journal article·2018-10

Synthesis, crystal structure and thermophysical properties of (La1-XEuX)3TaO7 ceramics

Lin Chen, Peng Wu, Peng Song, Jing Feng

Ceramics International· Volume 44· Issue 14
Publisher page

Abstract

Abstract Rare earth tantalates (La1-XEuX)3TaO7 ceramics are synthesized via solid-state reaction in this work. The phase structure is characterized via X-ray diffraction and Raman spectrum, when the microstructure and element distribution are detected by scanning electron microscopy and energy dispersive spectroscopy. As for various properties, (La1-XEuX)3TaO7 ceramics own excellent absorption for the UV light and the band gap ranges from 4.0 to 4.7 eV. The highest thermal expansion coefficients reach 10.8 × 10−6 K−1 (1200 ℃) and the entire series of (La1-XEuX)3TaO7 ceramics exhibit excellent high-temperature phase stability. The minimum thermal conductivity reaches 1.04 W m−1 K−1 (500 ℃) ascribed to various phonon scattering mechanisms. The thermal radiation resistance relates to the crystal structure, which relies on the mean RE3+ ionic radius. The results reveal that (La1-XEuX)3TaO7 ceramics are candidate thermal insulation materials.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nuclear materials and radiation effects · Luminescence Properties of Advanced Materials · Glass properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (57)

