journal article·2021-07Open access

Solvothermal synthesis, characterization and visible-light-driven photocatalysis of self-assembled flower-like CdS nanostructure

Division of Physical Science, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand, P. Intaphong, A. Phuruangrat, Division of Physical Science, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand, K. Akhbari, School of Chemistry, College of Science, University of Tehran, Tehran, Iran, T. Sakhon, Electron Microscopy Research and Service Center, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand, B. Kuntalue, Electron Microscopy Research and Service Center, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand, T. Thongtem, Materials Science Research Center, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand, Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand, S. Thongtem, Materials Science Research Center, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand, Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand

Chalcogenide Letters· Volume 18· Issue 7

Abstract

Self-assembled nanorods/nanowires of CdS were successfully synthesized by a solvothermal method at 200 oC for 5, 10 and 20 h using sodium dodecylsulfonate as a capping reagent. X-ray diffraction (XRD) patterns of all CdS samples can be indexed to pure phase of hexagonal CdS structure. The degree of crystallinity of CdS was increased with the increase of holding reaction time from 5 h to 20 h. Transmission electron microscopic (TEM) images revealed that the product synthesized by the solvothermal method at 200 oC for 20 h contained self-assembled flower-like CdS nanostructure. The UV-visible absorption of self-assembled flower-like CdS nanostructure shows excellent absorption in UV-visible region with the absorption peak at 481 nm. Photocatalytic efficiency of the as-prepared CdS samples was investigated through rhodamine B (RhB) degradation under visible light irradiation. In this research, the self-assembled flowerlike CdS nanostructure has the highest degradation of 94.91 % within 80 min.
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Research context

OpenAlex topics: Quantum Dots Synthesis And Properties · Chalcogenide Semiconductor Thin Films · Advanced Photocatalysis Techniques

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