1O2 as cathode material for lithium-ion batteries10.1016/j.jpowsour.2012.08.029 ↗
29. Residual Li compounds-selective washing process for Ni-rich layered oxide cathode materials for Li-ion batteries10.1149/1945-7111/ac2f05 ↗
30. A comparative review of metal oxide surface coatings on three families of cathode materials for lithium ion batteries10.3390/coatings11070744 ↗
31. Review—Surface coatings for cathodes in lithium ion batteries: from crystal structures to electrochemical performance10.1149/1945-7111/ac60f3 ↗
32. Conformal coatings for lithium-ion batteries: a comprehensive review
33. Impact of coatings on the electrochemical performance of LiNi0.5Mn1.5O4 cathode materials: a focused review10.1016/j.ceramint.2021.12.118 ↗
34. A scalable snowballing strategy to construct uniform rGO-wrapped LiNi0.8Co0.1Mn0.1O2 with enhanced processability and electrochemical performance10.1016/j.apsusc.2020.148663 ↗
35. Enabling ambient stability of LiNiO2 lithium-ion battery cathode materials via graphene–Cellulose composite coatings10.1021/acs.chemmater.3c00851 ↗
36. Carbon-coated Honeycomb Ni-Mn-Co-O inverse opal: a high capacity ternary transition metal oxide anode for Li-ion batteries10.1038/srep42263 ↗
37. LiNi0.8Co0.15Al0.05O2 cathode materials prepared by TiO2 nanoparticle coatings on Ni0.8Co0.15Al0.05(OH)2 precursors10.1016/j.electacta.2010.08.074 ↗
38. Improved cycling stability of LiNi0.6Co0.2Mn0.2O2 through microstructure consolidation by TiO2 coating for Li-ion batteries10.1016/j.jpowsour.2019.227439 ↗
39. From surface ZrO2 coating to bulk Zr doping by high temperature annealing of nickel-rich lithiated oxides and their enhanced electrochemical performance in lithium ion batteries10.1002/aenm.201701682 ↗
40. Improvement of cycle performance of the high nickel cathode material LiNi0.88Co0.07Al0.05O2 for lithium-ion batteries by the spray drying of V2O510.1016/j.jallcom.2021.162161 ↗
41. Improvement of long-term cycling performance of Li[Ni0.8Co0.15Al0.05]O2 by AlF3 coating10.1016/j.jpowsour.2013.01.045 ↗
42. Enhanced electrochemical properties of Li[Ni0.5Co0.2Mn0.3]O2 cathode by surface coating using LaF3 and MgF210.1007/s10832-012-9747-y ↗
43. Synergistic effect of F– Doping and LiF coating on improving the high-voltage cycling stability and rate capacity of LiNi0.5Co0.2Mn0.3O2 cathode materials for lithium-ion batteries10.1021/acsami.8b10016 ↗
44. Enhanced cyclability and safety performance of LiNi0.6Co0.2Mn0.2O2 at elevated temperature by AlPO4 modification10.1016/j.jallcom.2019.151834 ↗
45. In situ surface modification for improving the electrochemical performance of Ni-rich cathode materials by using ZrP2O710.1002/cssc.201902219 ↗
46. In-situ formation of hybrid Li3PO4-AlPO4-Al(PO3)3 coating layer on LiNi0.8Co0.1Mn0.1O2 cathode with enhanced electrochemical properties for lithium-ion battery10.1016/j.cej.2019.122959 ↗
47. Lithium phosphonate functionalized polymer coating for high-energy Li[Ni0.8Co0.1Mn0.1]O2 with superior performance at ambient and elevated temperatures
48. Simultaneous synthesis and synergetic stabilization of Zr-doped and Li6Zr2O7-coated Ni-rich layered cathode for advanced lithium ion batteries10.1016/j.electacta.2020.137120 ↗
49. Oxygen release and its effect on the cycling stability of LiNixMnyCozO2 (NMC) cathode materials for Li-ion batteries10.1149/2.0021707jes ↗
50. Natural and synthetic superhydrophobic surfaces: a review of the fundamentals, structures, and applications10.1016/j.aej.2023.01.058 ↗
51. Electrically conductive PEDOT coating with self-healing superhydrophobicity10.1021/la500603c ↗
52. Enhancing the water resistance and stability of CsPbBr3 perovskite quantum dots for light-emitting-diode applications through encapsulation in waterproof polymethylsilsesquioxane aerogels10.1021/acsami.0c18371 ↗
