Features of structural ordering and magnetic properties of the cobalt intercalates of titanium dichalcogenides
Source abstract
Abstract
CoxTiS2 (x = 0.20, 0.30, 0.50, 0.75) compounds have a layered crystal structure with Ti atoms surrounded by the S octahedrons in the S-Ti-S layers and Co ions which could be surrounded both by the S octahedrons and tetrahedrons. The features of the crystal structure and magnetic properties of the polycrystalline CoxTiS2 samples were studied as a function of the cobalt concentration using X-ray diffraction and magnetization measurements. The disordered state of the Co atoms (x < 0.20) changes to the ordered one (x ≥ 0.20). The magnetic ordering arises at x = 0.20 with mostly antiferromagnetic interaction. For compound with x = 0.30 and 0.50 there is a weak ferromagnetic ordering. The ferromagnetic ordering is observed in Co0.75TiS2 below Tc = 375 K.
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OpenAlex topics: Inorganic Chemistry and Materials · 2D Materials and Applications · Crystal Structures and Properties
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References (32)
Show source-provided references
1. [1] M. S. Whittingham, Prog. Solid State Chem. 12(1) 41-99 (1978); https://doi.org/10.1016/0079-6786(78)90003-110.1016/0079-6786(78)90003-1 ↗
2. [2] M. S. Whittingham, Chem. Rev. 104(10), 4271-4302 (2004); https://doi.org/10.1021/cr020731c10.1021/cr020731c ↗
3. [3] T. Hibma, Structural aspects of monovalent cation intercalates of layered dichalcogenides: Intercalation Chemistry. Ed. London: Acad. Press, 285 (1982).10.1016/B978-0-12-747380-2.50014-6 ↗
4. [4] Y. Hara, H. Negishi, M. Sasaki, M. Inoue, V. A. Kulbachinskii, J. Magn. Magn. Mater. 145(1- 2), 157-164 (1995); https://doi.org/10.1016/0304-8853(94)00867-110.1016/0304-8853(94)00867-1 ↗
5. [5] E. Morosan, H. W. Zandbergen, B. S. Dennis, J. W. G. Bos, Y. Onose, T. Klimczuk, A. P. Ramirez, N. P. Ong, R. J. Cava, Nat. Phys. 2(8), 544-550 (2006); https://doi.org/10.1038/nphys36010.1038/nphys360 ↗
6. [6] M. Inoue, H. Negishi, T. Fujii, K. Takase, Y. Hara, M. Sasaki, J. Phys. Chem. Solids 57(6-8), 1109-1112 (1996); https://doi.org/10.1016/0022-3697(95)00405-X10.1016/0022-3697(95)00405-X ↗
7. [7] Y.-S. Kim, M. Mizuno, I. Tanaka, H. Adachi, Jpn. J. Appl. Phys. 37(9R), 4878 (1998); https://doi.org/10.1143/JJAP.37.487810.1143/JJAP.37.4878 ↗
8. [8] J. A. Wilson, A. D. Yoffe, Adv. Phys. 18(73), 193-335 (1969); https://doi.org/10.1080/0001873690010130710.1080/00018736900101307 ↗
9. [9] A. S. Shkvarin, Yu. M. Yarmoshenko, N. A. Skorikov, M. V. Yablonskikh, A. I. Merentsov, E. G. Shkvarina, A. N. Titov, J. Exp. Theor. Phys. 114(1), 169-176 (2012); https://doi.org/10.1134/S106377611201017710.1134/S1063776112010177 ↗
10. [10] Y. Ōnuki, R. Inada, and S. Tanuma, J. Phys. Soc. Japan 51(4), 1223-1227 (1982); https://doi.org/10.1143/JPSJ.51.122310.1143/JPSJ.51.1223 ↗
11. [11] P. C. Klipstein, A. G. Bagnall, W. Y. Liang, E. A. Marseglia, R. H. Friend, J. Phys. C Solid State Phys. 14(28), 4067-4081 (1981); https://doi.org/10.1088/0022-3719/14/28/00910.1088/0022-3719/14/28/009 ↗
12. [12] R. Winter, P. Heitjans, J. Phys. Chem. B 105(26), 6108-6115 (2001); https://doi.org/10.1021/jp011200f10.1021/jp011200f ↗
13. [13] D. Wiedemann, M. M. Islam, S. Nakhal, A. Senyshyn, T. Bredow, and M. Lerch, J. Phys. Chem. C 119(21), 11370-11381 (2015); https://doi.org/10.1021/acs.jpcc.5b0116610.1021/acs.jpcc.5b01166 ↗
