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journal article·2025-09Open access

High Ionic Conduction in Rb‐ and Cs‐Mixed Cation Amide for Energy Storage (Small 36/2025)

Thi Thu Le, Kai Sellschopp, Fabrizio Murgia, Anna Louise Garden, Simone Bordignon, Jan Peter Embs, Michele Remo Chierotti, Alexander Schökel, Fahim Karimi, Paul Jerabek, Thomas Klassen, Claudio Pistidda

Small· Volume 21· Issue 36
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Source abstract

Abstract

Ionic conductivity In article number 2502943, Thi Thu Le, Claudio Pistidda, and co-workers illustrate the ionic transport behaviour of the newly developed Rb0.5Cs0.5NH2 solid solution. Rotational dynamics of NH2 groups, coupled with cation pathways, enable significantly high ionic conductivity. The synergy between experimental observations and DFT calculations reveals the fundamental mechanisms underlying enhanced ion mobility and structural stabilization in this promising solid-state material.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Inorganic Chemistry and Materials · Solid-state spectroscopy and crystallography · Rare-earth and actinide compounds

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Affiliations

Institute of Hydrogen Technology Helmholtz‐Zentrum hereon GmbH D‐21502 Geesthacht Germany

Department of Chemical Physical Mathematical and Natural Sciences University of Sassari Sassari 07100 Italy

Department of Chemistry University of Otago Dunedin 9054 New Zealand

The MacDiarmid Institute for Advanced Materials and Nanotechnology Victoria University of Wellington Wellington 6140 New Zealand

Department of Chemistry and NIS Centre University of Torino Torino 10125 Italy

PSI Center for Neutron and Muon Sciences PSI Villigen 5232 Switzerland

Deutsches Elektronen‐Synchrotron DESY D‐22607 Hamburg Germany

Helmut Schmidt University University of the Federal Armed Forces Hamburg D‐22043 Hamburg Germany

References

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