DataVXChalcogenide LettersPaper
journal article·2022-11-03Open access

Thermal stability and glass transition kinetics in GeTeSb glasses by using non-isothermal measurement

Departement of Exact Sciences, Higher Training Teacher's School of Oran, Algeria, M. M. Heireche, L. Heireche, Laboratory of Sciences and Condensed Matter (LSMC), University of Oran1 Ahmed Ben Bella, Algeria, M. Belhadji, Laboratory of Sciences and Condensed Matter (LSMC), University of Oran1 Ahmed Ben Bella, Algeria

Chalcogenide Letters· Volume 19· Issue 10
Publisher pageOpen full text
Source abstract

Abstract

In this paper we have analysed the thermal properties of three different compositions of chalcogenide glasses Ge15Te85-xSbx (x=0.5, 1, 1.5). The samples have been prepared using the melt quenching technique and the characterisation is done using X-ray diffraction. The compositional dependence on properties were studied using Differential Scanning Calorimetry (DSC) analysis using non-isothermal measurement. The glassy sample crystallized by two transition temperatures Tg1 and Tg2.The dependence of glass transition temperature on heating rate has been studied by Lasocka empirical relation and the Kissinger equation. As a result, the apparent activation energy for glass transition has been determined. Thermal stability has also been determined from the temperature difference between the onset crystallization and glass transition temperature.
Source: crossref · Quality: baseline

Research context

Ceramics & glasses

OpenAlex topics: Phase-change materials and chalcogenides · Thermal and Kinetic Analysis · Glass properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (25)

Show source-provided references
1. [1] L.Heireche, M.Belhadji, Journal of optoelectronics and advanced materials 11, 1058 (2009).
2. [2] H. Cinkaya, A. Ozturk, A.S.A. Hasekioğlua, Z.E. Kaya, S. Kalem, C.C. Nicolle, G. Bourgeois, N. Guillaume, M.C. Cyrille, J. Garrione, G. Navarro, and E. Nowak, Solid-State Electron 185, 108 (2021).10.1016/j.sse.2021.108101 ↗
3. [3] X. Shi, C. Chen, S. Liu, and G. Li, Res. Phys 22, 103897 (2021).10.1016/j.rinp.2021.103897 ↗
4. [4] N. Ziani, M. Belhadji, L. Heireche, Z. Bouchaour and M. Belbachir, Physica B: Condensed Matter 358, 132 (2005).10.1016/j.physb.2004.12.068 ↗
5. [5] I.S. Yahia, A.M. Shakra, M. Fadel, N.A. Hegab, A.M. Salem, A.S. Farid, Chalcogenide Letters 8, 453 (2011).
6. [6] K.A. Aly , H.H. Amer , A. Dahshan, Materials Chemistry and Physics 113, 690 (2009).10.1016/j.matchemphys.2008.08.035 ↗
7. [7] J. Sanghera, L. B. Shaw, L. Busse, V. Nguyen, P. Pureza, B. Cole, B. B. Harbison, and I. Aggarwal, Fiber and Integrated Optics 19, 251 (2000);https://doi.org/10.1080/0146803005005881110.1080/01468030050058811 ↗
8. [8] N. Yamada, E. Ohno, N. Akahira, K. Nishiuchi, K. Nagata, M. Takao, Jpn. J. Appl. Phys. Suppl 26, 61(1987).10.7567/JJAPS.26S4.61 ↗
9. [9]D. Thornburg, Journal of Electronic Materials2 131, 495 (1987).
10. [10] D. C. Hunt, S.S. Kirby, J.A. Rowlands, Medical Physics29, 2464 (2002);http://dx.doi.org/10.1118/1.151315710.1118/1.1513157 ↗
11. [11] J. Zhang, S.Y. Zhang, J.J. Xu, H.Y. Chen, Chinese Chemical Letters 15, 1345 (2004).
12. [12] L. Le Neindre, F Smektala, K. Le Foulgoc, X.H. Zhang, J. Lukas, J Non Cryst Solid 24, 103 (1989).
13. [13] T. Akiyama, M. Uno, H. Kitaura, K. Narumi, R. Kojima, K. Nishiuchi, N. Yamada, Japanese Journal of Applied Physics 40,1598 (2001).10.1143/JJAP.40.1598 ↗
14. [14] T. Ohta, J. Optoelectron. Adv. Mater 3,609 (2001).
15. [15] P. Lebaudy, J. M. Saiter, J Grenet, M. Belhadji, C. Vautier, Mat. Sci. Eng. A 132, 273 (1991); https://doi.org/10.1016/0921-5093(91)90384-Y10.1016/0921-5093(91)90384-Y ↗
16. [16] A. Morvan, A. Lavanant, L. Arnoldi, X Sauvage, L. Calvez. Journal of Physical Chemistry C, American Chemical Society 125, 4196(2021).10.1021/acs.jpcc.0c09889 ↗
17. [17] S. Asokan, G. Parthasarathy, ESR. Gopal, J Mater Sci Lett 4, 502 (1985). https://doi.org/10.1007/BF0072001710.1007/BF00720017 ↗
18. [18] D. Rathore, K.N. Saxena, New Journal of Glass and Ceramics 2, 23 ( 2012).
19. [19] J.J. Tauc, in: F. Abeles (Ed.), North Holland, Amsterdam, 1970.
20. [20] Ch. Hurst, E.A. Davis, in: J. Stuke, W. Brenig (Eds.), Amorphous and Liquid Semiconductors, Taylor and Francis, London, 1974.
21. [21] M. Lasocka, Mater SciEng 23, 173 (1976).10.1093/nq/23-4-173 ↗
22. [22] S.F. Naqvi, N.S. Saxena, J Therm Anal Calorim, 108,1161 (2012);https://doi.org/10.1007/s10973-011-1857-210.1007/s10973-011-1857-2 ↗
23. [23] H.E. Kissinger, Anal. Chem 29, 1702 (1957).https://doi.org/10.1021/ac60131a04510.1021/ac60131a045 ↗
24. [24]K. Singh, N.S. Saxena, The Bulletin of Materials Science 26, 543 (2003).
25. [25] A. Hruby, Czechoslov J Phys B. 22 (1972).