14. [14] A. H. Thompson, Phys. B+C. 105(1-3), 461-465 (1981); https://doi.org/10.1016/0378-4363(81)90295-310.1016/0378-4363(81)90295-3 ↗
15. [15] N. I. Schwarzburger, R. Knobel, H. Behrens, M. Binnewies, I. Horn, A. Pelster, H. F. Arlinghaus, L. Dörrer, H. Schmidt, Zeitschrift für Phys. Chemie 226(5-6), 461-489 (2012); https://doi.org/10.1524/zpch.2012.022710.1524/zpch.2012.0227 ↗
16. [16] M. S. Brezhestovskii, E. A. Suslov, O. V. Bushkova, A. I. Merentsov, A. N. Titov, Phys. Solid State 57(10), 2078-2086 (2015); https://doi.org/10.1134/S106378341510008X10.1134/S106378341510008X ↗
17. [17] E. G. Shkvarina, A. I. Merentsov, M. S. Postnikov, A. S. Shkvarin, S. V. Pryanichnikov, I. Pıs, S. Nappini, F. Bondino, A. N. Titov, J. Mater. Chem. C 9(5), 1657-1670 (2021); https://doi.org/10.1039/D0TC03277H10.1039/D0TC03277H ↗
18. [18] H. Negishi, M. Marushita, M. Koyano, M. Inoue, J. Low Temp. Phys. 73(5-6), 459-468 (1988); https://doi.org/10.1007/BF0068357310.1007/BF00683573 ↗
19. [19] G. Guélou, P. Vaqueiro, J. Prado-Gonjal, T. Barbier, S. Hebert, E. Guilmeau, W. Kockelmann, A. V. Powell, J. Mater. Chem. C 4(9), 1871-1880 (2016); https://doi.org/10.1039/C5TC04217H10.1039/C5TC04217H ↗
20. [20] H. Negishi, A. Shoube, H. Takahashi, Y. Ueda, M. Sasaki, M. Inoue, J. Magn. Magn. Mater. 67(2), 179-186 (1987); https://doi.org/10.1016/0304-8853(87)90227-710.1016/0304-8853(87)90227-7 ↗
21. [21] M. Inoue, H. Negishi, J. Phys. Chem. 90(2), 235-238 (1986); https://doi.org/10.1021/j100274a00610.1021/j100274a006 ↗
22. [22] T. Kawasaki, K. Ohshima, J. Phys. Soc. Japan. 80(4), 044601-7 (2011); https://doi.org/10.1143/JPSJ.80.04460110.1143/JPSJ.80.044601 ↗
23. [23] J. Rodríguez-Carvajal, Phys. B Condens. Matter. 192(1-2), 55-69 (1993); https://doi.org/10.1016/0921-4526(93)90108-I10.1016/0921-4526(93)90108-I ↗
24. [24] K. Momma, F. Izumi, J. Appl. Crystallogr. 41(3), 653-658 (2008); https://doi.org/10.1107/S002188980801201610.1107/S0021889808012016 ↗
25. [25] X.-C. Liu, Y. Yang, J. Wu, M. Liu, S. Zhou, B. D. A. Levin, X.-D. Zhou, H. Cong, D. A. Muller, P. M. Ajayan, H. D. Abruña, F.-S. Ke, ACS Energy Lett. 3(6), 1325-1330 (2018); https://doi.org/10.1021/acsenergylett.8b0056110.1021/acsenergylett.8b00561 ↗
26. [26] R.R. Chianelli, J.C. Scanlon, A.H. Thompson, Mat. Res. Bull. 10, 1379-1382 (1975); https://doi.org/10.1016/0025-5408(75)90100-210.1016/0025-5408(75)90100-2 ↗
27. [27] M. Danot, R. Brec, Acta Crystallogr. Sect. B Struct. Crystallogr. Cryst. Chem. 31(6), 1647- 1652 (1975); https://doi.org/10.1107/S056774087500584510.1107/S0567740875005845 ↗
28. [28] M. Danot, J. Rouxel, O. Gorochov, Mater. Res. Bull. 9(10), 1383-1392 (1974); https://doi.org/10.1016/0025-5408(74)90063-410.1016/0025-5408(74)90063-4 ↗
29. [29] E. A. Suslov, O. V. Bushkova, E. A. Sherstobitova, O. G. Reznitskikh, A. N. Titov, Ionics 22(4), 503-514 (2016); https://doi.org/10.1007/s11581-015-1566-010.1007/s11581-015-1566-0 ↗
30. [30] M. M. Islam, T. Bredow, Zeitschrift für Phys. Chemie 226(5-6), 449-459 (2012); https://doi.org/10.1524/zpch.2012.022510.1524/zpch.2012.0225 ↗
31. [31] Y. Tazuke, A. Nomura, T. Ebina, J. Phys. Soc. Japan 56(3), 1250-1251 (1987); https://doi.org/10.1143/JPSJ.56.125010.1143/JPSJ.56.1250 ↗
32. [32] M. Inoue, M. Matsumoto, H. Negishi, H. Sakai, J. Magn. Magn. Mater. 53(1-2), 131-138 (1985); https://doi.org/10.1016/0304-8853(85)90141-610.1016/0304-8853(85)90141-6 ↗