journal article·2025-07Open access

Hierarchically Porous Poly(aryl thioether)s Through Dynamic Linker Engineering for Thiyl Radical Photocatalysis (Small 27/2025)

Sunil Kumar, Doyun Kim, Youngdong Song, Bolormaa Bayarkhuu, Jueun Park, Donghee Hoh, Cafer T. Yavuz, Jeehye Byun

Small· Volume 21· Issue 27

Abstract

Porous Polymers In article number 2501398, Cafer T. Yavuz, Jeehye Byun, and co-workers present a bio-inspired synthesis of hierarchically porous polymers. Balancing disulfide bridges in poly(aryl thioether)s, fine control over porosity is achieved, showcasing enhanced adsorption and visible-light-driven thiyl radical photocatalysis. The in-situ linkage control integrates structural hierarchy with catalytic functionality, demonstrating a new design strategy for multifunctional porous organic polymers.
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Research context

OpenAlex topics: Covalent Organic Framework Applications · Advanced Photocatalysis Techniques · Chemical Synthesis and Reactions

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Affiliations

Water Cycle Research Center Korea Institute of Science and Technology (KIST) Seoul 02792 Republic of Korea

Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology (KAIST) 291 Daehak‐ro, Yuseong‐gu Daejeon 34141 Republic of Korea

Division of Energy and Environment Technology KIST‐School University of Science and Technology Seoul 02792 Republic of Korea

MSU‐DOE Plant Research Laboratory Michigan State University East Lansing Michigan 48824 USA

Oxide & Organic Nanomaterials for Energy & Environment Laboratory Chemistry Program Physical Science & Engineering (PSE) King Abdullah University of Science and Technology (KAUST) Thuwal 23955 Saudi Arabia

References

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