journal article·2025-06Open access

Xerogelthermal Synthesis of an Aluminophosphate Zeolite with Unique Topological Structure

Haojie Li, Ningning Gao, Xibing Gao, Junjun Qiao, Congxin Wang, Xiaoge Wang, Ling Zhang, Shuo Tao, Jingbo Jia, Runduo Zhang, Zhijian Tian, Ying Wei

Small· Volume 21· Issue 25

Abstract

Abstract Xerogelthermal synthesis, as one type of green dry‐synthesis method, is for the first time developed for the preparation of an aluminophosphate (AlPO) zeolite with a new topological structure, named BUCT‐10. Its framework is comprised of afi ([6 5 ]) and nsc ([4 2 6 2 ]) units, which are jointly connected in an unprecedented combined linear and bent configuration. This is notably different from the known topological structures, in which only a single configuration is observed within any one structure. BUCT‐10 possesses 1D 10‐ring (10R) straight channels with an unusual egg‐shape aperture, templated by butyltrimethylammonium cation, and presents high structural stability after detemplation. Heteroatom magnesium can be effectively incorporated into the structure, showing superior catalytic performance in 1‐butene skeleton isomerization with integrated advantages of AEL and FER‐type industrial zeolitic catalysts. The xerogelthermal approach presents a promising sustainable strategy for the exploration of industrially important zeolitic materials with a novel structure.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Zeolite Catalysis and Synthesis · Chemical Synthesis and Characterization · Metal-Organic Frameworks: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Organic‐Inorganic Composites Beijing Key Laboratory of Energy Environmental Catalysis Beijing University of Chemical Technology Beijing 100029 P. R. China

National Engineering Research Center for Petroleum Refining Technology and Catalyst, RIPP SINOPEC Beijing 100083 P. R. China

Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian 116023 P. R. China

College of Chemistry and Molecular Engineering Peking University Beijing 100871 P. R. China

National Energy Research Center for Coal to Clean Fuels Synfuels China Co., Ltd Beijing 101407 P. R. China

College of Chemistry and Chemical Engineering Liaocheng University Liaocheng 252059 P. R. China

State Key Laboratory of Chemical Resource Engineering Beijing Key Laboratory of Energy Environmental Catalysis Beijing University of Chemical Technology Beijing 100029 P. R. China

Funding

Natural Science Foundation of Beijing Municipality · Fundamental Research Funds for the Central Universities

References (48)

Show source-provided references
1. 10.1039/C5CS00023H10.1039/C5CS00023H ↗
2. 10.1126/science.abk325810.1126/science.abk3258 ↗
3. 10.1126/science.ade177110.1126/science.ade1771 ↗
4. 10.1038/s41586-024-07194-610.1038/s41586-024-07194-6 ↗
5. 10.1038/s41586-024-08206-110.1038/s41586-024-08206-1 ↗
6. 10.1021/jacs.1c0265410.1021/jacs.1c02654 ↗
7. 10.1002/anie.20201180110.1002/anie.202011801 ↗
8. Sara A. · Angew. Chem., Int. Ed. · 2020 · 60
9. 10.1002/anie.20191248810.1002/anie.201912488 ↗
10. 10.1002/chem.20180208710.1002/chem.201802087 ↗
11. 10.1002/anie.20241651510.1002/anie.202416515 ↗
12. 10.1021/jacs.4c0139310.1021/jacs.4c01393 ↗
13. 10.1002/anie.20210673410.1002/anie.202106734 ↗
14. 10.1002/anie.20201548310.1002/anie.202015483 ↗
15. 10.1002/anie.20191523210.1002/anie.201915232 ↗
16. 10.1002/anie.20200174010.1002/anie.202001740 ↗
17. 10.1002/anie.20180138610.1002/anie.201801386 ↗
18. 10.1021/ja057933l10.1021/ja057933l ↗
19. 10.1002/anie.20100032010.1002/anie.201000320 ↗
20. 10.1021/cm201221z10.1021/cm201221z ↗
21. 10.1021/cr400151310.1021/cr4001513 ↗
22. 10.1021/acs.accounts.8b0005710.1021/acs.accounts.8b00057 ↗
23. 10.1021/ja304495410.1021/ja3044954 ↗
24. 10.1002/anie.20130267210.1002/anie.201302672 ↗
25. 10.1021/ja512401310.1021/ja5124013 ↗
26. 10.1002/chem.20220009610.1002/chem.202200096 ↗
27. 10.1021/jacs.3c0025810.1021/jacs.3c00258 ↗
28. 10.1021/jacs.6b0120010.1021/jacs.6b01200 ↗
29. 10.1002/anie.20120900210.1002/anie.201209002 ↗
30. Y.Wei H.Li J.Qiao R.Zhang (China Patent Application) CN202310693866.4 2023.
31. 10.1002/chem.20170503810.1002/chem.201705038 ↗
32. 10.1021/cr020060i10.1021/cr020060i ↗
33. Yang N. · Pro. Chem. · 2012 · 24 · 253
34. 10.1021/ja802207p10.1021/ja802207p ↗
35. 10.1039/D0SC05731B10.1039/D0SC05731B ↗
36. Deposition numbers 2388989 (for as‐synthesized BUCT‐10) and 2388990 (for calcined BUCT‐10) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service.
37. C.h.Baerlocher L. B.McCusker Database of Zeolite Structures https://www.iza‐structure.org/databases(accessed: January 2025).
38. 10.1021/ja020999l10.1021/ja020999l ↗
39. 10.1038/ncomms932810.1038/ncomms9328 ↗
40. 10.1038/nature0286010.1038/nature02860 ↗
41. 10.1021/j150669a01610.1021/j150669a016 ↗
42. 10.1039/C8NJ03462A10.1039/C8NJ03462A ↗
43. 10.1007/s10562-006-0070-610.1007/s10562-006-0070-6 ↗
44. 10.1016/S0926-860X(00)00847-410.1016/S0926-860X(00)00847-4 ↗
45. 10.1006/jcat.1997.152510.1006/jcat.1997.1525 ↗
46. 10.1016/S0926-860X(98)00413-X10.1016/S0926-860X(98)00413-X ↗
47. 10.1021/cs400025s10.1021/cs400025s ↗
48. 10.1021/acscatal.4c0189810.1021/acscatal.4c01898 ↗