journal article·2025-05Open access

Evaluation of Alternative Lithium Salts for High‐Voltage Lithium Ion Batteries: Higher Relevance of Plated Li Morphology Than the Amount of Electrode Crosstalk (Small 19/2025)

Anindityo Arifiadi, Lennart Wichmann, Tobias Brake, Christian Lechtenfeld, Julius Buchmann, Feleke Demelash, Peng Yan, Gunther Brunklaus, Isidora Cekic‐Laskovic, Simon Wiemers‐Meyer, Martin Winter, Johannes Kasnatscheew

Small· Volume 21· Issue 19

Abstract

Lithium-Ion Batteries High voltage Li-ion batteries have higher specific energy/energy density but lower cycle life. The latter is relevantly impacted by electrode crosstalk, i.e., transition metal dissolution from cathode and deposition on anode, triggering high surface area lithium (HSAL) plating. Conducting salts like LiBF4 or lithium difluoro(oxalate)borate (LiDFOB) decrease parasitic reactions by lowering HSAL surface area, thus boosting cycle life. More in article number 2410762, Johannes Kasnatscheew and co-workers.
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Research context

OpenAlex topics: Advancements in Battery Materials · Extraction and Separation Processes · Advanced Battery Materials and Technologies

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Affiliations

MEET Battery Research Center Institute of Physical Chemistry University of Münster Corrensstr. 46 48149 Münster Germany

International Graduate School for Battery Chemistry, Characterization, Analysis, Recycling and Application (BACCARA) University of Münster Corrensstr. 40 48149 Münster Germany

Helmholtz Institute Münster IMD‐4 Forschungszentrum Jülich GmbH Corrensstr. 46 48149 Münster Germany

References

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