Volcanic Eruption in the Nanoworld: Efficient Oxygen Exchange at the Si/SnO₂ Interface

Abstract Here, a phenomenon of efficient oxygen exchange between a silicon surface and a thin layer of tin dioxide during chemical vapor deposition is presented, which leads to a unique Sn:SiO₂ layer. Under thermodynamic conditions in the temperature range of 725–735 °C, the formation of nanostructures with volcano‐like shapes in “active” and “dormant” states are observed. Extensive characterization techniques, such as electron microscopy, X‐ray diffraction, synchrotron radiation‐based X‐ray photoelectron, and X‐ray absorption near‐edge structure spectroscopy, are applied to study the formation. The mechanism is related to the oxygen retraction between tin(IV) oxide and silicon surface, leading to the thermodynamically unstable tin(II)oxide, which is immediately disproportionate to metallic Sn and SnO₂ localized in the SiO₂ matrix. The diffusion of metallic tin in the amorphous silicon oxide matrix leads to larger agglomerates of nanoparticles, which is similar to the formation of a magma chamber during the natural volcanic processes followed by magma eruption, which here is associated with the formation of depressions on the surface filled with metallic tin particles. This new effect contributes a new approach to the formation of functional composites but also inspires the development of unique Sn:SiO₂ nanostructures for diverse application scenarios, such as thermal energy storage.