journal article·2014-03-25

Self-Organized Platinum Nanoparticles on Freestanding Graphene

Peng Xu, Lifeng Dong, Mehdi Neek-Amal, Matthew L. Ackerman, Jianhua Yu, Steven D. Barber, James Kevin Schoelz, Dejun Qi, Fangfang Xu, Paul M. Thibado, Francois M. Peeters

ACS Nano· Volume 8· Issue 3
Publisher page

Abstract

Freestanding graphene membranes were successfully functionalized with platinum nanoparticles (Pt NPs). High-resolution transmission electron microscopy revealed a homogeneous distribution of single-crystal Pt NPs that tend to exhibit a preferred orientation. Unexpectedly, the NPs were also found to be partially exposed to the vacuum with the top Pt surface raised above the graphene substrate, as deduced from atomic-scale scanning tunneling microscopy images and detailed molecular dynamics simulations. Local strain accumulation during the growth process is thought to be the origin of the NP self-organization. These findings are expected to shape future approaches in developing Pt NP catalysts for fuel cells as well as NP-functionalized graphene-based high-performance electronics.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Graphene research and applications · Molecular Junctions and Nanostructures · Surface and Thin Film Phenomena

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Physics, University of Arkansas, Fayetteville, Arkansas 72701, United States

College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China

Department of Physics, Astronomy, and Materials Science, Missouri State University, Springfield, Missouri 65897, United States

Departement Fysica, Universiteit Antwerpen, Groenenborgerlaan 171, B-2020 Antwerpen, Belgium

Department of Physics, Shahid Rajaee Teacher Training University, Lavizan, Tehran 16788, Iran

State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Shanghai 200050, China

References (37)

Show source-provided references
1. Steele B. C. H. · Nature · 2001 · 414 · 34510.1038/35104620 ↗
2. Yamamoto K. · Nat. Chem. · 2009 · 1 · 39710.1038/nchem.288 ↗
3. Siburian R. · J. Phys. Chem. C · 2013 · 117 · 363510.1021/jp311852j ↗
4. Costamagna P. · J. Power Sources · 2001 · 102 · 24210.1016/S0378-7753(01)00807-2 ↗
5. Li W. · J. Phys. Chem. B · 2003 · 107 · 629210.1021/jp022505c ↗
6. Dong L. · Carbon · 2010 · 48 · 78110.1016/j.carbon.2009.10.027 ↗
7. Seger B. · J. Phys. Chem. C · 2009 · 113 · 799010.1021/jp900360k ↗
8. Tang Y. · Phys. Chem. Chem. Phys. · 2012 · 14 · 1656610.1039/c2cp41441d ↗
9. Okazaki-Maeda K. · Surf. Sci. · 2010 · 604 · 14410.1016/j.susc.2009.11.001 ↗
10. Kumar V. · Phys. Rev. B · 2008 · 77 · 20541810.1103/PhysRevB.77.205418 ↗
11. Okamoto Y. · Chem. Phys. Lett. · 2006 · 420 · 38210.1016/j.cplett.2006.01.007 ↗
12. Meyer J. C. · Nature · 2007 · 446 · 6010.1038/nature05545 ↗
13. Pantelic R. S. · Solid State Commun. · 2012 · 152 · 137510.1016/j.ssc.2012.04.038 ↗
14. Xu P. · Phys. Rev. B · 2012 · 85 · 121406(R)10.1103/PhysRevB.85.121406 ↗
15. Zan R. · Nanoscale · 2012 · 4 · 306510.1039/c2nr30162h ↗
16. Crewe A. V. · Science · 1970 · 168 · 133810.1126/science.168.3937.1338 ↗
17. Nellist P. D. · Science · 1996 · 274 · 41310.1126/science.274.5286.413 ↗
18. Meyer J. C. · Nature · 2008 · 454 · 31910.1038/nature07094 ↗
19. Yuk J. M. · Nano Lett. · 2011 · 11 · 329010.1021/nl201647p ↗
20. Wei D. · Part. Part. Syst. Charact. · 2013 · 30 · 14310.1002/ppsc.201200120 ↗
21. Xu P. · J. Vac. Sci. Technol., B · 2013 · 31 · 04D10110.1116/1.4803137 ↗
22. Wiesendanger R. · 1994 · 45210.1017/CBO9780511524356 ↗
23. Yuk J. M. · Science · 2012 · 336 · 6110.1126/science.1217654 ↗
24. Mohanty N. · Nano Lett. · 2011 · 11 · 127010.1021/nl104292k ↗
25. Xu P. · Phys. Rev. B · 2011 · 84 · 161409(R)10.1103/PhysRevB.84.161409 ↗
26. Smythe W. R. · 1939 · 193
27. Neek-Amal M. · Nanotechnology · 2009 · 20 · 13560210.1088/0957-4484/20/13/135602 ↗
28. Liu L. · J. Phys. Chem. B · 2013 · 117 · 430510.1021/jp305521g ↗
29. Venezuela P. · Nature · 1999 · 397 · 67810.1038/17767 ↗
30. Yang H. · J. Vac. Sci. Technol., B · 1999 · 17 · 177810.1116/1.590825 ↗
31. Ahmadi T. S. · Science · 1996 · 272 · 192410.1126/science.272.5270.1924 ↗
32. Reina A. · Nano Lett. · 2009 · 9 · 3010.1021/nl801827v ↗
33. Regan W. · Appl. Phys. Lett. · 2010 · 96 · 11310210.1063/1.3337091 ↗
34. van Duin A. C. T. · J. Phys. Chem. A · 2001 · 105 · 939610.1021/jp004368u ↗
35. van Duin A. C. T. · Org. Geochem. · 2003 · 34 · 51510.1016/S0146-6380(02)00247-4 ↗
36. Plimpton S. · J. Comput. Phys. · 1995 · 117 · 110.1006/jcph.1995.1039 ↗
37. Sanz-Navarro C. F. · J. Phys. Chem. A · 2008 · 112 · 139210.1021/jp074806y ↗