journal article·2024-11-05

Facilitating Ion Storage and Transport Pathways by In Situ Constructing 1D Carbon Nanotube Electric Bridges between 2D MXene Interlayers

Qi Fan, Kui Xu, Minghua Chen, Qing Tang, Ke Chen, Xiaofei Hu, Fuli Lan, Yueqi Wang, Hui Shao, Sicong Qiao, Ziwei Yan, Changda Wang, Li Song, Wencheng Hu, Michael Naguib, Patrice Simon, Qing Huang, Yao Xiao, Kun Liang

ACS Nano· Volume 18· Issue 44
Publisher page

Abstract

Multiple van der Waals (vdW) gaps invoke abundant opportunities for contriving artificial architectures and tailoring desired properties via the intercalation route beyond the reach of conventional concepts. Intriguingly, the electrochemical intercalation strategy can precisely and reversibly tune the intercalation stage of charged functional species. This study presents a valid structural editing protocol facilitated by electrochemical intercalation to engineer MXene interlayers, ultimately incorporating in situ constructed carbon nanotube (CNT) electric bridges for enhanced ion storage and transport pathways. The method allows for the precise modulation of electrochemical forces to tailor materials for specific applications. Deep intercalation and in situ growth processes establish robust anchoring sites and connectivity hubs between MXenes and CNTs, ensuring structural homogeneity and stability in advanced electrode materials. The results demonstrate the effectiveness of electrochemistry-mediated interlayer nanoengineering in MXenes, offering a versatile approach to design vdW heterostructures with tailored functionalities for energy storage and conversion applications. This work highlights the potential of electrochemical modulation in advancing materials engineering strategies for next-generation energy storage technologies.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: MXene and MAX Phase Materials · Advanced Memory and Neural Computing · Energy Harvesting in Wireless Networks

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Zhejiang Key Laboratory of Data-Driven High-Safety Energy Materials and Applications Ningbo Key Laboratory of Special Energy Materials and Chemistry, Ningbo Institute of Materials Technology and Engineering

Chinese Academy of Sciences

University of Chinese Academy of Sciences, 19A Yuquan Road, Shijingshan District, Beijing 100049, P. R. China

School of Flexible Electronics (Future Technologies) & Institute of Advanced Materials (IAM)

Nanjing Tech University

Qianwan Institute of CNITECH

Center of Test and Analysis, Ningbo Institute of Materials Technology and Engineering

i-Lab, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics

National Synchrotron Radiation Laboratory, Key Laboratory of Precision and Intelligent Chemistry, School of Nuclear Science and Technology

University of Science and Technology of China

School of Materials and Energy

University of Electronic Science & Technology of China

Department of Physics and Engineering Physics

Tulane University

Université Paul Sabatier

College of Chemistry and Materials Engineering

Wenzhou University

Funding

Science and Technology Department of Zhejiang Province · National Natural Science Foundation of China · Ten-Thousand Talents Plan of Zhejiang Province · Youth Science and Technology Innovation Leading Talent Project of Ningbo · Ningbo Top-talent Team Program

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