DataVXSmallPaper
journal article·2026-05

Anion Storing Boron Nitride Hybrid Nanosheets for High‐Performance Dual Ion and Zinc Alkaline Full Cells

Dong Hyun Min, Mingyu Jung, Phuong Minh Nguyen, Peixun Xiong, Sang Joon Lee, Xiaotong Han, Wenwu Li, Xu Yu, Hyeyoung Shin, Bruce Dunn, Ho Seok Park

Small· Volume 22· Issue 25
Publisher page
Source abstract

Abstract

Abstract Hexagonal boron nitride (BN), a well‐known member of 2D materials, has a structure similar to graphene and is often referred to as white graphene. Despite its unique physical and chemical properties for energy storage applications, there have been very few studies on how BN stores anion carriers. Herein, the hybrid architecture and anion storage mechanism of BN nanosheets for high‐performance hybrid energy storage full cells based on dual‐ion and Zinc (Zn) alkaline systems is demonstrated. The chemical bonding between BN and reduced graphene oxide (rGO) is attributed to the formation of the heterointerface, which facilitates the charge transfer kinetics during an OH storing process. Based on the reversible surface redox reaction of BN and rGO hybrid (BN@rGO) confirmed by computational and spectroscopic analyses, the BN@rGO electrode is applied to both Na and OH dual‐ion and Zn alkaline full cells. In the dual‐ion system, Ti 3 C 2 ‖BN@rGO full cells extended the operating voltage range up to 1.7 V, delivering a cell capacity of 49.4 mAh g −1 at 1000 mA g −1 and retaining 80% of its initial capacity after 40 000 cycles. In the Zn alkaline system, Zn‖BN@rGO full cells achieved a cell capacity of 58.1 mAh g −1 at 1000 mA g −1 and retained 80% capacity over 90 000 cycles.
Source: crossref · Quality: baseline

Research context

Nanomaterials

OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced battery technologies research · MXene and MAX Phase Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemical Engineering Sungkyunkwan University (SKKU) Suwon 16419 Republic of Korea

Graduate School of Energy Science and Technology (GEST) Chungnam National University Daejeon 34134 Republic of Korea

School of Chemistry and Chemical Engineering Chongqing University No.55 University City South Road Chongqing 401331 P. R. China

School of Chemistry and Chemical Engineering Yangzhou University Yangzhou 225002 P. R. China

Department of Materials Science and Engineering Henry Samueli School of Engineering and Applied Science University of California Los Angeles CA 90095 USA

Department of Health Sciences and Technology Samsung Advanced Institute for Health Sciences and Technology (SAIHST) Sungkyunkwan University 2066, Seoburo, Jangan‐gu Suwon 440–746 Republic of Korea

SKKU Advanced Institute of Nano Technology (SAINT) Sungkyunkwan University 2066, Seoburo, Jangan‐gu Suwon 440–746 Republic of Korea

SKKU Institute of Energy Science and Technology (SIEST) Sungkyunkwan University 2066, Seoburo, Jangan‐gu Suwon 440–746 Republic of Korea

Funding

National Research Foundation of Korea

References (66)