Show source-provided references
1. Thermal barrier coatings for gas-turbine engine applications10.1126/science.1068609 ↗
2. Thermal barrier coatings10.1016/S1369-7021(05)70934-2 ↗
3. Thermal barrier coatings for aircraft engines: history and directions10.1007/BF02646310 ↗
4. Failure mechanisms associated with the thermally grown oxide in plasma-sprayed thermal barrier coatings10.1016/S1359-6454(00)00171-3 ↗
5. Materials selection guidelines for low thermal conductivity thermal barrier coatings
6. Comprehensive damage evaluation of localized spallation of thermal barrier coatings10.1007/s40145-017-0234-4 ↗
7. Zirconates as new materials for thermal barrier coatings10.1111/j.1151-2916.2000.tb01506.x ↗
8. Anisotropic elastic and thermal properties of the double perovskite slab–rock salt layer Ln2SrAl2O7 (Ln = La, Nd, Sm, Eu, Gd or Dy) natural superlattice structure10.1016/j.actamat.2012.03.004 ↗
9. Thermal conductivity of dense and porous yttria-stabilized zirconia10.1023/A:1017970924312 ↗
10. Low thermal conductivity oxides10.1557/mrs.2012.234 ↗
11. Thermal conductivity and thermal expansion coefficients of lanthanum rare-earth-element zirconates system10.1111/j.1151-2916.2003.tb03473.x ↗
12. Thermal conductivity of plasma sprayed Sm2Zr2O7 coatings10.1016/j.jeurceramsoc.2009.09.010 ↗
13. Self-propagating high-temperature synthesis of ZrO2 incorporated Gd2Ti2O7 pyrochlore10.1007/s40145-017-0254-0 ↗
14. Microstructure and thermal properties of a promising thermal barrier coating: YTaO410.1016/j.ceramint.2016.05.194 ↗
15. Microstructure and thermal properties of RETaO4 (RE = Nd, Eu, Gd, Dy, Er, Yb, Lu) as promising thermal barrier coating materials10.1016/j.scriptamat.2016.08.019 ↗
16. Microstructure evolution of ZrO2-YbTaO4 thermal barrier coatings10.1016/j.actamat.2015.06.007 ↗
17. Exploration of the low thermal conductivities of γ-Y2Si2O7, β-Y2Si2O7, β-Yb2Si2O7, and β-Lu2Si2O7 as novel environmental barrier coating candidates10.1016/j.jeurceramsoc.2016.04.022 ↗
18. Anisotropy in elasticity and thermal conductivity of monazite-type REPO4 (RE = La, Ce, Nd, Sm, Eu and Gd) from first-principles calculations10.1016/j.actamat.2013.08.043 ↗
19. Lanthanum-cerium oxide as a thermal barrier-coating material for high-temperature applications10.1002/adma.200304132 ↗
20. Thermo-mechanical properties of ThO2-doped Y2O3 stabilized ZrO2 for thermal barrier coatings10.1016/j.ceramint.2015.08.137 ↗
21. Electronic structure, anisotropic elastic and thermal properties of monoclinic Ca2Nb2O710.1016/j.ceramint.2016.02.169 ↗
22. Properties and microstructure of machinable Al2O3/LaPO4 ceramic composites10.1016/S0272-8842(02)00083-4 ↗
23. Optimum pyrochlore compositions for low thermal conductivity10.1080/09500830310001646699 ↗
24. Thermal conductivity of single- and multi-phase compositions in the ZrO2-Y2O3-Ta2O5 system10.1016/j.jeurceramsoc.2014.03.013 ↗
25. Synthesis and thermophysical properties of RETa3O9 (RE = Ce, Nd, Sm, Eu, Gd, Dy, Er) as promising thermal barrier coatings10.1111/jace.15268 ↗
26. The glass-like thermal conductivity in ZrO2-Dy3TaO7 ceramic for promising thermal barrier coating application10.1063/1.5022610 ↗
27. Synthesis, thermal conductivities and phase stability of Gd3TaO7 and La doped Gd3TaO7 ceramics10.1016/j.jallcom.2017.10.266 ↗
28. Thermal properties of La3TaO7 and La2AlTaO7 oxides10.1016/j.ceramint.2016.10.005 ↗
29. Quantitative analysis in diffuse reflectance spectrometry: a modified Kubelka-Munk equation10.1016/0924-2031(94)00065-O ↗
30. Ultralow thermal conductivity in highly anion-defective aluminates10.1103/PhysRevLett.101.085901 ↗
31. Relation between the parameters of the elasticity theory and averaged bulk modulus of solids10.1134/S106378421111020X ↗
32. order-disorder in R3TaO7 (R = rare earth) phases10.1016/0167-2738(88)90365-7 ↗
33. Crystal structures and magnetic properties of rare earth tantalates RE3TaO7 (RE = rare earths)10.1088/0953-8984/16/23/025 ↗
34. Synchrotron X-ray diffraction and Raman spectroscopy of Ln3NbO7 (Ln = La, Pr, Nd, Sm-Lu) ceramics obtained by molten-salt synthesis10.1016/j.jssc.2013.10.015 ↗
35. High-temperature anion and proton conduction in RE3NbO7 (RE = La, Gd, Y, Yb, Lu) compounds10.1016/j.jeurceramsoc.2015.04.014 ↗
36. Absorption spectra of octahedral lanthanide hexahalides10.1021/j100881a021 ↗
37. Photocatalytic property and electronic structure of lanthanide tantalates, LnTaO4 (Ln = La, Ce, Pr, Nd and Sm)10.1021/jp004297z ↗
38. Thermophysical properties of rare-earth stannates: effect of pyrochlore structure10.1016/j.actamat.2012.01.057 ↗
39. Thermal expansion behaviour of some rare earth oxide pyrochlores10.1016/0025-5408(94)90201-1 ↗
40. Estimation of heat capacities of solid mixed oxides
41. Radiation tolerance of complex oxides10.1126/science.289.5480.748 ↗
42. Radiation stability of gadolinium zirconate: a waste form for plutonium disposition10.1557/JMR.1999.0606 ↗
43. Kittle · 1996
44. Klemens · 1969 · 2
45. Inorganic crystals with glass-like and ultralow thermal conductivities10.1002/crat.201700114 ↗
46. The scattering of low-frequency lattice waves by static imperfections10.1088/0370-1298/68/12/303 ↗
47. Effect of point imperfection on lattice thermal conductivity10.1103/PhysRev.120.1149 ↗
48. High-temperature thermal conductivity of porous Al2O3 nanostructures10.1103/PhysRevB.70.134201 ↗
49. Interfacial thermal resistance in nanocrystalline yttria-stabilized zirconia10.1016/S1359-6454(02)00057-5 ↗
50. Materials selection guidelines for low thermal conductivity thermal barrier coatings10.1016/S0257-8972(02)00593-5 ↗
51. Lower limit to the thermal conductivity of disordered crystals10.1103/PhysRevB.46.6131 ↗
52. A simplified method for calculating the Debye temperature from elastic constants
53. Relation between the parameters of the elasticity theory and averaged bulk modulus of solids10.1134/S106378421111020X ↗
54. Revised effective ionic radii and systematic studies of interatomic distances in halides and chaleogenides10.1107/S0567739476001551 ↗
55. Glass-like thermal conductivity in ytterbium-doped lanthanum zirconate pyrochlore10.1016/j.actamat.2010.07.035 ↗
56. Effect of point defects on the thermal transport properties of (LaxGd1-x)2Zr2O7: experiment and theoretical model10.1103/PhysRevB.74.144109 ↗
57. Influence of ZrO2 alloying effect on the thermophysical properties of fluorite-type Eu3TaO7 ceramics10.1016/j.scriptamat.2018.03.042 ↗