53. Superhydrophobic TiO2–Polymer nanocomposite surface with UV-induced reversible wettability and self-cleaning properties10.1021/am401668y ↗
54. Bio-inspired titanium dioxide materials with special wettability and their applications10.1021/cr4006796 ↗
55. The green solvent: a critical perspective10.1007/s10098-021-02188-8 ↗
56. Solvent use and waste issues
57. 2015
58. To enhance the performance of LiNi0.5Co0.2Mn0.3O2 aqueous electrodes by the coating process10.1021/acsomega.4c00301 ↗
59. Hydrophobic surface coating against chemical environmental instability for Ni-rich layered oxide cathode materials10.1016/j.cej.2022.135276 ↗
60. Molecular-scale hydrophobic modification of Ni-rich cathode materials toward superior critical endurability and environmental stability10.1002/adsu.202200002 ↗
61. Enhanced storage and interface structure stability of NCM811 cathodes for lithium-ion batteries by hydrophobic fluoroalkylsilanes modification10.1002/ente.202101013 ↗
62. Hydrophobic Ni-rich layered oxides as cathode materials for lithium-ion batteries10.1021/acsaem.9b00786 ↗
63. Origin of enhanced cyclability in covalently modified LiMn1.5Ni0.5O4 cathodes10.1021/acsami.9b12912 ↗
64. Environmentally friendly gas phase grafting of mesoporous silicas10.1016/j.cej.2021.132627 ↗
65. Non-aqueous electrode processing and construction of lithium-ion coin cells10.3791/53490 ↗
66. Stability of LiNi0.6Mn0.2Co0.2O2 as a cathode material for lithium-ion batteries against air and moisture10.1002/bkcs.10679 ↗
67. Effect of ambient storage on the degradation of Ni-rich positive electrode materials (NMC811) for Li-ion batteries10.1149/2.0401802jes ↗
68. Reaction heterogeneity in LiNi0.8Co0.15Al0.05O2 induced by surface layer10.1021/acs.chemmater.7b02236 ↗
69. Graphene-based sulfur cathodes and dual salt-based sparingly solvating electrolytes: a perfect marriage for high performing, safe, and long cycle life lithium-sulfur prototype batteries10.1002/aenm.202302378 ↗
70. How does Li2C4O4 prelithiation additive influence the solid electrolyte interphase of dual carbon lithium-ion capacitors?10.1021/acsami.4c09411 ↗
71. Dehydrofluorination process of poly(vinylidene difluoride) PVdF-based gel polymer electrolytes and its effect on lithium-sulfur batteries10.3390/gels9040336 ↗
72. Improving high-voltage cycling performance of nickel-rich NMC layered oxide cathodes for rechargeable lithium–ion batteries by Mg and Zr co-doping
73. High-temperature thermal reactivity and interface evolution of the NMC-LATP-carbon composite cathode10.1021/acsami.2c20097 ↗
74. Morphological evolution and solid–Electrolyte interphase formation on LiNi0.6Mn0.2Co0.2O2 cathodes using highly concentrated ionic liquid electrolytes10.1021/acsami.1c21853 ↗
75. On the role of ultrathin lithium metal anodes produced by thermal evaporation10.1016/j.jpowsour.2024.235218 ↗
76. Characterization of silica modified with silanes by using thermogravimetric analysis combined with infrared detection10.5254/rct.18.82626 ↗
77. Investigation of grafting silane coupling agents on superhydrophobicity of carbonyl iron/SiO2 particles for efficient oil/water mixture and emulsion separation10.1038/s41598-023-28131-z ↗
78. Understanding the roles of tris(trimethylsilyl) phosphite (TMSPi) in LiNi0.8Mn0.1Co0.1O2 (NMC811)/silicon–Graphite (Si–Gr) lithium-ion batteries10.1002/admi.202000277 ↗
79. Air- and moisture robust surface modification for Ni-rich layered cathode materials for Li-ion batteries
80. Full-, half-, and symmetrical cell analysis of lithium-ion battery using impedance and nonlinear frequency response10.1149/1945-7111/ad5ef9 ↗
81. Modeling and applications of electrochemical impedance spectroscopy (EIS) for lithium-ion batteries10.33961/jecst.2019.00528 ↗
82. Experimental challenges for electrochemical evaluation of cathodes in lithium-ion battery half-cells10.1016/j.est.2023.108706 ↗