Show source-provided references
1. 10.1002/aenm.20170240910.1002/aenm.201702409 ↗
2. 10.1002/adma.20240018410.1002/adma.202400184 ↗
3. 10.1002/adma.20200495910.1002/adma.202004959 ↗
4. 10.1126/science.124808010.1126/science.1248080 ↗
5. Wang L. · Exploration · 2021 · 1 · 3
6. 10.1002/EXP.2023005610.1002/EXP.20230056 ↗
7. 10.1002/aenm.20170293010.1002/aenm.201702930 ↗
8. 10.1002/sus2.810.1002/sus2.8 ↗
9. 10.1038/nenergy.2016.7010.1038/nenergy.2016.70 ↗
10. 10.1038/s41563-020-0747-z10.1038/s41563-020-0747-z ↗
11. 10.1039/D0CS00721H10.1039/D0CS00721H ↗
12. 10.1038/nmat400010.1038/nmat4000 ↗
13. 10.1007/s10971-018-4580-710.1007/s10971-018-4580-7 ↗
14. 10.1149/2.1281810jes10.1149/2.1281810jes ↗
15. 10.1149/2.0681903jes10.1149/2.0681903jes ↗
16. 10.1039/C5NR08963H10.1039/C5NR08963H ↗
17. 10.1016/j.mtener.2023.10138810.1016/j.mtener.2023.101388 ↗
18. 10.1021/acsaem.9b0056610.1021/acsaem.9b00566 ↗
19. 10.1039/D0EE03356A10.1039/D0EE03356A ↗
20. 10.1038/s41467-022-28176-010.1038/s41467-022-28176-0 ↗
21. 10.1016/j.ensm.2021.08.01710.1016/j.ensm.2021.08.017 ↗
22. 10.1002/advs.20230650410.1002/advs.202306504 ↗
23. 10.1016/j.ensm.2022.04.00810.1016/j.ensm.2022.04.008 ↗
24. 10.1063/5.003070910.1063/5.0030709 ↗
25. 10.1021/nn100649510.1021/nn1006495 ↗
26. 10.1038/s41578-019-0124-110.1038/s41578-019-0124-1 ↗
27. 10.1016/j.ceramint.2018.11.10110.1016/j.ceramint.2018.11.101 ↗
28. 10.1021/acs.chemmater.6b0294710.1021/acs.chemmater.6b02947 ↗
29. 10.1016/j.carbon.2017.10.04710.1016/j.carbon.2017.10.047 ↗
30. 10.1063/1.297368210.1063/1.2973682 ↗
31. 10.1039/C7RA12872J10.1039/C7RA12872J ↗
32. 10.1016/j.colsurfa.2021.12618110.1016/j.colsurfa.2021.126181 ↗
33. 10.1007/s10904-022-02500-z10.1007/s10904-022-02500-z ↗
34. 10.1007/s10853-017-1729-710.1007/s10853-017-1729-7 ↗
35. 10.1016/0038-1098(78)90288-010.1016/0038-1098(78)90288-0 ↗
36. 10.1039/C8NR06283H10.1039/C8NR06283H ↗
37. 10.1016/j.compositesb.2022.11049610.1016/j.compositesb.2022.110496 ↗
38. 10.1039/D0RA00326C10.1039/D0RA00326C ↗
39. 10.1016/j.pnsc.2015.10.00410.1016/j.pnsc.2015.10.004 ↗
40. 10.1016/j.apcatb.2022.12157410.1016/j.apcatb.2022.121574 ↗
41. 10.1007/s40820-022-00966-710.1007/s40820-022-00966-7 ↗
42. 10.1021/acsaem.9b0161710.1021/acsaem.9b01617 ↗
43. 10.1039/D3DT02182C10.1039/D3DT02182C ↗
44. 10.3390/catal911095410.3390/catal9110954 ↗
45. 10.3390/ma1710243810.3390/ma17102438 ↗
46. Chang B. Y. S. · Int. J. Nanomed. · 2012 · 7 · 3379
47. 10.1007/s12034-021-02576-210.1007/s12034-021-02576-2 ↗
48. 10.3390/mi1402030310.3390/mi14020303 ↗
49. Noorazlan A. M. · J. Nanomater. · 2015 · 952308 · 9
50. 10.1126/science.124148810.1126/science.1241488 ↗
51. 10.1039/C9TA11827F10.1039/C9TA11827F ↗
52. 10.1039/c3ee41143e10.1039/c3ee41143e ↗
53. 10.1021/acsami.5b0566010.1021/acsami.5b05660 ↗
54. 10.1039/C5TA01804H10.1039/C5TA01804H ↗
55. 10.1016/j.jpowsour.2009.12.01810.1016/j.jpowsour.2009.12.018 ↗
56. 10.1002/anie.20160360110.1002/anie.201603601 ↗
57. 10.1021/acsenergylett.8b0139310.1021/acsenergylett.8b01393 ↗
58. 10.1016/j.ensm.2021.03.02910.1016/j.ensm.2021.03.029 ↗
59. 10.1016/j.jallcom.2018.02.23110.1016/j.jallcom.2018.02.231 ↗
60. 10.1021/acsami.6b0816510.1021/acsami.6b08165 ↗
61. 10.1016/j.jpowsour.2016.09.15110.1016/j.jpowsour.2016.09.151 ↗
62. 10.1002/smll.20180156210.1002/smll.201801562 ↗
63. 10.1039/C7TA07160D10.1039/C7TA07160D ↗
64. 10.1039/C6CP02228F10.1039/C6CP02228F ↗
65. 10.1039/c2jm35307e10.1039/c2jm35307e ↗
66. 10.1002/aenm.20140188210.1002/aenm.201401882 ↗