journal article·2025-11Open access

Multistage Activation Barriers in the Chiral Metallosupramolecular Polymerization of Alkynylplatinum(II) Complexes (Small 46/2025)

Kayeong Go, Tomoki Nishimura, Sung Ho Jung, Jong Hwa Jung

Small· Volume 21· Issue 46

Abstract

Supramolecular Polymerization Chiral terpyridine-based alkynylplatinum(II) complexes undergo a multistep kinetic process that ultimately yields a thermodynamically stable product. According to the F–W two-step model, the final stage—characterized by a substantially high activation energy—serves as the rate-determining step, thereby governing the overall kinetics of the supramolecular polymerization pathway. More in article number 2503480, Sung Ho Jung, Jong Hwa Jung, and co-workers.
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Research context

OpenAlex topics: Organometallic Complex Synthesis and Catalysis · Synthesis and Properties of Aromatic Compounds · Supramolecular Chemistry and Complexes

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Affiliations

Department of Chemistry and Research Institution of Natural Sciences Gyeongsang National University (GNU) Jinju 52828 Republic of Korea

Department of Chemistry and Materials Science Faculty of Textile Science and Technology Shinshu University Ueda Nagano 386‐8567 Japan

Research Institute for Advanced Chemistry Gyeongsang National University (GNU) Jinju 52828 Republic of Korea

References

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