journal article·2023-08Open access

Two‐Step Synthesis of B2N2‐Doped Polycyclic Aromatic Hydrocarbon Containing Pentagonal and Heptagonal Rings with Long‐Lived Delayed Fluorescence (Small 34/2023)

Huan Luo, Qingyun Wan, Wookjin Choi, Yusuke Tsutsui, Evgenia Dmitrieva, Lili Du, David Lee Phillips, Shu Seki, Junzhi Liu

Small· Volume 19· Issue 34

Abstract

Polycyclic Aromatic Hydrocarbons A pentagon-heptagon-embedded polycyclic aromatic hydrocarbon (PAH) consisting of B-N heteroatoms (BN-2) is synthesized in only two steps. Combining spectroscopic measurements and theoretical calculations, the excited-state dynamics of the resultant BN-doped PAHs are well-investigated, demonstrating both prompt fluorescence and long-lived delayed fluorescence components with their triplet excited-state lifetimes in the microsecond time region. More details can be found in article number 2301769 by Shu Seki, Junzhi Liu, and co-workers.
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Research context

OpenAlex topics: Organoboron and organosilicon chemistry · Luminescence and Fluorescent Materials · Boron Compounds in Chemistry

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Affiliations

Department of Chemistry and State Key Laboratory of Synthetic Chemistry The University of Hong Kong Pokfulam Road Hong Kong 999077 China

Chemistry and Chemical Engineering Guangdong Laboratory Shantou 515031 China

Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan

Leibniz Institute for Solid State and Materials Research (IFW) Dresden Helmholtzstr. 20 01069 Dresden Germany

School of Life Sciences Jiangsu University Zhenjiang 212013 China

References

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