SHS of copper Chevrel phase compounds
Source abstract
Abstract
Chevrel phase (CP) compounds are a highly multifunctional class of materials but are underused due to the high energy processing required for their synthesis. Self-propagation high-temperature synthesis (SHS) is a low energy and quick alternative for synthesizing this material system. In this investigation, copper-based CPs were synthesized via SHS using either elemental or binary precursor powders. The elemental precursors produced non-stoichiometric Cu 2.76 Mo 6 S 8 , and consisted mainly of grown MoS 2 platelets. The binary precursor, on the other hand, produced stoichiometric Cu 2 Mo 6 S 8 . The influences of mixing and precursor concentration are discussed as well as the reaction mechanisms operating for the elemental system and the binary system, separately. The investigation into this synthesis process aims to provide a better understanding of the Chevrel SHS mechanism to accurately control the product.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Intermetallics and Advanced Alloy Properties · Advanced materials and composites · Semiconductor materials and interfaces
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (42)
Show source-provided references
1. A rapid solid-state synthesis of electrochemically active Chevrel phases (Mo6T8; T = S, Se) for rechargeable magnesium batteries10.1007/s12274-017-1695-z ↗
2. Sur de nouvelles phases sulfurées ternaires du molybdène10.1016/0022-4596(71)90095-8 ↗
3. Chemistry and structure of ternary molybdenum chalcogenides
4. Chevrel phases: past, present and future10.1016/j.physc.2015.02.019 ↗
5. Cu2Mo6S8 Chevrel phase, A promising cathode material for new rechargeable Mg batteries: a mechanically induced chemical reaction10.1021/cm021122o ↗
6. Fabrication of nanocrystalline and amorphous Chevrel phase PbMo 6S 8 powder by ball milling10.1016/S0921-4534(02)00875-4 ↗
7. Perrin · 2019 · 1
8. Facile synthesis of Chevrel phase nanocubes and their applications for multivalent energy storage10.1021/cm502306c ↗
9. Size-controlled Chevrel Mo6S8 as cathode material for Mg rechargeable battery10.5012/bkcs.2013.34.10.3033 ↗
10. Express and low-cost microwave synthesis of the ternary Chevrel phase Cu2Mo6S8 for application in rechargeable magnesium batteries10.1016/j.jssc.2016.07.022 ↗
11. Thermal explosion and ignition as a method for formal kinetic studies of exothermic reactions in the condensed phase10.1016/0010-2180(67)90046-6 ↗
12. Self-spreading high-temperature synthesis of refractory inorganic compounds
13. Salt-Assisted SHS synthesis of aluminum nitride powders for refractory applications
14. Combustion-synthesized functionally gradient refractory materials10.1557/JMR.1993.2026 ↗
15. A common regularity of stoichiometry-induced morphology evolution of transition metal carbides, nitrides, and diborides during self-propagating high-temperature synthesis10.1021/cg201604z ↗
16. Synthesis of porous Ni-Ti shape-memory alloys by self-propagating high-temperature synthesis: reaction mechanism and anisotropy in pore structure10.1016/S1359-6454(00)00184-1 ↗
17. The ability of systems based on Ni, Al and Ti to be synthesized by self-propagating high-temperature synthesis (SHS)10.1016/S0966-9795(01)00013-9 ↗
18. 8 - self-propagating high-temperature synthesis (SHS) of intermetallic matrix composites
19. Combustion synthesis of nanosized β-SiC powder on a large scale10.1021/jp710942m ↗
20. Scalable self-propagating high-temperature synthesis of graphene for supercapacitors with superior power density and cyclic stability
21. The chemistry of self-propagating high temperature synthesis10.1039/b401358c ↗
22. Self-propagating high-temperature synthesis of aluminum substituted lanthanum ferrites LaFe1−xAlxO3 (0 ≤ x ≤ 1.0)10.1039/C5NJ00981B ↗
23. ChemInform abstract: ultra fast elemental synthesis of high yield copper Chevrel phase with high electrochemical performance10.1016/j.jssc.2012.01.016 ↗
24. Intercalation based synthesis of Chevrel phase superconductors10.1007/s10853-024-09910-z ↗
25. Screw-dislocation-driven bidirectional spiral growth of Bi₂Se₃ nanoplates10.1002/anie.201403530 ↗
26. Screw dislocation driven growth of nanomaterials10.1021/ar400003q ↗
27. Spontaneous growth of hexagonal ZrB2 nanoplates driven by a screw dislocation mechanism10.1039/C8CE01618F ↗
28. Self-propagating high-temperature synthesis of ultradisperse molybdenum disulfide10.1007/BF00755826 ↗
29. The sublimation of metals at low pressures
30. Effect of sulfur evaporation rate on screw dislocation driven growth of MoS2 with high atomic step density10.1021/acs.cgd.6b01367 ↗
31. Observation of an intermediate state during lithium intercalation of twisted bilayer MoS210.1038/s41467-022-30516-z ↗
32. Li intercalation in MoS2: in situ observation of its dynamics and tuning optical and electrical properties10.1021/acs.nanolett.5b02619 ↗
33. Lithium intercalation via n-Butyllithium of the layered transition metal dichalcogenides10.1016/0025-5408(75)90115-4 ↗
34. Intercalation of MoS2(0001) with Fe, Ni and Pd10.1016/0038-1098(87)90171-2 ↗
35. Transition metal dichalcogenides and their intercalates10.1080/01442358309353343 ↗
36. Enhancing light–matter interactions in MoS2 by copper intercalation10.1002/adma.202008779 ↗
37. Van der Waals interactions and the properties of graphite and 2H-, 3R- and 1T-MoS2: A comparative study10.1016/j.commatsci.2018.05.045 ↗
38. Exfoliation of MoS2 by zero-valent transition metal intercalation10.1039/D3CC02528D ↗
39. Exfoliation of MoS2 nanosheets enabled by a redox-potential-matched chemical lithiation reaction10.1021/acs.nanolett.2c00148 ↗
40. Self-propagating exothermic reactions: the synthesis of high-temperature materials by combustion10.1016/0920-2307(89)90001-7 ↗
41. Self-propagating high-temperature synthesis for compound thermoelectrics and new criterion for combustion processing10.1038/ncomms5908 ↗
42. Intercalation‐assisted massive phase transformation: the key to SHS synthesis?