Li-Ions Transport Promoting and Highly Stable Solid–Electrolyte Interface on Si in Multilayer Si/C through Thickness Control

Lithium-ion batteries (LIBs) have been considered as promising electrochemical energy storage devices due to the high volumetric, gravimetric capacity and high power density. The charge/discharge rate and power output of LIBs largely depend on the transport property of lithium-ions (Li-ions). The Li-ions diffusion coefficient and diffusion length are the critical factors influencing the charge/discharge rate of LIBs. In this work, we present that silicon-carbon (Si-C) interfaces in an amorphous Si/C multilayer electrode promote the transport of Li-ions along the direction not only perpendicular to but also parallel to the Si-C interfaces after electrode cracking. The electrode, stacked with 5 nm amorphous carbon and 10 nm amorphous Si, has the most stable solid-electrolyte interface (SEI) formed at the cracks, even when the Si is in direct contact with the electrolyte. It exhibits highly stable cycle performance and a high retained specific capacity. Electron microscopy characterization shows that the structure contains uniform Si/C multilayer blocks of about 1 μm. A micro-size hierarchical multilayer-block design strategy with proper stacking thickness of amorphous Si and carbon is thus proposed for high-performance film LIB anodes. Furthermore, the results may be used as a reference for the design of high-performance core-shell LIB anodes.