A Critical Challenge for Anion Exchange Membrane Fuel Cells (AEMFCs): Insufficient Stability of Non‐Precious Cathode Catalyst
Source abstract
Abstract
ABSTRACT Non‐precious metal (NPM) catalysts for the oxygen reduction reaction (ORR) are promising alternatives to platinum, crucial for affordable anion‐exchange membrane fuel cells (AEMFCs). Although NPM‐based AEMFCs now achieve power densities exceeding 1.0 W cm −2 , a critical barrier remains: insufficient durability for real‐world use. This review analyzes the scientific underpinnings of this durability challenge. We pinpoint four key degradation mechanisms, including carbon corrosion, Fenton reactions, water mismanagement and active‐site loss, and synthesize recent strategies to combat them. To bridge the lab‐to‐industry gap, we recommend a dual focus: developing synergistic multi‐active‐site catalysts and innovating electrode designs for superior water management. Cross‐disciplinary collaboration is urgently needed to mature these high‐stability NPM catalysts for commercial deployment.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Fuel Cells and Related Materials · Electrocatalysts for Energy Conversion · Advanced battery technologies research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
State Key Laboratory of Advanced Chemical Power Sources, College of Chemistry and Chemical Engineering; Center of Advanced Electrochemical Energy (CAEE), Institute of Advanced Interdisciplinary Studies Chongqing University Chongqing China
Funding
National Key Research and Development Program of China · Fundamental Research Funds for the Central Universities · National Natural Science Foundation of China
References (75)
Show source-provided references
1. 10.1002/smll.20250972310.1002/smll.202509723 ↗
2. 10.1002/smll.20251029310.1002/smll.202510293 ↗
3. 10.18686/cest36910.18686/cest369 ↗
4. 10.1016/j.jpowsour.2021.22949910.1016/j.jpowsour.2021.229499 ↗
5. 10.1002/adma.20200629210.1002/adma.202006292 ↗
6. 10.1002/cey2.42610.1002/cey2.426 ↗
7. 10.1021/acscatal.9b0389210.1021/acscatal.9b03892 ↗
8. 10.1038/s41560‐021‐00878‐710.1038/s41560‐021‐00878‐7 ↗
9. 10.1039/d3ee01768k10.1039/d3ee01768k ↗
10. 10.1016/j.apcatb.2022.12173310.1016/j.apcatb.2022.121733 ↗
11. 10.1016/j.mtadv.2021.10017910.1016/j.mtadv.2021.100179 ↗
12. 10.1039/c9ee00381a10.1039/c9ee00381a ↗
13. 10.1038/2011212a010.1038/2011212a0 ↗
14. 10.1038/s41467‐025‐66161‐510.1038/s41467‐025‐66161‐5 ↗
15. 10.1126/science.aad083210.1126/science.aad0832 ↗
16. 10.1002/aenm.20220439010.1002/aenm.202204390 ↗
17. 10.1016/j.ccr.2023.21540010.1016/j.ccr.2023.215400 ↗
18. 10.1021/acs.chemrev.2c0042410.1021/acs.chemrev.2c00424 ↗
19. 10.1002/aenm.20180195610.1002/aenm.201801956 ↗
20. 10.1002/anie.20200391710.1002/anie.202003917 ↗
21. 10.1021/acscatal.0c0351110.1021/acscatal.0c03511 ↗
22. 10.1021/acsenergylett.9b0059710.1021/acsenergylett.9b00597 ↗
