Solid-State Reactions in Binary Molecular Assemblies of F16CuPc and Pentacene
Source abstract
Abstract
Various phases of binary molecular assemblies of perfluorinated Cu-phthalocyanine (F₁₆CuPc) and pentacene were examined using scanning tunneling microscopy (STM). Alloying, solid solutions, phase separation, and segregation were observed in assemblies on monolayers according to the mixture ratios. The main driving force behind such molecular blending is CH-F hydrogen bonds. Lattice matching and molecular symmetry are other factors that determine the assembly configuration. A detailed understanding of such solid-state reactions provides a guideline to the construction of multilayered binary assemblies, where intermixing between molecules takes place when multiple layers are stacked.
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Research context
OpenAlex topics: Surface Chemistry and Catalysis · Molecular Junctions and Nanostructures · Spectroscopy and Quantum Chemical Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Advanced Electronic Materials Center, National Institute for Materials Science, 1-1 Namiki, Tsukuba 305-0044, Japan
Department of Chemistry and Biochemistry, Faculty of Engineering, Kyushu University, 1-1 Namiki, Tsukuba 305-0044, Japan
Donostia International Physics Center, Paseo Manuel Lardizabal 4, San Sebastián, Spain
Nano-Bio Spectroscopy Group and European Theoretical Spectroscopy Facility, Departamento Fisica de Materiales UPV/EHU, Apartado 1072, San Sebastián, Spain
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