23. 10.1002/adma.20180143010.1002/adma.201801430 ↗
24. 10.1039/c8ee02495b10.1039/c8ee02495b ↗
25. 10.1002/anie.20181109910.1002/anie.201811099 ↗
26. 10.1021/jacs.3c0537110.1021/jacs.3c05371 ↗
27. 10.1039/d4cy00351a10.1039/d4cy00351a ↗
28. 10.1002/anie.20221604110.1002/anie.202216041 ↗
29. 10.1007/s40820‐024‐01580‐510.1007/s40820‐024‐01580‐5 ↗
30. 10.1002/advs.20250101610.1002/advs.202501016 ↗
31. 10.1002/anie.20201339510.1002/anie.202013395 ↗
32. 10.1149/2.1301910jes10.1149/2.1301910jes ↗
33. 10.1039/c9ee00331b10.1039/c9ee00331b ↗
34. 10.1002/anie.20251310210.1002/anie.202513102 ↗
35. 10.1038/s41467‐025‐63322‐410.1038/s41467‐025‐63322‐4 ↗
36. 10.1002/aenm.20200198610.1002/aenm.202001986 ↗
37. 10.1021/acscatal.5c0549210.1021/acscatal.5c05492 ↗
38. 10.1021/jacs.5c1198510.1021/jacs.5c11985 ↗
39. 10.1038/s41467‐020‐17370‐710.1038/s41467‐020‐17370‐7 ↗
40. 10.1039/d0ee01133a10.1039/d0ee01133a ↗
41. 10.1016/j.memsci.2022.12034110.1016/j.memsci.2022.120341 ↗
42. 10.1016/j.memsci.2025.12395710.1016/j.memsci.2025.123957 ↗
43. 10.1016/j.cej.2024.15144610.1016/j.cej.2024.151446 ↗
44. 10.1039/d5cc01361e10.1039/d5cc01361e ↗
45. 10.1016/j.ijhydene.2024.09.26110.1016/j.ijhydene.2024.09.261 ↗
46. 10.1007/s40843‐024‐3179‐510.1007/s40843‐024‐3179‐5 ↗
47. 10.1039/c9ee01334b10.1039/c9ee01334b ↗
48. 10.1002/anie.20250393410.1002/anie.202503934 ↗
49. 10.1002/anie.20190947510.1002/anie.201909475 ↗
50. 10.1039/d1ta01748a10.1039/d1ta01748a ↗
51. 10.1002/fuce.20170009410.1002/fuce.201700094 ↗
52. 10.1126/science.aad083210.1126/science.aad0832 ↗
53. 10.1038/s41467‐018‐06279‐x10.1038/s41467‐018‐06279‐x ↗
54. 10.1002/smll.20231094010.1002/smll.202310940 ↗
55. 10.1038/s41929‐024‐01136‐110.1038/s41929‐024‐01136‐1 ↗
56. 10.1007/s11426‐024‐2359‐910.1007/s11426‐024‐2359‐9 ↗
57. 10.1016/j.jece.2026.12232710.1016/j.jece.2026.122327 ↗
58. 10.1021/jacs.5c1294710.1021/jacs.5c12947 ↗
59. 10.1021/acsnano.5c0008510.1021/acsnano.5c00085 ↗
60. 10.1016/s0013‐4686(03)00393‐110.1016/s0013‐4686(03)00393‐1 ↗
61. 10.1021/jacs.4c0690410.1021/jacs.4c06904 ↗
62. 10.1038/s41560‐022‐00988‐w10.1038/s41560‐022‐00988‐w ↗
63. 10.1021/acscatal.0c0094810.1021/acscatal.0c00948 ↗
64. 10.1002/adfm.20230385710.1002/adfm.202303857 ↗
65. 10.1016/j.ijhydene.2020.05.02610.1016/j.ijhydene.2020.05.026 ↗
66. 10.1021/acsenergylett.5c0120210.1021/acsenergylett.5c01202 ↗
67. 10.1016/j.memsci.2024.12243210.1016/j.memsci.2024.122432 ↗
68. 10.1002/smll.20250806310.1002/smll.202508063 ↗
69. 10.1039/d5ta05392g10.1039/d5ta05392g ↗
70. 10.1002/anie.20250618310.1002/anie.202506183 ↗
71. 10.1038/s41467‐019‐09503‐410.1038/s41467‐019‐09503‐4 ↗
72. 10.1016/j.checat.2025.10152510.1016/j.checat.2025.101525 ↗
73. 10.1021/acsenergylett.4c0282410.1021/acsenergylett.4c02824 ↗
74. 10.1016/j.joule.2024.02.01110.1016/j.joule.2024.02.011 ↗
75. 10.1021/jacs.5c1148910.1021/jacs.5c11489 ↗